• Title/Summary/Keyword: In-doped

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Organic Electroluminescence Device using Dye doped Emitting (색소 doped 유기EL 소자에 의한 고효율화)

  • 임장순;강성종;노병규;오환술
    • Proceedings of the IEEK Conference
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    • 2000.11b
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    • pp.261-264
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    • 2000
  • Organic light emitting diodes(OLEDs) have been expected to find an application as a new type of display since C. W. Tang and VanSlyke first reported on high performance OLEDs. This paper has been stuied a green organic EL device using dye doped emitting layer such as C6(Coumarin 6). In the Alq-based e]ectroluminescence diodes, we applied highly fluorescent molecular(Coumarin 6) and obtained enhancement in the electroluminescence efficiency.

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Aging Studies on Conducting Polypyrrole

  • Kaynak, Akif
    • Fibers and Polymers
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    • v.2 no.4
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    • pp.171-177
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    • 2001
  • Change of tensile properties, electrical conductivity and microwave shielding of electrochemically synthesized polypyrrole films with time are presented. Highly doped films had good electrical stability, retaining high microwave reflectivity throughout the aging period. Lightly doped films were less stable and partially reflective and absorptive of microwaves. FT-IR spectral observations revealed a progressive increase in intensity of an unsaturated conjugated carbonyl peak, which was not observed in the highly doped films, suggesting that the concentration of the dopant had an influence on mechanism of degradation of conductivity.

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Lasing Characteristics of Dye-Doped Cholesteric Liquid Crystal

  • Porov, Preeti;Chandel, Vishal Singh;Manohar, Rajiv
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.3
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    • pp.117-123
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    • 2015
  • Cholesteric liquid crystals are one dimensional photonic band-gap materials due to their birefringence and periodic structure. Dye doped cholesteric liquid crystals are self-assembling, mirror-less, low threshold laser structures that exhibit distributed feedback. In this review paper, we have presented the development in the field of lasing characteristics of dye doped cholesteric liquid crystals.

Evaluation of Advanced Oxidation Processes by Catalytic Ozonation with Mn-doped GAC (망간담지촉매를 이용한 오존/촉매 고급산화공정 평가)

  • Song, Seung-Ju;Oh, Byung-Soo;Na, Seung-Jin;Lee, Eung-Taek;Kang, Joon-Wun
    • Journal of Korean Society on Water Environment
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    • v.20 no.2
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    • pp.176-182
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    • 2004
  • The purpose of this study was to investigate the heterogeneous catalytic ozonation of oxalic acid by manganese (Mn) doped-granular activated carbon (GAC). In order to observe the effect of the amount of Mn doped on GAC, catalysts were manufactured by varying the impregnated Mn concentration. In this paper, the following had labeled all sorts kinds of Mn-doped GAC were labeled with suitable names according to the amount (mM) of the concentration of dipping solution: They were each named as 'Mn20', 'Mn50', 'Mn100' and 'Mn200'. These experiments were performed in a batch reactor (0.5 L) and a semi-batch reactor (1 L) and Mn-free GAC was used as a blank catalyst. The ozone decay properties of each manufactured catalyst were firstly investigated to find out the reactivity between the aqueous ozone and the catalysts. Oxalic acid removal by catalytic ozonation was then performed to demonstrate the oxidative efficiencies of each catalyst.

Microstructure and Electrical Properties of W-doped $\textrm{TiO}_2$ (W를 첨가한 $\textrm{TiO}_2$의 미세구조 및 전기적 성질)

  • Baek, Seung-Bong;Lee, Sun-Il;Kim, Myeong-Ho
    • Korean Journal of Materials Research
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    • v.9 no.1
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    • pp.57-64
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    • 1999
  • The electrical conductivity of TiO$_2$ doped with 0.05~1.5mol% WO$_3$ was measured in the oxygen partial pressure range of 10\ulcorner~10\ulcorner atm and temperature range of 1100~130$0^{\circ}C$ to investigate the defect types and the electrical properties. The grain size and density were increased as the liquid phase was formed by the doped WO$_3$. The secondary phase and WO$_3$peaks at the sample doped up to 4.0 mol% were not detected from the XRD results. The data(log$\sigma$/logPo$_2$) over 110$0^{\circ}C$ were divided into the four regions. From these experimental results, we proposed the following defect regions. 1) Magneli phase(extended defect), 2) Reduced rutile region which is similar to the behavior of undoped rutile, 3) Nearly stoichiometric Ti\ulcornerW\ulcornerO$_2$region in which extra charge of W\ulcorner cation is expected to be compensated by an electron, 4) Overstoichiometric Ti\ulcornerW\ulcornerO\ulcorner region which is a metal deficiency not to be observed in pure TiO$_2$. The electrical conductivity of w-doped TiO$_2$ was influenced by the measuring temperature, oxygen partial pressure, and the dopig content.

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WOx Doped TiO2 Photocatalyst Nano Powder Produced by Sonochemistry Method (초음파 화학 반응을 이용한 WOx 도핑 TiO2 광촉매 나노 분말의 합성)

  • Cho, Sung-Hun;Lee, Soo-Wohn
    • Korean Journal of Materials Research
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    • v.21 no.2
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    • pp.83-88
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    • 2011
  • Nano-technology is a super microscopic technology to deal with structures of 100 nm or smaller. This technology also involves the developing of $TiO_2$ materials or $TiO_2$ devices within that size. The aim of the present paper is to synthesize $WO_x$ doped nano-$TiO_2$ by the Sonochemistry method and to evaluate the effect of different percentages (0.5-5 wt%) of tungsten oxide load on $TiO_2$ in methylene blue (MB) elimination. The samples were characterized using such different techniques as X-ray diffraction (XRD), TEM, SEM, and UV-VIS absorption spectra. The photo-catalytic activity of tungsten oxide doped $TiO_2$ was evaluated through the elimination of methylene blue using UV-irradiation (315-400nm). The best result was found with 5 wt% $WO_x$ doped $TiO_2$. It has been confirmed that $WO_x-TiO_2$ could be excited by visible light (E<3.2 eV) and that the recombination rate of electrons/holes in $WO_x-TiO_2$ declined due to the existence of $WO_x$ doped in $TiO_2$.

Preparation of Ta-doped $TiO_2$ thin rums by co-sputtering and their photo-electrode properties (동시스퍼터법에 의한 Ta 도핑된 $TiO_2$ 박박 합성과 광전극 특성)

  • Yoon, Jong-Won
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.4
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    • pp.165-168
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    • 2008
  • Ta-doped thin films were deposited on quartz and indium-tin oxide glass substrates using a co-sputtering method. The Ta-doped films formed a solid solution that induced structural changes from rutile to anatase phase. The anodic photocurrents of the Ta-doped $TiO_2$ electrodes were observed not only in UV but also in the visible light range. The photocurrent response in visible light on Ta-doped $TiO_2$ films are due to bandgap reduction.

Preparation of 20mol% Gd-doped $CeO_2$ Electrolyte for the Low-Temperature Solid Oxide Fuel Cells (저온형 고체산화물 연료전지를 위한 20mo1% Gd-doped $CeO_2$ 전해질의 제조에 관한 연구)

  • Kim, Sun-Jae;Hwang, Jong-Sun
    • Proceedings of the KIEE Conference
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    • 1997.11a
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    • pp.305-307
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    • 1997
  • Gd-doped $CeO_2$, ultrafine powders were synthesized by the glycine-nitrate process and then their sintering and electrical characteristics were analysed using the dilatometric and AC impedance measurements. In the dilatometric measurements green bodies from the synthesized powders after milling shrinked to about $1470^{\circ}C$ in appearance and then expanded thermally with the increase of the heating temperature, whereas those from the synthesized powders before milling continuously shrinked to the temperatures of $1600^{\circ}C$. It may be due to the change of the packing density of the synthesized powders by milling. In the AC impedance measurements, the electrical resistivity of the Gd-doped $CeO_2$ bodies from the as-milled powders, sintered at $1500^{\circ}C$ with the increase of the sintering time, showed the minimum value at the sintering time of 10h. The minimum total resistivity of the Gd-doped $CeO_2$ bodies sintered at $1500^{\circ}C$ for 10h seems to result from the lowest activation energy by the combination between the activation energies for the resistivities at the grain interior and grain boundary.

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Synthesis and Characterization of a Ceria Based Composite Electrolyte for Solid Oxide Fuel Cells by an Ultrasonic Spray Pyrolysis Process (초음파분무 열분해법을 이용한 고체산화물 연료전지용 세리아계 복합체 전해질의 제조 및 특성)

  • Lee, Young-In;Choa, Yong-Ho
    • Journal of Powder Materials
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    • v.21 no.3
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    • pp.222-228
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    • 2014
  • Much research into fuel cells operating at a temperature below $800^{\circ}C$. is being performed. There are significant efforts to replace the yttria-stabilized zirconia electrolyte with a doped ceria electrolyte that has high ionic conductivity even at a lower temperature. Even if the doped ceria electrolyte has high ionic conductivity, it also shows high electronic conductivity in a reducing environment, therefore, when used as a solid electrolyte of a fuel cell, the powergeneration efficiency and mechanical properties of the fuel cell may be degraded. In this study, gadolinium-doped ceria nanopowder with $Al_2O_3$ and $Mn_2O_3$ as a reinforcing and electron trapping agents were synthesized by ultrasonic pyrolysis process. After firing, their microstructure and mechanical and electrical properties were investigated and compared with those of pure gadolinium-doped ceria specimen.

Effect of Microwave Irradiation on Morphology and Size of Anatase Nano Powder: Efficient Photodegradation of 4-Nitrophenol by W-doped Titania

  • Shojaei, Abdollah Fallah;Loghmani, Mohammad Hassan
    • Bulletin of the Korean Chemical Society
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    • v.33 no.12
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    • pp.3981-3986
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    • 2012
  • Anatase nanocrystalline and its tungsten-doped (0.4, 2, and 4 mol %) powders have been synthesized by microwave irradiation through hydrolysis of titanium tetra-isopropoxide (TIP) in aqueous solution. The materials are characterized by XRD, Raman, SEM-EDX, TEM, FT-IR and UV-vis techniques. The nanocrystalline $TiO_2$ particles are 30 nm in nature and doping of tungsten ion decreases their size. As seen in TEM images, the crystallites of W (4 mol %) doped $TiO_2$ are small with a size of about 10 nm. The photocatalytic activity was tested on the degradation of 4-nitrophenol (4-NP). Catalytic activities of W-doped and pure $TiO_2$ were also compared. The results show that the photocatalytic activity of the W-doped $TiO_2$ photocatalyst is much higher than that of pure $TiO_2$. Degradation decreases from 96 to 50%, during 115 min, when the initial 4-NP concentration increases from 10 to 120 ppm. Maximum degradation was obtained at 35 mg of photocatalyst.