• Title/Summary/Keyword: Indium trichloride

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InCl3-Catalyzed Regioselective Ring-Opening Reactions of Epoxides to β-Hydroxy Ethers

  • Kim, Byeong-Hyo;Piao, Fengyu;Lee, Eun-Joo;Kim, Ji-Sook;Jun, Young-Moo;Lee, Byung-Min
    • Bulletin of the Korean Chemical Society
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    • v.25 no.6
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    • pp.881-888
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    • 2004
  • By applying a catalytic amount of indium trichloride, regioselective ring-opening of epoxides to ${\beta}$-hydroxy ethers was established. While the alcoholysis of styrene oxides produed $S_N1$-type product, the alcoholysis of ${\alpha}$-heteroatom-substituted epoxides predominantly produced $S_N2$-type product.