• Title/Summary/Keyword: In Situ Degradation

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Airborne Fine Particle Measurement Data Analysis and Statistical Significance Analysis (공기중 미세입자 측정 데이터 분석 및 통계 유의차 분석)

  • Sung Jun An;Moon Suk Hwan
    • Journal of the Semiconductor & Display Technology
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    • v.22 no.1
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    • pp.1-5
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    • 2023
  • Most of the production process is performed in a cleanroom in the case of facilities that produce semiconductor chips or display panels. Therefore, environmental management of cleanrooms is very important for product yield and quality control. Among them, airborne particles are a representative management item enough to be the standard for the actual cleanroom rating, and it is a part of the Fab or Facility monitoring system, and the sequential particle monitoring system is mainly used. However, this method has a problem in that measurement efficiency decreases as the length of the sampling tube increases. In addition, a statistically significant test of deterioration in efficiency has rarely been performed. Therefore, in this study, the statistically significant test between the number of particles measured by InSitu and the number of particles measured for each sampling tube ends(Remote). Through this, the efficiency degradation problem of the sequential particle monitoring system was confirmed by a statistical method.

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In situ isolation and characterization of the biosurfactants of B. Subtilis

  • Akthar, Wasim S.;Aadham, Mohamed Sheik;Nisha, Arif S.
    • Advances in environmental research
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    • v.9 no.3
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    • pp.215-232
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    • 2020
  • Crude oils are essential source of energy. It is majorly found in geographical locations beneath the earth's surface and crude oil is the main factor for the economic developments in the world. Natural crude oil contains unrefined petroleum composed of hydrocarbons of various molecular weights and it contains other organic materials like aromatic compounds, sulphur compounds, and many other organic compounds. These hydrocarbons are rapidly getting degraded by biosurfactant producing microorganisms. The present study deals with the isolation, purification, and characterization of biosurfactant producing microorganism from oil-contaminated soil. The ability of the microorganism producing biosurfactant was investigated by well diffusion method, drop collapse test, emulsification test, oil displacement activity, and blue agar plate method. The isolate obtained from the oil contaminated soil was identified as Bacillus subtilis. The identification was done by microscopic examinations and further characterization was done by Biochemical tests and 16SrRNA gene sequencing. Purification of the biosurfactant was performed by simple liquid-liquid extraction, and characterization of extracted biosurfactants was done using Fourier transform infrared spectroscopy (FTIR). The degradation of crude oil upon treatment with the partially purified biosurfactant was analyzed by FTIR spectroscopy and Gas-chromatography mass spectroscopy (GC-MS).

Localization of Germin Genes and Their Products in Developing Wheat Coleoptiles

  • Caliskan, Mahmut;Ozcan, Birgul;Turan, Cemal;Cuming, Andrew C.
    • BMB Reports
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    • v.37 no.3
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    • pp.339-342
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    • 2004
  • Germination is a process which characterized with nescient synthesis of genes. Among the genes synthesized during the germination of wheat embryos, germin genes, proteins and their enzymatic activity were defined. Germin is a water soluble homopentameric glycoprotein which is remarkable resistant to degradation by a broad range of proteases including pepsin. Germin proteins found to have strong oxalate oxidase activity which produces hydrogen peroxide by degrading oxalic acid. The current study, aimed to localize the germin genes, proteins and enzymatic activities in developing coleoptiles which is a rapidly growing protective tissue of leaf primordium and shoot apex. Non-radioactively abeled germin riboprobes were employed to localize germin mRNAs in situ. FITC (Fluorescein isothiocyanate) and alkaline phosphatase linked anti-germin antibodies were used to localize germin proteins under the fluorescence and light microscopy and finally germin enzymatic activity was localized by using appropriate enzyme assay. The results revealed that in coleoptiles germin genes, proteins and their enzymatic activity were predominantly associated with the cells of epidermis and vascular bundle sheath cells.

High Electrical Current Stressing Effects on the Failure Mechanisms of Austudbumps/ACFFlip Chip Joints (고전류 스트레싱이 금스터드 범프를 이용한 ACF 플립칩 파괴 기구에 미치는 영향)

  • Kim Hyeong Jun;Gwon Un Seong;Baek Gyeong Uk
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2003.11a
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    • pp.195-202
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    • 2003
  • In this study, failure mechanisms of Au stud bumps/ACF flip chip joints were investigated underhigh current stressing condition. For the determination of allowable currents, I-V tests were performed on flip chip joints, and applied currents were measured as high as almost 4.2Amps $(4.42\times10^4\;Amp/cm^2)$. Degradation of flip chip joints was observed by in-situ monitoring of Au stud bumps-Al pads contact resistance. All failures, defined at infinite resistance, occurred at upward electron flow (from PCB pads to chip pads) applied bumps (UEB). However, failure did not occur at downward electron flow applied bumps (DEB). Only several $m\Omega$ contact resistance increased because of Au-Al intermetallic compound (IMC) growth. This polarity effect of Au stud bumps was different from that of solder bumps, and the mechanism was investigated by the calculation of chemical and electrical atomic flux. According to SEM and EDS results, major IMC phase was $Au_5Al_2$, and crack propagated along the interface between Au stud bump and IMC resulting in electrical failures at UEB. Therefore. failure mechanisms at Au stud bump/ACF flip chip Joint undo high current density condition are: 1) crack propagation, accompanied with Au-Al IMC growth. reduces contact area resulting in contact resistance increase; and 2) the polarity effect, depending on the direction of electrons. induces and accelerates the interfacial failure at UEBs.

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Solar Wind Observations Using STELab-IPS Array In Japan

  • Fujiki, Ken'ichi;Tokumaru, Munetoshi;Iju, Tomoya;Hirota, Maria;Noda, Momotaro;Kojima, Masayoshi
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.2
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    • pp.93.1-93.1
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    • 2011
  • Radio wave from a compact radio source such as a quasar are scattered by irregularities of electron density. The scattered waves interfere with each other as they propagate to the Earth producing diffraction patterns on the ground. This phenomenon is called interplanetary scintillation (IPS). The IPS pattern contains the information of solar wind velocities and density fluctuations passing across a line-of-sight (LOS) from an observer to a radio source. The IPS is a useful tool which allows us to measure the solar wind in three dimensional space inaccessible to in situ observations. Although the IPS measurement is an integral of solar wind velocities and density fluctuations along the LOS, which causes degradation of accuracy, we have succeeded to develop computer assisted tomography (CAT) analysis to remove the effect of LOS integration. These techniques greatly improved the accuracy of determinations of solar wind velocity structures. In this talk we present our IPS observation system and long-term variation of global solar wind structures from 1980-2009, then we focus on recent peculiar solar wind properties.

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Isolation and Characterization of Psychrotrophic and Halotolerant Rhodococcus sp. YHLT-2

  • Ryu Hee-Wook;Joo Yang-Hee;An Youn-Joo;Cho Kyung-Suk
    • Journal of Microbiology and Biotechnology
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    • v.16 no.4
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    • pp.605-612
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    • 2006
  • A psychrotrophic bacterium was isolated from oil-contaminated groundwater and identified as Rhodococcus sp. YHLT-2. Growth was observed at the temperature of 4 to $30^{\circ}C$. This strain degraded various petroleum hydrocarbons such as crude oil, diesel oil, and gasoline over the whole range of temperatures tested. The Rhodococcus sp. YHLT-2 was capable of growing even at $4^{\circ}C$, exhibiting 90% of oil biodegradation after 20 days. Degradation of crude oil occurred at low temperature in nature. This strain was also able to grow at 7% NaCl, and utilized not only short chain alkenes $(C_9\;to\;C_{12})$, but also a broad range of long chain alkenes $(C_{19}\;to\;C_{32})$ present in crude oil at $4^{\circ}C$. The Rhodococcus sp. YHLT-2 is expected to be of potential use in the in situ bioremediation of hazardous hydrocarbons under low-temperature and high-salt conditions.

A Study on Anaerobic Biodegradation of MTBE and BTEX by Indigenous Microorganisms (토착 미생물을 이용한 MTBE와 BTEX의 혐기성 생분해 연구)

  • Chung, Woo-Jin;Chang, Soon-Woong
    • Journal of Soil and Groundwater Environment
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    • v.21 no.3
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    • pp.88-94
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    • 2016
  • The simultaneous biodegradation between MTBE (Gasoline additives) and BTEX (Benzene, Toluene, Ethyl-benzene, o-Xylene, m-Xylene, p-Xylene) was achieved within a competitive inter-relationship, with not only electron accepters such as nitrate, sulfate, and iron(III) without oxygen, but also with electron donors such as MTBE and BTEX. Preexisting indigenous microorganisms from a domestic sample of gasoline contaminated soil was used for a lab-scale batch test. The result of the test showed that the biodegradation rate of MTBE decreased when there was co-existing MTBE and BTEX, compared to having just MTBE present. The growth of indigenous microorganisms was not affected in the case of the MTBE treatment, whereas the growth of the microorganisms was decreased in combined MTBE and BTEX sample. This may indicate that an inhibitor related to biodegradation when BTEX and MTBE are mixed will be found. This inhibitor may be found to retard the anaerobic conditions needed for efficient breakdown of these complex carbon chain molecules in-situ. Moreover, it is also possible that an unknown competitive reaction is being imposed on the interactions between MTBE and BTEX dependent on conditions, ratios of mixture, etc.

Application of in situ Liquid Ferrate(VI) for 2-Bromophenol Removal (2-브로모페놀 제거를 위한 액상 페레이트 적용 연구)

  • Laksono, Fajar Budi;Kim, Il-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.29 no.6
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    • pp.685-692
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    • 2015
  • The concern over the risk of environmental exposure to brominated phenols has been increased and has led the researchers to focus their attention on the study of bromophenol treatment. In this study, the effects of pH and ferrate(VI) dose on the degradation of 2-bromophenol were investigated. The results indicated that the oxidation of 2-bromophenol by liquid ferrate(VI) was found to be highly sensitive to the pH condition. Furthermore, the highest removal efficiency was observed at the neutral condition with the removal efficiency of 94.2%. In addition, experimental results showed that 2-bromophenol removal efficiency increased with increasing of ferrate dosage. Ferrate(VI) dose of 0.23 mM was sufficient to remove most of the 2-bromophenol with the efficiency of 99.73% and kapp value of $2982M^{-1}s^{-1}$. Seven compounds were identified as the intermediate products by the GC/MS analysis.

The Electric and Ferroelectric of Pb(Zr0.52Ti0.48)O3 Thin Films Deposited on Ruthenium Electrodes (루테늄 전극위에 증착된 PZT 박막의 전기적 및 강유전 특성)

  • Hwang, Hyun Suk;Yu, Yougn Sik;Lim, Yun-Sik;Kang, Hyun-Il
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.63 no.1
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    • pp.46-49
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    • 2014
  • $Pb(Zr_{0.52}Ti_{0.48})O_3(PZT)$ thin films deposited on $Ru/RuO_2$ bottom electrode that grown for in-situ progress used rf magnetron sputtering method. We investigated the dependence of the crystalline and electrical properties in the way of capacitors PZT thin films. Our results show that all PZT films indicated polycrystalline perovskite structure with preferred orientation (110) and no pyrochlore phase is observed. The electric properties of the Ru improved with increasing Ru thin films thickness. A well-fabricated Ru/PZT/Ru (100 nm) /$RuO_2$ capacitor showed a leakage current density in the order of $2.03{\times}10^{-7}$ $A/cm^2$ as a 50 kV/cm, a remnant polarization (Pr) of 9.22 ${\mu}C/cm^2$, and a coercive field (-EC) of -32.22 kV/cm. The results show that $Ru/Ru/RuO_2$ bottom electrodes are expected to reduce the degradation ferroelectric fatigue and excellent ferroelectric properties.

Preparation of AgCl/Ag3PO4/Diatomite Composite by Microemulsion Method for Rapid Photo-Degradation of Rhodamine B with Stability under Visible Light

  • Zhu, Hai-Tao;Ren, Qi-Fang;Jin, Zhen;Ding, Yi;Liu, Xin-Yu;Ni, Xi-Hui;Han, Meng-Li;Ma, Shi-Yu;Ye, Qing;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.30 no.8
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    • pp.383-392
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    • 2020
  • In this paper, AgCl/Ag3PO4/diatomite photocatalyst is successfully synthesized by microemulsion method and anion in situ substitution method. X-ray diffraction (XRD), photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM), and ultraviolet-visible spectroscopy (UV-Vis) are used to study the structural and physicochemical characteristics of the AgCl/Ag3PO4/diatomite composite. Using rhodamine B (RhB) as a simulated pollutant, the photocatalytic activity and stability of the AgCl/Ag3PO4/diatomite composite under visible light are evaluated. In the AgCl/Ag3PO4/diatomite visible light system, RhB is nearly 100 % degraded within 15 minutes. And, after five cycles of operation, the photocatalytic activity of AgCl/Ag3PO4/diatomite remains at 95 % of the original level, much higher than that of pure Ag3PO4 (40 %). In addition, the mechanism of enhanced catalytic performance is discussed. The high photocatalytic performance of AgCl/Ag3PO4/diatomite composites can be attributed to the synergistic effect of Ag3PO4, diatomite and AgCl nanoparticles. Free radical trapping experiments are used to show that holes and oxygen are the main active species. This material can quickly react with dye molecules adsorbed on the surface of diatomite to degrade RhB dye to CO2 and H2O. Even more remarkably, AgCl/Ag3PO4/diatomite can maintain above 95 % photo-degradation activity after five cycles.