• Title/Summary/Keyword: Imine

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Preparation and Characterization of Tin(II) Complexes with Isomeric Series of Schiff Bases as Ligands

  • Refat, M. S.;Sadeek, S. A.
    • Journal of the Korean Chemical Society
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    • v.50 no.2
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    • pp.107-115
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    • 2006
  • Complexes of Sn(II) with L1 = acac-o-phdnH2 [N,N'-o-phenylene bis(acetylacetoneimine)], L2 = acac-m-phdnH2 [N,N'-m-phenylene bis(acetylacetoneimine)] and L3 = acac-p-phdnH2 [N,N'-p-phenylene bis(acetylacetoneimine)] have been prepared and characterized by elemental analyses, vibrational, electronic spectra and thermal studies (TGA and DTA). Vibrational spectra indicated the coordination mode of imine and carbonyl oxygen for ligands giving (ONNO) that belong to C2V point group symmetry. The [Sn(L3)] complex has a maximum activation energy and [Sn(L2)] complex has a minimum activation energy.

Synthesis and Identification of Novel Pyrazoline and Its Anti-cancer Property (새로운 피라졸린 화합물의 합성과 구조결정 및 항암효과)

  • Koh, Dong-Soo
    • Journal of Applied Biological Chemistry
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    • v.54 no.2
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    • pp.143-146
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    • 2011
  • Novel pyrazoline (4) was synthesized from chalcone (3) which was prepared from 2'-hydroxy-l'acetonaphthone (1) and 4-methoxy benzaldehyde (2). Pyrazoline (4) forms resonance assisted hydrogen bond between naphthol hydroxyl group and imine nitrogen in a pyrazoline ring. Pyrazoline (4) shows Poly ADP-ribose Polymerase (PARP) cleavage ability as a proof of apoptosis in cancer cell, which reveals its anti-cancer property.

The Recent Current of Fluorescent Polypyridine Compounds Having Photofuctionality

  • Choi, Chang-Shik
    • Rapid Communication in Photoscience
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    • v.5 no.2
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    • pp.21-26
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    • 2016
  • Many kinds of fluorescent polypyridine compounds including bpy and dppz derivatives are described in understanding the recent current of fluorescent materials having photofuctionality. Those polypyridine compounds have the photofunctionality such as the fluorescence recognition and/or photo-switching. Furthermore, those compounds are applicated for the construction of long ranged photoinduced electron/energy transfer system. Various fluorescent ${\pi}-conjugation$ systems connected by amide or imine bond as well as the simple fluorescent bpy derivatives are introduced in this review paper.

An Efficient Synthesis of Substituted Quinolines via Indium(III) Chloride Catalyzed Reaction of Imines with Alkynes

  • Zhu, Mei;Fu, Weijun;Xun, Chen;Zou, Guanglong
    • Bulletin of the Korean Chemical Society
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    • v.33 no.1
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    • pp.43-47
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    • 2012
  • An efficient synthetic method for the preparation of quinolines through indium(III) chloride-catalyzed tandem addition-cyclization-oxidation reactions of imines with alkynes was developed. The processes can provide a diverse range of quinoline derivatives in good yields from simple imines and alkynes.

Synthesis of N-methylspiro [1,2,3,4-tetrahydro-naphthalene-1,2'-pyrrolidine]

  • Jang, Jin-Hee;Sin, Kwan-Seog;Park, Hae-Il
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.237.2-237.2
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    • 2003
  • A pathway for synthesis of N-methylspiro [1,2,3,4-tetrahydro-naphthalene-1,2'- pyrrolidine] was developed. Formation of the imine compound from ${\alpha}$-tetralone and methylamine using titanium tetrachloride followed by ddition of allylmagnesium bromide gave (1-allyl-1,2,3,4-tetrahydro-naphthalen-1-yl)methylamine. (omitted)

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Total synthesis of Antofine by using Intramolecular 1.3-dipolar cycloaddition of Azidealkene

  • Lee, Jae-Kwang;Lee, Tae-Ho;Song , So-Young
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.362.2-362.2
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    • 2002
  • Antofine belongs to the Phenathroindolizidine group of alkaloids. This natural products exhibit interesting biological properties such as antitumour activity. and anti-inflammentory. Wittig reaction of phenathrenealdehyde with the phosponium salt provided the phenathreneazidealkene in good yield. Intramolecular 1.3-dipolar cycloaddition of the resulting azidealkent in refluxing benzene proceeded the imine. It was reduced with cyanoborohydride of Noyori's Asymmetric Hydrogenation. (omitted)

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