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InCl3-Catalyzed Regioselective Ring-Opening Reactions of Epoxides to β-Hydroxy Ethers

  • Published : 2004.06.20
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Abstract

By applying a catalytic amount of indium trichloride, regioselective ring-opening of epoxides to ${\beta}$-hydroxy ethers was established. While the alcoholysis of styrene oxides produed $S_N1$-type product, the alcoholysis of ${\alpha}$-heteroatom-substituted epoxides predominantly produced $S_N2$-type product.

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References

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