• Bulletin of the Korean Chemical Society
• /
• 제28권9호
• /
• pp.1523-1530
• /
• 2007

The first reduction peak of the cyclic voltammogram (CV) for sulfur reduction in dimethyl sulfoxide has been studied using time resolved Fourier transform electrochemical impedance spectroscopic (FTEIS) analysis of small potential step chronoamperometric currents. The FTEIS analysis results reveal that the impedance signals obtained during short potential steps can be resolved into electron transfer reactions of two different time constants in a high frequency region. The FTEIS method provides snap shots of impedance profiles during an earlier phase of the reaction, leading to time resolved EIS measurements. Our results obtained by the FTEIS analysis are consistent with a series of electron transfer and chemical equilibrium steps of a complex reaction, making up an ECE (electrochemical-chemical-electrochemical) mechanism postulated from the results of computer simulation.

• Applied Science and Convergence Technology
• /
• 제26권5호
• /
• pp.114-117
• /
• 2017

Plasma characteristics of two-dimensional inductively coupled discharge simulation is investigated. Impedance of an inductively coupled plasma discharge was considered. Voltage drops across antenna coils and current variation between coils made different profiles of plasma characteristics. Importance of the capacitive field effect in some case was analyzed.

• Journal of Power Electronics
• /
• 제16권3호
• /
• pp.1046-1055
• /
• 2016

A controller to mitigate the destabilizing effect of constant power load (CPL) is proposed for a DC/DC buck-boost converter. The load profile has been considered to be predominantly of CPL type. The negative incremental resistance of the CPL tends to destabilize the feeder system, which may be an input filter or another DC/DC converter. The proposed sliding mode controller aims to ensure system stability under the dominance of CPL. The effectiveness of the controller has been validated through real-time simulation studies and experiments under various operating conditions. The controller has been demonstrated to be robust with respect to variations in supply voltage and load and capable of mitigating instabilities induced by CPL. Furthermore, the controller has been validated using all possible load profiles, which may arise in modern-day DC-distributed power systems.

• 반도체디스플레이기술학회지
• /
• 제20권3호
• /
• pp.27-31
• /
• 2021

VI probe, which is one of various in-situ plasma monitoring sensor, is frequently used for in-situ process monitoring in mass production environment. In this paper, we correlated the plasma etch results with VI probe data with the small amount of gas flow rate changes to propose usefulness of the VI probe in real-time process monitoring. Several different sized contact holes were employed for the etch experiment, and the etched profiles were measured by scanning electron microscope (SEM). Although the shape of etched hole did not show satisfactory relationship with VI probe data, the chamber status changed along the incremental/decremental modification of the amount of gas flow was successfully observed in terms of impedance monitoring.

• Journal of Power Electronics
• /
• 제13권3호
• /
• pp.429-436
• /
• 2013

Online simulations are utilized to reduce time and cost in the development and performance optimization of plug-in hybrid electric vehicle (PHEV) and electric vehicles (EV) systems. One of the most important factors in an online simulation is the accuracy of the model. In particular, a model of a battery should accurately reflect the properties of an actual battery. However, precise dynamic modeling of high-capacity battery systems, which significantly affects the performance of a PHEV, is difficult because of its nonlinear electrochemical characteristics. In this study, a dynamic model of a high-capacity battery cell for a PHEV is developed through the extraction of the equivalent impedance parameters using electrochemical impedance spectroscopy (EIS). Based on the extracted parameters, a battery cell model is implemented using MATLAB/Simulink, and charging/discharging profiles are executed for comparative verification. Based on the obtained results, the model is optimized for a high-capacity battery cell for a PHEV. The simulation results show good agreement with the experimental results, thereby validating the developed model and verifying its accuracy.

• Nuclear Engineering and Technology
• /
• 제55권4호
• /
• pp.1518-1527
• /
• 2023

A method was proposed for in-situ evaluating the thickness and resistivity of the oxide/hydroxide film formed on the surface of aluminum alloy exposed to sump water formed in the containment after a loss-of-coolant accident. The evaluation entailed fitting a model for the film impedance, which has film thickness and other variables describing the resistivity profile of the film along its thickness direction as fitting parameters, to the practically measured electrochemical impedance data. The obtained resistivity profiles implied that the films formed at pHs_25℃ 7, 8, 9, 10, and 11 all had a duplex structure; compared to the outer layer in contact with the solution, the inner layer of the film had a much higher resistivity and was inferred to be denser and provide most of the protectiveness of the film. Both the thickness and the total resistance of the film decreased with the increasing solution pH_25℃, suggesting that the films formed in more alkaline solutions had less protectiveness against corrosion, consistent with the increasing aluminum alloy corrosion rates previously identified.

• The Journal of the Acoustical Society of Korea
• /
• 제15권2E호
• /
• pp.76-84
• /
• 1996

The experimental testing results of the large-scale version of a forward-looking ultrasound imaging catheter(FLUIC) are presented, along with the fabrication techniques used, experimental methods, and comparisons of the measured and simulated results. The transducer model is verified by measuring the electrical impedance of the transducer. The pulse width, beamwidth, and the dynamic range for both transmit and pulse-echo response of the fabricated FLUIC are also analyzed. The experimental results conformed its forward-looking imaging capability and the sources of discrepancies between the simulated and experimental beam profiles are addressed.

• 대한전자공학회논문지SD
• /
• 제41권10호
• /
• pp.31-39
• /
• 2004

이 논문은 파워 잡음 특성이 칩(chip)의 코아 동작에 따라 DDR DRAM용 모듈(Module)과 패키지(package)의 종류의 영향을 받는 다는 것을 보여주고 있다. 이를 분석하기 위해 상용 TSOP-based DIMM 과 FBGA-based DIMM에서 FBGA와 TSOP 패키지형 DRAM 칩을 가지고 임피던스 모양과 파워 잡음을 분석하였다. 일반적인 상식과 달리, FBGA 패키지의 잡음 격리 특성이 TSOP 패키지의 잡음 격리 특성보다 전달되는 잡음에 더 약하고 민감하다는 것이 발견되었다. 또한 자체 및 전달 잡음 특성을 조절하는데 있어서는 모듈상의 디커풀링 커패시터(decoupling capacitors)들 위치가 패키지 자체의 리드선 인덕턴스(lead inductance)보다 더 중요하다는 것을 또한 시뮬레이션 결과들은 보여준다. 따라서 잡음 억제나 잡음 전달로부터 격리의 목표설정 값을 만족시키는 것은 패키지 형태 뿐 아니라 모듈 전체를 고려한 파워 분배 시스템의 설계를 통해서만 얻어질수 있다.

• Journal of Electrochemical Science and Technology
• /
• 제10권3호
• /
• pp.257-270
• /
• 2019

The inhibition performance of sodium gluconate (SG), cetyltrimethylammonium bromide (CTAB) and their mixture (SG/CTAB) on the corrosion behavior of ${\alpha}$-brass in 0.5 M $H_2SO_4$ solution has been investigated by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), Scanning Electron Microscope with Energy-Dispersive Spectrometer (SEM-EDS), Inductively Coupled Plasma Spectrometry (ICPS) and molecular dynamics (MD) simulation techniques. The results reveal that SG with 5ppm CTAB, noted SG/CTAB, acts as a good corrosion inhibitor and its inhibition efficiency reached 89% after 24 h immersion in sulfuric acid solution, but slightly decreased at higher temperatures. The polarization curves displayed that SG/CTAB acts as a cathodic-kind inhibitor. Electrochemical impedance spectroscopy (EIS) studies revealed that the addition of 5ppm CTAB to different concentrations of SG considerably increases the corrosion resistance of ${\alpha}$-brass. The SEM-EDS and ICPS analyses support the experimental results. Further, molecular dynamics (MD) simulations were used to understand the adsorption profiles of SG/CTAB on Cu(111) and Zn(111) surfaces.

• Nuclear Engineering and Technology
• /
• 제45권5호
• /
• pp.613-624
• /
• 2013

Multi-dimensional two-phase phenomena occur in many industrial applications, particularly in a nuclear reactor during steady operation or a transient period. Appropriate modeling of complicated behavior induced by a multi-dimensional flow is important for the reactor safety analysis results. SPACE, a safety analysis code for thermal hydraulic systems which is currently being developed, was designed to have the capacity of multi-dimensional two-phase thermo-dynamic phenomena induced in the various phases of a nuclear system. To validate the performance of SPACE, a two-dimensional two-phase flow test was performed with slab geometry of the test section having a scale of $1.43m{\times}1.43m{\times}0.11m$. The test section has three inlet and three outlet nozzles on the bottom and top gap walls, respectively, and two outlet nozzles installed directly on the surface of the slab. Various kinds of two-dimensional air/water flows were simulated by selecting combinations of the inlet and outlet nozzles. In this study, two-dimensional two-phase void fraction profiles were quantified by measuring the local gap impedance at 225 points. The flow conditions cover various flow regimes by controlling the flow rate at the inlet boundary. For each selected inlet and outlet nozzle combination, the water flow rate ranged from 2 to 20 kg/s, and the air flow rate ranged from 2.0 to 20 g/s, which corresponds to 0.4 to 4 m/s and 0.2 to 2.3 m/s of the superficial liquid and gas velocities based on the inlet port area, respectively.