• Title/Summary/Keyword: Improved synthesis

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Preparation and characterization of ZnO photocatalyst and their photocatalysis

  • Lee, Sang-Deok;Nam, Sang-Hun;Jo, Sang-Jin;Bu, Jin-Hyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.292-292
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    • 2010
  • Among the semiconducting materials, ZnO has considerably attracted attention over the past few years due to the high activities in removing organic contaminants created from industry. In this work, ZnO nanoparticles were synthesized by spray pyrolysis method using the zinc acetate dihydrate as starting material at various synthesis temperatures. The structures of the synthesized ZnO were characterized by X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Brunauer, Emmett & Teller (BET), Fourier Transformation Infrared (FT-IR), and UV-vis spectroscopy. The Miller indices of XRD patterns indicate that the synthesized ZnO nanoparticles showed a hexagonal wurtzite structure. With increasing synthesis temperature, the mean diameter of ZnO nanoparticles increased, and their crystallinity was improved. Also, the photocatalytic activity of ZnO was studied by the photocatalytic degradation of methyleneblue (MB) under UV irradiation (365 nm) at room temperature. The results show that the photocatalytic efficiency of ZnO nanoparticles was enhanced by increasing synthesis temperature.

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A Study of Decision Tree Modeling for Predicting the Prosody of Corpus-based Korean Text-To-Speech Synthesis (한국어 음성합성기의 운율 예측을 위한 의사결정트리 모델에 관한 연구)

  • Kang, Sun-Mee;Kwon, Oh-Il
    • Speech Sciences
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    • v.14 no.2
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    • pp.91-103
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    • 2007
  • The purpose of this paper is to develop a model enabling to predict the prosody of Korean text-to-speech synthesis using the CART and SKES algorithms. CART prefers a prediction variable in many instances. Therefore, a partition method by F-Test was applied to CART which had reduced the number of instances by grouping phonemes. Furthermore, the quality of the text-to-speech synthesis was evaluated after applying the SKES algorithm to the same data size. For the evaluation, MOS tests were performed on 30 men and women in their twenties. Results showed that the synthesized speech was improved in a more clear and natural manner by applying the SKES algorithm.

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A STUDY ON THE SPEECH SYNTHESIS-BY-RULE SYSTEM APPLIED MULTIBAND EXCITATION SIGNAL

  • Kyung, Younjeong;Kim, Geesoon;Lee, Hwangsoo;Lee, Yanghee
    • Proceedings of the Acoustical Society of Korea Conference
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    • 1994.06a
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    • pp.1098-1103
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    • 1994
  • In this paper, we design and implement the Korean speech synthesis by rule system. This system is applied the multiband excitation signal on voiced sounds. The multiband excitation signal is obtained by mixing impluse spectrum and which noise spectrum. We find that the quality of synthesized speech is improved using this application. Also, we classify the voiced sounds by cepstral euclidian distance measure for reducing overhead memory. The representative excitation signal of the same group's voiced sounds is used as excitation signal on synthesis. This method does not affect the quality of synthesized speech. As the result of experiment, this method eliminates the "buzziness" of synthesized speech and reduces the spectral distortion of synthesized speech.ed speech.

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Effects of Physical Form and Urea Treatment of Rice Straw on Rumen Fermentation, Microbial Protein Synthesis and Nutrient Digestibility in Dairy Steers

  • Gunun, P.;Wanapat, M.;Anantasook, N.
    • Asian-Australasian Journal of Animal Sciences
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    • v.26 no.12
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    • pp.1689-1697
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    • 2013
  • This study was designed to determine the effect of physical form and urea treatment of rice straw on rumen fermentation, microbial protein synthesis and nutrient digestibility. Four rumen-fistulated dairy steers were randomly assigned according to a 2 (2 factorial arrangement in a 4 (4 Latin square design to receive four dietary treatments. Factor A was roughage source: untreated rice straw (RS) and urea-treated (3%) rice straw (UTRS), and factor B was type of physical form of rice straw: long form rice straw (LFR) and chopped (4 cm) rice straw (CHR). The steers were offered the concentrate at 0.5% body weight (BW) /d and rice straw was fed ad libitum. DM intake and nutrient digestibility were increased (p<0.05) by urea treatment. Ruminal pH were decreased (p<0.05) in UTRS fed group, while ruminal ammonia nitrogen ($NH_3$-N) and blood urea nitrogen (BUN) were increased (p<0.01) by urea treatment. Total volatile fatty acid (VFA) concentrations increased (p<0.01) when steers were fed UTRS. Furthermore, VFA concentrations were not altered by treatments (p>0.05), except propionic acid (C3) was increased (p<0.05) in UTRS fed group. Nitrogen (N) balance was affected by urea treatment (p<0.05). Microbial protein synthesis (MCP) synthesis were greater by UTRS and CHR group (p<0.05). The efficiency of microbial N synthesis was greater for UTRS than for RS (p<0.05). From these results, it can be concluded that using the long form combined with urea treatment of rice straw improved feed intake, digestibility, rumen fermentation and efficiency of microbial N synthesis in crossbred dairy steers.

Improved Phase Synthesis for Parametric Stereo Audio Coding (파라메트릭 스테레오 오디오 부호화를 위한 향상된 위상 합성 기법)

  • Hyun, Dong-Il;Park, Young-Cheol;Youn, Dae Hee
    • Journal of the Institute of Electronics and Information Engineers
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    • v.50 no.12
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    • pp.184-190
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    • 2013
  • Parametric stereo(PS) audio coding is a specific version of spatial audio coding. In this paper, the problem due to the conventional synthesis of phase differences. In the conventional upmix matrix, phase differences are synthesized not only on downmix signal but also ambient signal, which violates the assumption that the ambient signals are anti-phased. Deterioration due to the phase synthesis is analyzed, especially, for low interchannel correlation. To solve this problem, new upmix matrix is proposed, which synthesizes phase differences only on downmix signal. The performance of the proposed upmix matrix is verified by the subjective listening tests.

Stepwise Refinement Data Path Synthesis Algorithm for Improved Testability (개선된 테스트 용이화를 위한 점진적 개선 방식의 데이타 경로 합성 알고리즘)

  • Kim, Tae-Hwan;Chung, Ki-Seok
    • Journal of KIISE:Computer Systems and Theory
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    • v.29 no.6
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    • pp.361-368
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    • 2002
  • This paper presents a new data path synthesis algorithm which takes into account simultaneously three important design criteria: testability, design area, and total execution time. We define a goodness measure on the testability of a circuit based on three rules of thumb introduced in prior work on synthesis for testability. We then develop a stepwise refinement synthesis algorithm which carries out the scheduling and allocation tacks in an integrated fashion. Experimental results for benchmark and other circuit examples show that we are able to enhance the testability of circuits with very little overheads on design area and execution time.

Seismic Response Control of a Cable-Stayed Bridge using a $\mu$-Synthesis Method ($\mu$-합성법을 이용한 사장교의 지진응답 제어)

  • 박규식;정형조;윤우현;이인원
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2004.10a
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    • pp.476-483
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    • 2004
  • This paper presents a hybrid system combining lead rubber bearings and hydraulic actuators controlled by a μ-synthesis method for seismic response control of a cable-stayed bridge. A hybrid system could alleviate some of restrictions and limitations that exist when each system is acting alone because multiple control devices are operating. Therefore, the overall control performance of a hybrid system may be improved compared to each system, however the overall system robustness may be negatively impacted by active device in the hybrid system or active controller may cause instability due to small margins. Therefore, a f-synthesis method that guarantees the robust performance is considered to enhance the possibility of real applications of the control system. The control performances of the proposed control system are compared with those of passive, active, semiactive control systems and hybrid system controlled by LQG algorithm and an extensive robust analysis with respect to stiffness and mass matrices perturbation and time delay of actuator is performed. Numerical simulation results show that the control performance of the proposed control system is superior to that of the passive system and slightly better than that of the active and semiactive systems and two hybrid systems show similar control performances. Furthermore, the hybrid system controlled by a μ-synthesis method shows the good robustness without loss of control performances. Therefore, the proposed control system could effectively be used to seismically excited cable-stayed bridge which contains many uncertainties.

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A Study on Syngas Production By Noncatalytic Partial Oxidation of Methane (메탄의 무촉매 부분산화를 통한 합성가스 제조 연구)

  • Na, Ik-Hwan;Yang, Dong-Jin;Choi, Sin-Yeong;Chae, Tae-Young;Bang, Byoung-Yeol;Yang, Won
    • Journal of Hydrogen and New Energy
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    • v.20 no.4
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    • pp.337-343
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    • 2009
  • Noncatalytic partial oxidation of methane for producing synthesis gas was studied in a lab-scale experimental apparatus. Partial oxidation developed for high-temperature, fuel-rich combustion and it is exothermic process. but Steam reforming and Caron reforming is highly endothermic process to need much energy. Noncatalytic partial oxidation of methane is affected by temperature and equivalent ratio, so we studied effect about composition of synthesis gas at lab scale reactor. We used electronic heater to control the temperature of reactor. The quality of synthesis gas is improved and reduced heat value to require at Noncatalytic partial oxidation because the reacting temperature is lower at oxy condition.

Model Establishment of a Deployable Missile Control Fin Using Substructure Synthesis Method (부구조물 합성법을 이용한 접는 미사일 조종날개 모델 수립)

  • Kim, Dae-Kwan;Bae, Jae-Sung;Lee, In;Han, Jae-Hung
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.15 no.7 s.100
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    • pp.813-820
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    • 2005
  • A deployable missile control fin has some structural nonlinearities because of the worn or loose hinges and the manufacturing tolerance. The structural nonlinearity cannot be eliminated completely, and exerts significant effects on the static and dynamic characteristics of the control fin. Thus, It is important to establish the accurate deployable missile control fin model. In the present study, the nonlinear dynamic model of 4he deployable missile control fin is developed using a substructure synthesis method. The deployable missile control fin can be subdivided Into two substructures represented by linear dynamic models and a nonlinear hinge with structural nonlinearities. The nonlinear hinge model is established by using a system identification method, and the substructure modes are improved using the Frequency Response Method. A substructure synthesis method Is expanded to couple the substructure models and the nonlinear hinge model, and the nonlinear dynamic model of the fin is developed. Finally, the established nonlinear dynamic model of the deployable missile control fin is verified by dynamic tests. The established model is In good agreement with test results, showing that the present approach is useful in aeroelastic stability analyses such as time-domain nonlinear flutter analysis.

Novel solvothermal approach to hydrophilic nanoparticles of late transition elements and its evaluation by nanoparticle tracking analysis

  • Dutilleul, Marion Collart;Seisenbaeva, Gulaim A.;Kessler, Vadim G.
    • Advances in nano research
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    • v.2 no.2
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    • pp.77-88
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    • 2014
  • Solvothermal treatment of late transition metal acetylacetonates in a novel medium composed either of pure acetophenone or acetophenone mixtures with amino alcohols offers a general approach to uniform hydrophilic metal nanoparticles with high crystallinity and low degree of aggregation. Both pure metal and mixed-metal particles can be accesses by this approach. The produced materials have been characterized by SEM-EDS, TEM, FTIR in the solid state and by Nanoparticle Tracking Analysis in solutions. The chemical mechanisms of the reactions producing nanoparticles has been followed by NMR. Carrying out the process in pure acetophenone produces palladium metal, copper metal with minor impurity of $Cu_2O$, and NiO. The synthesis starting from the mixtures of Pd and Ni acetylacetonates with up to 20 mol% of Pd, renders in minor yield the palladium-based metal alloy along with nickel oxide as the major phase. Even the synthesis starting from a mixed solution of $Cu(acac)_2$ and $Ni(acac)_2$ produces oxides as major products. The situation is improved when aminoalcohols such as 2-aminoethanol or 2-dimethylamino propanol are added to the synthesis medium. The particles in this case contain metallic elements and pairs of individual metals (not metal alloys) when produced from mixed precursor solutions in this case.