• 제목/요약/키워드: Impurity concentration

검색결과 156건 처리시간 0.026초

Systematic Analysis for the Effects of Atmospheric Pollutants in Cathode Feed on the Performance of Proton Exchange Membrane Fuel Cells

  • Yoon, Young-Gon;Choi, Insoo;Lee, Chang-Ha;Han, Jonghee;Kim, Hyoung-Juhn;Cho, EunAe;Yoo, Sung Jong;Nam, Suk Woo;Lim, Tae-Hoon;Yoon, Jong Jin;Park, Sehkyu;Jang, Jong Hyun
    • Bulletin of the Korean Chemical Society
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    • 제35권12호
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    • pp.3475-3481
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    • 2014
  • This paper describes how primary contaminants in ambient air affect the performance of the cathode in fuel cell electric vehicle applications. The effect of four atmospheric pollutants ($SO_2$, $NH_3$, $NO_2$, and CO) on cathode performance was investigated by air impurity injection and recovery test under load. Electrochemical analysis via polarization and electrochemical impedance spectroscopy was performed for various concentrations of contaminants during the impurity test in order to determine the origins of performance decay. The variation in cell voltage derived empirically in this study and data reported in the literature were normalized and juxtaposed to elucidate the relationship between impurity concentration and performance. Mechanisms of cathode degradation by air impurities were discussed in light of the findings.

Salt and Sand Transport from Aral Sea Basin

  • 이귀주
    • 한국해양공학회지
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    • 제19권3호
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    • pp.47-53
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    • 2005
  • Model for dust and salt transportation from the dried bottom of the Aral Sea is suggested. Theoretical analysis is based on the turbulent diffusion equation for the averaged function of passive impurity concentration. One-layer model of the atmospheric boundary layer is assumed. Impurity precipitation rates are calculated as the functions of the particle size and the distance source of particles. Analytical solutions for the point and two-dimensional sources of impurities are found. Model calculations for salt and sand transport from the Aral Sea basin are made on the basis of 2D source model with a constant intensity.

유리 기판을 이용한 비정질 실라콘 박막의 결정화 (Laser Induced Crystallizatioo of Amorphous Si Films on Glass Substrates)

  • 김필규;문승재;정성호
    • 한국레이저가공학회지
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    • 제13권1호
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    • pp.6-10
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    • 2010
  • Crystallization of 100 nm thick amorphous silicon (a-Si) films on glass substrates was carried out by using a double laser irradiation method. Depending on a-Si deposition method or glass types, the quality of crystallized silicon film varies significantly. For a-Si films deposited with high concentration of impurities, large grains or high crystallinity can not be achieved. Crystallization with different a-Si deposition methods confirmed that for the polycrystallization of a-Si films on glass substrates, controlling the impurity density during substrate preparation is critical.

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고분자전해질 연료전지 연료극의 일산화탄소 및 황화수소 농도에 따른 불순물영향에 관한 연구 (A Study on Hydrogen Impurity Effect in Anode of Proton Exchange Membrane Fuel Cell on Various Concentration of CO and H2S)

  • 이은경;백재훈;이정운;이승국;이연재
    • 한국수소및신에너지학회논문집
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    • 제27권6호
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    • pp.670-676
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    • 2016
  • Hydrogen town in Republic of Korea was established in 2013. Hydrogen as a byproduct produced by various processes of factories is used in hydrogen town facilities. As cell performance is affected by contaminations in fuel gas, various standards about impurities of fuel have been determined by many countries. This study shows performance degradation of single cell with impurities concentrations. Traces of carbon monoxide (CO) and hydrogen sulfide ($H_2S$)can cause considerable cell performance losses. For comparing the performances by poisoning of CO, acceleration test, I-V curve, constant current are performed. Both the CO and $H_2S$ poisoning rate are a function of their concentration. With the higher concentrations the higher poisoning rates are observed. And, it was confirmed that, oxidation behavior and side reaction generation are not affected. Under the lower $H_2S$ concentration condition, the poisoning rate is much higher than that of CO because of its different adsorption intensity. It can be possible that the result of this study can be used for enacting regulation as a baseline data.

YBCO의 특성분석에 있어서 불순물효과의 보정 (Correction of lmpurity Effects on the Characterization of YBCO)

  • 하동한;변순예;김용일;한기열;이규원
    • 한국초전도학회:학술대회논문집
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    • 한국초전도학회 1999년도 High Temperature Superconductivity Vol.IX
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    • pp.171-174
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    • 1999
  • We have characterized solid solution Y$_{l-x}Ca_xBa_2Cu_3O_y$ (0${\le}$x${\le}$0.3) materials by measuring the XRD pattern, resistivity and hole concentrations, etc. As Ca concentration increases, T$_c$, is decreased monotonically because the hole concentration on the superconducting plane increases beyond the optimum region in the electronic phase diagram due to the hole transfer from the Cu-O chain to the CuO$_2$ plane. A very small amount of secondary phase have large effects on the analysis of oxygen content and hole concentration etc. The results before the correction of impurity phase are compared with those after the correction.

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[Li]/[Nb]조성비 변화에 따른 iron-doped $LiNbO_3$ 결정의 특성분석

  • 한지웅;원종원;오근호
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1997년도 Proceedings of the 13th KACG Technical Meeting `97 Industrial Crystallization Symposium(ICS)-Doosan Resort, Chunchon, October 30-31, 1997
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    • pp.111-115
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    • 1997
  • Iron-doped LiNbO$_3$ crystals were grown by floating zone(FZ) method with different [Li]/[Nb] ratio in order to investigate doping effects of transition metal impurity in LiNbO$_3$ crystal. The grown crystals were analyized edge in UV/VIS/IR spectrometry and EPMA(electron probe micro-analysis). The absorption edge in UV-VIS region and OH-absorption peak in IR region were investigated. The change of Fe concentration along the solidification direction was also investigated

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동심원형 대칭 전기장 집속 방식을 응용한 자가 이온 보조 소스 제작 및 Cu 박막 증착 (Design of Self-ion assisted beam source (SIAB) based on electron focusing with concentric symmetrical electric field and Cu thin film growth by SIAB)

  • 송재훈;김기환;이충만;최성창;송종한;정형진;최원국
    • 한국진공학회지
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    • 제8권2호
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    • pp.121-126
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    • 1999
  • Cu thin film was deposited by a self-ion assisted beam source (SIAB) and the assessment of the Cu films was given. Some characteristics of the source and the experimental procedure are described at various conditions such as total power, ionization efficiency, and ion current vs. deposition rate. The dependence of crystalline structure, impurity concentration, and resistivity of the Cu films deposited by SIAB on acceleration voltage are discussed.

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양자역학적 원자 및 분자 분석에 의한 정공의 이동 불가능성과 운반자로써의 주도 전자에 관한 이론 (A theory on the impossibility of the moving for hle and the primary electron as a carrier using the analyses, by quantum mechanics, of the structure of atoms and molecules)

  • 주정규
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 1998년도 하계종합학술대회논문집
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    • pp.327-330
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    • 1998
  • In this theory, we explained the impossibility of the motion or miving of the hole that has been recognized to be a carrier, by giving some fundamental reasons. We treated energy gap and impurity concentration, in p- and n-type region, as functions of the mobility that is one of te factors which determine current quantity, and analyzed the primary electron theory as a carrier by introducing 2 hypotheses.

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글로우방전을 이용한 가스크로마토그라프 검출기의 개발 (Glow Discharge as Detector for Gas Chromatography)

  • 김효진;박일영;장성기;김박광;박만기
    • 약학회지
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    • 제37권1호
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    • pp.76-83
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    • 1993
  • The changes in discharge current, emission and/or oscillation frequency of the electric oscillation of a glow discharge are the potential sensitive measure of the concentration of an impurity in the argon plasma supporting gas. A single jet enhanced glow discharge has been interfaced with the gas chromatograph via 1/8" O.D. tube with a heating pad to study the changes in discharge current. To investigate the optimum operating conditions of the glow discharge system as detector for gas chromatography, pressure, gas flow rate, discharge current, distance between the anode and the cathode have been studied.

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