• Title/Summary/Keyword: In(III)

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Polarograms of Uranium(VI) and Rare Earth(III) Metal Complexes with Macrocyclic Ligands in Dimethylsulfoxide Solvent (디메틸술폭시드 용매중에서 거대고리리간드를 포함한 우라늄(VI)과 희토류(III) 금속 착물의 폴라로그램)

  • Hak Jin Jung;Oh Jin Jung;Chilnam Choi
    • Journal of the Korean Chemical Society
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    • v.32 no.3
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    • pp.233-242
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    • 1988
  • The uranium(VI) complexes with new unsaturated macrocyclic ligands of cryptand types and the neodymium(III) complexes with cryptand 222 and DBC ligands have been investigated polarographically in dimethylsulfoxide solvent. The reduction states, electron numbers involved in the reduction process, effects of the added acid on the polarograms of complexes, and the mechanisms of the reduction electrode reactions have been examined. The stability constants and mole-ratio of new complexes were also obtained by polarographic method. The reaction of ligands was controlled by the diffusion in the reduction with four electrons at a step, whereas the redox reaction with six electrons at three steps in $UO_2\;^{2+}$ complexes with macrocyclic ligands and the redox reaction with one electron at a step in $Nd^{3+}$ complexes with cryptand 222 and DBC have been observed. The imine ligands formed stable complexes with uranium(VI) above pH 7.0, and the neodymium(III) complexes with cryptand 222 and DBC ligands were stable above pH 4.0.

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Search Design of Resolution III.2 for $3^n,n=4,5,6^+$

  • Um, Jung-Koog
    • Journal of the Korean Statistical Society
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    • v.17 no.2
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    • pp.134-145
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    • 1988
  • The basic conditions for a parallel-flats fraction to be a search design of Resolution III.2 have been developed in Um (1980, 1981, 1983, 1984). In this paper, a series of resolution III.2 search designs for $3^n, n=4, 5, 6$, are presented.

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Minimum presurgical orthodontic treatment: The influence of the postsurgial occlusal stability on postsurgical mandibular changes in class III malocclusion (임상가를 위한 특집 2 - 최소술전교정: 수술교합의 안정성이 술후 하악골 위치변화에 미치는 영향)

  • Kim, Byoung-Ho
    • The Journal of the Korean dental association
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    • v.50 no.2
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    • pp.64-71
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    • 2012
  • Recently, the presurgical orthodontic duration tends to be shortened by virtue of the advancement of surgical and orthodontic techniques in class III orthognathic surgery cases. But the predictability of the surgical results should be secured by removing several uncertain factors in presurgical orthodontic treatment. The purpose of this study is to investigate the influence of immediate postsurgical occlusal stability on postsurgical mandibular change. The study includes 40 patients who underwent orthognathic surgery to correct skeletal class III malocclusion. The patients were divided into two groups based on the numbers of occlusal contact in surgical setup occlusion: group 1 (stable surgical occlusion, n=24) and group 2(unstable surgical occlusion, n=16). Changes of horizontal and vertical mandibular measurements during postsurgical follow up period(from 1 week postsurgery to 12month after debonding) were compared to examine the differences between two groups. The stability of surgical occlusion is one of the factors influencing postsurgical mandibular changes in class III malocclusion. The various class III malocclusion cases have specific prerequisites for the orthognathic surgery according to the skeletal patterns. The prerequisites should be obtained by minimum presurgical orthodontics to increase the predictability of the surgical results.

Effects of CETP gena polymorphisms on atherogenic lipoprotein phenotypes in Koreans

  • Cho, Hong-Keun;Yangsoo Jang;Cho, Eun-Young;Park, Hyun-Young;Lee, Hakbae;Lee, Jong-Eun
    • Nutritional Sciences
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    • v.6 no.2
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    • pp.100-105
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    • 2003
  • Small dense LDL(LDL III) is emerging as a major risk factor for coronary artery disease. LDL III generation is associated with high triglyceride concentration, high hepatic lipase activity, and high cholesterol ester transfer protein (CETP) levels. CETP polymorphisms have been reported to be associated with coronary artery disease. In this study, we investigated the relationship between CETP polymorphism and LDL III generation. VLDL1, VLDL2, IDL and LDL subfractions were measured in 87 normal healthy Korean subjects who had been SNP genotyped for Taq1B, I405v and A629C. We found no differences in LDL subfractions and lipoprotein composition between homozygotes for Taq1B2B2, and those for Taq1B1B1 and Taq1B1B2. There were no differences in LDL subfractions and lipoprotein composition between homozygotes for 629AA, and those for 629AC and -629CC. However, homozygotes for 405VV had a significantly lower LDL III concentration and proportion than those for 405II and 405IV. We concluded that, among the Taq1B, I405V and A629C polymorphisms, only the 1405V polymorphism was associated with the concentration and proportion of LDL III.

Interhospital Comparison of Outcome from Intensive Care Unit with APACH III Scoring System (APACHE III 시스템을 이용한 병원간 중환자실 치료결과 비교분석)

  • Lee, Duk-Hee;No, Mee-Young;Kim, Byung-Sung
    • Journal of Preventive Medicine and Public Health
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    • v.27 no.3 s.47
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    • pp.437-445
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    • 1994
  • The objective of this study was to evaluate outcome for the patients of the intensive care unit, using APACHE III prognostic system. We prospectively collected the information of 429 patients in intensive care units at 2 tertiary care hospitals and 4 secondary care hospitals in PUSAN who had been admitted from December 1, 1993 to February 28, 1994. The results were as follows. 1. APACHE III scores were various from 0 to 173. But the distribution of the scores were similar between tertiary care hospitals and secondary care hospitals. 2. The mortality rate significantly increased as APACHE III score rised (p<0.001). Within the interval of same score, generally, the mortality of operative patients was higher in secondary care hospitals but in the case of nonoperative patients higher in tertiary care hospitals. 3. When the tertiary care hospitals compared with secondary for ratio of the predicted mortality rate to the actual mortality rate, there was little difference. 4. When we compared the 6 hospitals, one hospital had significantly better results and another hospital was significantly inferior (p<0.05).

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Multilayer Neural Network Using Delta Rule: Recognitron III (텔타규칙을 이용한 다단계 신경회로망 컴퓨터:Recognitron III)

  • 김춘석;박충규;이기한;황희영
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.40 no.2
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    • pp.224-233
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    • 1991
  • The multilayer expanson of single layer NN (Neural Network) was needed to solve the linear seperability problem as shown by the classic example using the XOR function. The EBP (Error Back Propagation ) learning rule is often used in multilayer Neural Networks, but it is not without its faults: 1)D.Rimmelhart expanded the Delta Rule but there is a problem in obtaining Ca from the linear combination of the Weight matrix N between the hidden layer and the output layer and H, wich is the result of another linear combination between the input pattern and the Weight matrix M between the input layer and the hidden layer. 2) Even if using the difference between Ca and Da to adjust the values of the Weight matrix N between the hidden layer and the output layer may be valid is correct, but using the same value to adjust the Weight matrixd M between the input layer and the hidden layer is wrong. Recognitron III was proposed to solve these faults. According to simulation results, since Recognitron III does not learn the three layer NN itself, but divides it into several single layer NNs and learns these with learning patterns, the learning time is 32.5 to 72.2 time faster than EBP NN one. The number of patterns learned in a EBP NN with n input and output cells and n+1 hidden cells are 2**n, but n in Recognitron III of the same size. [5] In the case of pattern generalization, however, EBP NN is less than Recognitron III.

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AN AXIOMATIC DESIGN APPROACH OF NANOFLUID-ENGINEERED NUCLEAR SAFETY FEATURES FOR GENERATION III+ REACTORS

  • Bang, In-Cheol;Heo, Gyun-Young;Jeong, Yong-Hoon;Heo, Sun
    • Nuclear Engineering and Technology
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    • v.41 no.9
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    • pp.1157-1170
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    • 2009
  • A variety of Generation III/III+ reactor designs featuring enhanced safety and improved economics are being proposed by nuclear power industries around the world to solve the future energy supply shortfall. Nanofluid coolants showing an improved thermal performance are being considered as a new key technology to secure nuclear safety and economics. However, it should be noted that there is a lack of comprehensible design works to apply nanofluids to Generation III+ reactor designs. In this work, the review of accident scenarios that consider expected nanofluid mechanisms is carried out to seek detailed application spots. The Axiomatic Design (AD) theory is then applied to systemize the design of nanofluid-engineered nuclear safety systems such as Emergency Core Cooling System (ECCS) and External Reactor Vessel Cooling System (ERVCS). The various couplings between Gen-III/III+ nuclear safety features and nanofluids are investigated and they try to be reduced from the perspective of the AD in terms of prevention/mitigation of severe accidents. This study contributes to the establishment of a standard communication protocol in the design of nanofluid-engineered nuclear safety systems.

Spectroscopic Characterization of Aqueous and Colloidal Am(III)-CO3 Complexes for Monitoring Species Evolution

  • Hee-Kyung Kim
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.20 no.4
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    • pp.371-382
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    • 2022
  • Carbonates are inorganic ligands that are abundant in natural groundwater. They strongly influence radionuclide mobility by forming strong complexes, thereby increasing solubility and reducing soil absorption rates. We characterized the spectroscopic properties of Am(III)-carbonate species using UV-Vis absorption and time-resolved laser-induced fluorescence spectroscopy. The deconvoluted absorption spectra of aqueous Am(CO3)2- and Am(CO3)33- species were identified at red-shifted positions with lower molar absorption coefficients compared to the absorption spectrum of aqua Am3+. The luminescence spectrum of Am(CO3)33- was red-shifted from 688 nm for Am3+ to 695 nm with enhanced intensity and an extended lifetime. Colloidal Am(III)-carbonate compounds exhibited absorption at approximately 506 nm but had non-luminescent properties. Slow formation of colloidal particles was monitored based on the absorption spectral changes over the sample aging time. The experimental results showed that the solubility of Am(III) in carbonate solutions was higher than the predicted values from the thermodynamic constants in OECD-NEA reviews. These results emphasize the importance of kinetic parameters as well as thermodynamic constants to predict radionuclide migration. The identified spectroscopic properties of Am(III)-carbonate species enable monitoring time-dependent species evolution in addition to determining the thermodynamics of Am(III) in carbonate systems.

Stability Rating of KSR-III Rocket Engine (KSR-III 로켓엔진의 연소 안정성 평가)

  • Sohn, Chae-Hoon;Kim, Young-Mog
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.32 no.3
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    • pp.95-101
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    • 2004
  • Stability rating of KSR-III rocket engine is conducted based on stability rating tests in the course of development of KSR-III rocket engine. Rocket engine is approved to have combustion stabilization ability when it can suppress the external perturbation or pressure oscillation with finite amplitude and recover the original stable combustion. Rocket engine in flight may be perturbed by unexpectedly large-amplitude pressure oscillation and thus a designer should not only assure combustion stabilization ability of the engine but also quantify the stabilization capacity. For this, principal quantitative parameters and their evaluation are introduced. To verify dynamic stability of KSR-III rocket engine, six stability rating tests have been conducted. Based on these test results, such parameters are quantified and thereby, the stabilization capacity of KSR-III rocket engine is evaluated.

Comparison of Fe(III) Coagulants and their Characterization for Water Treatment (수처리용 Fe(III)계 응집제의 특성 및 응집특성 비교)

  • Han, Seung Woo;Kang, Lim Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.4
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    • pp.169-176
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    • 2016
  • This research explored the feasibility of preparing and utilizing preformed polymeric solution of Fe(III) as coagulants for water treatment. The differentiation and quantification of hydrolytic Fe(III) species in coagulant was done by utilizing spectrophotometric method based on the interaction of Fe(III) with Ferron as a complexing agent. The properties of the synthesized polymeric iron chloride (PICl) showed that the quantity of polymeric Fe(III) produced at r = 1.5 was 20% of the total iron in solution, as showing maximum contents. Coagulation experiments were conducted under the condition of various coagulant doses and pH for each coagulant prepared. From the comparison of the characterization of coagulation for $FeCl_3$ (r = 0.0) and PICl (r = 0.5, 1.0, 1.5) coagulants, PICl (r = 0.5, 1.0, 1.5) coagulants was found to be more effective than other coagulant for the removal of organic matters. The experimental results for the coagulation tests at various pH ranges showed that the PICl was least affected by the coagulation pH and PICl was very effective for the removal of turbidity and organic materials over wide pH range (pH 4-9) tested.