• Title/Summary/Keyword: In-doped

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Study of Pd Target Power Effects on Physical Characteristics of Pd-Doped Carbon Thin Films Using Dual Magnetron Sputtering Method (듀얼 마그네트론 스퍼터링 법으로 제조된 Pd-Doped Carbon 박막의 물리적 특성에서 Pd 타겟 전력의 영향에 대한 연구)

  • Choi, Young-Chul;Park, Yong Seob
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.5
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    • pp.488-493
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    • 2022
  • Generally, diamond-like carbon films (a-C:H, DLC) have been shown to have a low coefficient of friction, a high hardness and a low wear rate. Pd-doped C thin film was fabricated using a dual magnetron sputtering with two targets of graphite and palladium. Graphite target RF power was fixed and palladium target RF power was varied. The structural, physical, and surface properties of the deposited thin film were investigated, and the correlation among these properties was examined. The doping ratio of Pd increased as the RF power increased, and the surface roughness of the thin film decreased somewhat as the RF power increased. In addition, the hardness value of the thin film increased, and the adhesive strength was improved. It was confirmed that the value of the contact angle indicating the surface energy increases as the RF power increases. It was concluded that the increase in RF power contributed to the improvement of the physical properties of Pd-doped C thin film.

Rational Design of Binder-Free Fe-Doped CuCo(OH)2 Nanosheets for High-Performance Water Oxidation

  • Patil, Komal;Jang, Su Young;Kim, Jin Hyeok
    • Korean Journal of Materials Research
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    • v.32 no.5
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    • pp.237-242
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    • 2022
  • Designing and producing a low-cost, high-current-density electrode with good electrocatalytic activity for the oxygen evolution reaction (OER) is still a major challenge for the industrial hydrogen energy economy. In this study, nanostructured Fe-doped CuCo(OH)2 was discovered to be a precedent electrocatalyst for OER with low overpotential, low Tafel slope, good durability, and high electrochemically active surface sites at reduced mass loadings. Fe-doped CuCo(OH)2 nanosheets are made using a hydrothermal synthesis process. These nanosheets are clumped together to form a highly open hierarchical structure. When used as an electrocatalyst, the Fe-doped CuCo(OH)2 nanosheets required an overpotential of 260 mV to reach a current density of 50 mA cm-2. Also, it showed a small Tafel slope of 72.9 mV dec-1, and superior stability while catalyzing the generation of O2 continuously for 20 hours. The Fe-doped CuCo(OH)2 was found to have a large number of active sites which provide hierarchical and stable transfer routes for both electrolyte ions and electrons, resulting in exceptional OER performance.

Non-Steady State Gas Permeation Measurements of $TiO_2$-Doped YSZ

  • Kobayashi, Kiyoshi;Yamaguchi, Shu;Iguchi, Yoshiaki
    • The Korean Journal of Ceramics
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    • v.6 no.2
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    • pp.150-154
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    • 2000
  • Mobilities of electrons ($\mu_p$) and holes ($\mu_p$) in 2, 5, and 10 mol% $TiO_2$-doped yttria stabilized zirconia (TD-YSZ) have been estimated by a non-steady state gas permeation method using models proposed by Weppner and Maruyama. Values of $\mu_n$ and $\mu_p$ were found to be closed to those in non-doped YSZ reported earlier. The concentration of electrons and holes were calculated from $\mu_n$ and $\mu_p$ values and the partial conductivities of electrons and holes measured by a dc-polarization method. The concentration of electrons at unit oxygen partial pressure increased with increasing $TiO_2$concentration, while the hole concentration was almost independent of $TiO_2$concentration.

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Red OLEDs containing the dotted-line doped layer structure in its emitting region.

  • Lee, Chang-Min;Han, Jeong-Whan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.612-615
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    • 2004
  • We present an extremely high efficient red organic light-emitting diodes (OLEDs) using a fluorescent dye 4-(dicyanomethylene)-2-tert-butyl-6-(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran (DCJTB) doped into an emitting region which consists of multiple pairs of a doped and an undoped layer. An emitting region of OLEDs composes of a tris-(8-hydroxyquinolinato) aluminum (Alq3) codoped with rubrene of 5% wt. or a mixture of Alq3 and rubrene (1:1). The luminance yield of the codoped device and the mixed device are 6.5 cd/A and 9.2 cd/A at 10 mA/$cm^2$, respectively. We have considerably improved the luminance yields of red OLEDs as much as ${\sim}$90% at 10 mA/$cm^2$ compared with that of the device doped with only DCJTB. We attribute it to both the emitting assist dopant (rubrene) and the dotted-line doping structure in an emitting region of OLED.

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Luminescence Properties of $Dy^{3+}-(or Tm^{3+}-)$ Doped $Ga_2O_3$ and $ZnGa_2O_4$ Phosphors

  • Ryu, Ho-Jin;Park, Hee-Dong
    • The Korean Journal of Ceramics
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    • v.3 no.2
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    • pp.134-138
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    • 1997
  • $Dy^{3+}-(or Tm^{3+}-)$ doped $Ga_2O_3 \;and\; ZnGa_2O_4$ phosphors were prepared using the solid state reaction method to investigate their photoluminescent characteristics. Under 254 nm excitation, $Dy^{3+}-doped Ga2_O_3$ exhibited two emission bands of 460~505nm and 570~600nm. On the other hand, $Dy^{3+}-(or Tm^{3+}-)$ doped $ZnGa_2O_4 $phosphors exhibited a broad-band emission extending from 330 nm to 610 nm, peaking at about 430 nm(or 370 nm). In this study, an emission peak shift of nealy 50 nm towards longer wavelength region was observed with $Dy^{3+}$ doping in the $ZnGa_2O_4 $.

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The Effect of Different Substrate Temperature on the Electrical Properties of Al-doped ZnO Thin Films (Al-doped ZnO 박막의 기판 온도에 따른 전기적, 광학적 특성)

  • Kim, Bong-Seok;Kim, Eung-Kwon;Lee, Kyu-Il;Oh, Su-Young;Song, Joon-Tae
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.10
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    • pp.1782-1785
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    • 2007
  • In this paper, the effect of substrate temperature on structural, electrical and optical properties of aluminium-doped zinc oxide (AZO) films were investigated. AZO thin films were prepared on glass substrate by pulsed DC magnetron sputtering technique. The properties of AZO were measured by using XRD, AFM, UV spectrophotometer, and hall effect measurement system. The resistivity of AZO films was improved under the condition of high substrate temperature. The resistivity decreased from $9.95{\times}10^{-2}\;{\Omega}-cm\;to\;1.1{\times}10^{-3}\;{\Omega}-cm$ as a result of high substrate temperature and the average transmittances in visible range were above 80%.

Red-shift of the photoluminescence peak of N-doped ZnO phosphors

  • Kim, Jun-Kwan;Lim, Jung-Wook;Kim, Hyun-Tak;Yun, Sun-Jin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.895-897
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    • 2008
  • ZnO films were fabricated using rf-magnetron sputter deposition process with different $N_2$ ambient. N-content in N-doped ZnO films was less than 1%. The wavelength of the highest intensity PL peak of N-doped ZnO was shifted to higher wavelength with increasing $N_2$ flow rate in the deposition ambient. These results indicated that the optical property of ZnO was significantly affected by the defect level created by doping with a very small amount of N.

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PREPARATION AND CHARACTERIZATION ON THIN FILMS OF DOPED IRON OXIDE PHOTOSEMICONDUCTIVE ELECTRODES. (얇은막 산화철 광반도성 전극의 제조와 그 특성)

  • Kim, Il-Kwang;Kim, Yon-Geun;Park, Tae-Young;Park, Choon-Bae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1993.05a
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    • pp.104-108
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    • 1993
  • Thin films of MgO-doped and CaO-doped iron oxide were prepared y spray pyrolysis. The films were characterized b X-ray diffraction, scanning electron microscopy and voltammetric techniques. The photoelectrochemical behavior of thin film electrodes depended greatly on the doping level, sintering temperature, substrate temperature and added photosensitizing compounds in solution, showed p-type photoelectrochemical behavior, while the CaO-doped iron oxide thin films prepared at low temperature showed n-type photoelectrochemical behavior. This characteristic change was interpreted in terms of the surface structure change of the thin films and doping effect of metal oxide.

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A Study of Phase-change Properties of Sb-doped Ag/Ge-Se-Te thin films (Sb-doped Ag/Ge-Se-Te 박막의 상변화 특성 연구)

  • Nam, Ki-Hyun;Jeong, Won-Kook;Park, Ju-Hyun;Chung, Hong-Bay
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.347-347
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    • 2010
  • In other to progress better crystallization transition and long phase-transformation data of phase-change memory (PRAM), we investigated about the effect of Sb doping and Ag ions percolating into Ge-Se-Te phase-change material. Doped Sb concentrations was determined each of 10 wt%, 20 wt% and 30 wt%. As the Sb-doping concentration was increased, the resistivity decreased and the crystallization temperature increased. Ionization of Ag was progressed by DPSS laser (532 nm) for 1 hour. The resistivity was more decreased and the crystallization temperature was more increased in case of adding Ag layer under Sb-(Ge-Se-Te) thin film. At the every condition of thin films included Ag layer more stable states were indicated compare with just Sb-doped Ge-Se-Te thin films.

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Effect of Ball-Milling on the Superconducting Properties of C and C-Based Compound Doped $MgB_2$ (탄소 및 탄소화합물이 도핑된 $MgB_2$ 초전도체의 볼밀링 효과)

  • Ahn, Jung-Ho;Jang, Min-Kyu;Oh, Sang-Jun
    • Progress in Superconductivity
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    • v.10 no.1
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    • pp.17-22
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    • 2008
  • We have examined the effect of ball-milling on the superconducting properties of $MgB_2$ doped with C. The ball-milling of pre-reacted $MgB_2$ powder was carried out in dry or wet state using C or diethylenetriamine ($C_{4}H_{13}N_3$) as additives. The diethylenetriamine, whose chemical formula contains no oxygen, was chosen to avoid an excess oxidation during doping. The superconducting transition temperature (Tc) of the ball-milled or doped $MgB_2$ powders was only slightly smaller than that of undoped $MgB_2$. The critical current density (Jc) of the highly ball-milled $MgB_2$ was higher than that of C-doped $MgB_2$. The addition of diethylenetriamine was detrimental to Jc, although Tc was almost unchanged.

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