• Title/Summary/Keyword: ITO박막

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Properties of ITO thin film's aging change prepared on the various substrate (다양한 기판에 제작한 ITO 박막의 실온 특성 변화)

  • Kim, Sang-Mo;Rim, You-Seung;Son, In-Hwan;Kim, Kyung-Hwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.403-404
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    • 2008
  • In this study, we prepared ITO thin film on glass, polycarbonate (PC) and polyethersulfone (PES) substrate in Facing Targets sputtering (FTS) system. Properties of as-deposited thin films's aging change were investigated as a function of time placed in the air. The electrical and optical properties of as-deposited thin films were employed by a four point probe and an UV/VIS spectrometer, an X-ray diffractometer (XRD), a Field Emission Scanning Electron Microscope(FESEM) and a Hall Effect measurement. As a result, as time went by, transmittance of all films did not change but resistivity of films was decreasing.

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Performance Characteristics of Organic Electroluminescence Diode Using a Carbon Nanotube-Doped Hole Injection Layer (탄소 나노튜브가 도입된 정공 주입층에 의한 유기발광다이오드의 성능 특성 연구)

  • Kang, Hak-Su;Park, Dae-Won;Choe, Youngson
    • Korean Chemical Engineering Research
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    • v.47 no.4
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    • pp.418-423
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    • 2009
  • MWCNT(multi-wall carbon nanotube)-doped PEDOT:PSS(poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)), used as a HIL(hole injection layer) material in OLEDs(organic light emitting diodes), was spin-coated on to the ITO glass to form PEDOT:PSS-MWCNT nano composite thin film. Morphology and transparency characteristics of nano composite thin films with respect to the loading percent of MWCNT have been investigated using FT-IR, UV-Vis and SEM. Furthermore, ITO/PEDOT:PSS-MWCNT/NPD/$Alq_3$/Al devices were fabricated, and then J-V and L-V characteristics were investigated. Functional group-incorporated MWCNT was prepared by acid treatment and showed good dispersion property in PEDOT:PSS solution. PEDOT:PSS-MWCNT thin films possessed good transparency property. For multi-layered devices, it was shown that as the loading percent of MWCNT increased, the current density increased but the luminance dramatically decreased. It might be conclusively suggested that the enhanced charge mobility by MWCNT could increase the current density but the hole trapping property of MWCNT could dramatically decrease the hole mobility in the current devices.

A Study of Thin Film deposition using of RF Magnetron Sputtering (RF 마그네트론 스퍼터링을 이용한 박막 증착에 관한 연구)

  • Lee, Woo Sik
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.11 no.6
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    • pp.772-777
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    • 2018
  • This paper used RF Magnetron Sputtering to deposition n-type and p-type to ITO glass. The N-type ohmic contact worked well under all conditions. Sheet resistance has been shown to increase sheet resistance as RF Power increases. After analyzing the surface of the deposited thin film, in the condition that RF Power was 250W and substrate temperature was $250^{\circ}C$, particles were measured to have a uniform and consistent thin film. P-type has good ohmic contact under all conditions and sheet resistance has been shown to increase as RF Power increases. As the RF Power grew, thickness increased and stabilized. PN junction thin film and NP junction thin film showed increased thickness and stabilized as sputtering time increased. As a result of thin film, conversion efficiency was at 0.2 when sputtering time was 10 minutes.

Characteristics and Application of PLT Thin-Films Deposited on ITO Substrate (ITO 기판위에 증착시킨 PLT 박막의 특성 및 그 응용)

  • Bae, Seung-Choon;Park, Sung-Kun;Choi, Byung-Jin;Kim, Ki-Wan
    • Journal of Sensor Science and Technology
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    • v.6 no.5
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    • pp.423-429
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    • 1997
  • We fabricated PLT thin films on ITO substrate for flat pannel display and investigated the characteristics, then we applicated to electroluminescent device and investigated application possibility. When we fabricated PLT thin films with substrate temperature of $500^{\circ}C$, and pressure of 30 mTorr, the relative deielectric constant and breakdown electricfield of PLT thin films were 120 and 3.2MV/cm. The electric resistivity was $2.0{\times}10^{12}{\Omega}{\cdot}cm$. PLT thin films had polycrystal structure of perovskite and pyrochlore at the higher substrate temperature than $450^{\circ}C$, and had good crystallinity at higher pressure. To use PLT insulator film and ZnS:Mn phosphor, we fabricated thin film electroluminescent device of ITO/PLT/ZnS:Mn/PLT/Al structure. At the result, threshold voltage was $35.2V_{rms}$ and brightness was $2400cd/m^{2}$ at $50V_{rms}$ and 1kHz. Maximum luminescence efficiency was 0.811m/W.

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Effect of Work Function of Zn-doped ITO Thin Films on Characteristics of Silicon Heterojunction Solar Cells (실리콘 이종접합 태양전지 특성에 대한 Zn 도핑된 ITO 박막의 일함수 효과)

  • Lee, Seung-Hun;Tark, Sung-Ju;Choi, Su-Young;Kim, Chan-Seok;Kim, Won-Mok;Kim, Dong-Hhwan
    • Korean Journal of Materials Research
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    • v.21 no.9
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    • pp.491-496
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    • 2011
  • Transparent conducting oxides (TCOs) used in the antireflection layer and current spreading layer of heterojunction solar cells should have excellent optical and electrical properties. Furthermore, TCOs need a high work function over 5.2 eV to prevent the effect of emitter band-bending caused by the difference in work function between emitter and TCOs. Sn-doped $In_2O_3$ (ITO) film is a highly promising material as a TCO due to its excellent optical and electrical properties. However, ITO films have a low work function of about 4.8 eV. This low work function of ITO films leads to deterioration of the conversion efficiency of solar cells. In this work, ITO films with various Zn contents of 0, 6.9, 12.7, 28.8, and 36.6 at.% were fabricated by a co-sputtering method using ITO and AZO targets at room temperature. The optical and electrical properties of Zn-doped ITO thin films were analyzed. Then, silicon heterojunction solar cells with these films were fabricated. The 12.7 at% Zn-doped ITO films show the highest hall mobility of 35.71 $cm^2$/Vsec. With increasing Zn content over 12.7, the hall mobility decreases. Although a small addition of Zn content increased the work function, further addition of Zn content over 12.7 at.% led to decreasing electrical properties because of the decrease in the carrier concentration and hall mobility. Silicon heterojunction solar cells with 12.7 at% Zn-doped ITO thin films showed the highest conversion efficiency of 15.8%.

Study of ablation depth control of ITO thin film using a beam shaped femtosecond laser (빔 쉐이핑을 이용한 펨토초 레이저 ITO 박막 가공 깊이 제어에 대한 연구)

  • Kim, Hoon-Young;Yoon, Ji-Wook;Choi, Won-Seok;Stolberg, Klaus;Whang, Kyoung-Hyun;Cho, Sung-Hak
    • Laser Solutions
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    • v.17 no.1
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    • pp.1-6
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    • 2014
  • Indium tin oxide (ITO) is an important transparent conducting oxide (TCO). ITO films have been widely used as transparent electrodes in optoelectronic devices such as organic light-emitting devices (OLED) because of their high electrical conductivity and high transmission in the visible wavelength. Finding ways to control ITO micromachining depth is important role in the fabrication and assembly of display field. This study presented the depth control of ITO patterns on glass substrate using a femtosecond laser and slit. In the proposed approach, a gaussian beam was transformed into a quasi-flat top beam by slit. In addition, pattern of square type shaped by slit were fabricated on the surfaces of ITO films using femtosecond laser pulse irradiation, under 1030nm, single pulse. Using femtosecond laser and slit, we selectively controlled forming depth and removed the ITO thin films with thickness 145nm on glass substrates. In particular, we studied the effect of pulse number on the ablation of ITO. Clean removal of the ITO layer was observed when the 6 pulse number at $2.8TW/cm^2$. Furthermore, the morphologies and fabricated depth were characterized using a optical microscope, atomic force microscope (AFM), and energy dispersive X-ray spectroscopy (EDS).

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The Fabrication and Properties of Polymer Light Emitting Diode with different concentration of MEH-PPV (MEH-PPV 농도에 따른 고분자 OLED의 제작과 특성평가)

  • Gong Su-cheol;Chang Ho-jong;Baek In-jae;Lim Hyun-Seung
    • Proceedings of the KAIS Fall Conference
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    • 2005.05a
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    • pp.173-176
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    • 2005
  • 고분자 OLED는 저분자 OLED에 비하여 공정이 간단하고 대화면, Plastic 기판을 사용하여 All organic display로의 구현이 있다는 많은 장점을 가지고 있지만 소자의 신뢰성과 안정성에 문제를 갖고 있어 현재까지 저분자 OLED에 비하여 기술 수준이 미약하다. 그러나 차세대 디스플레이의 실현을 위하여 많은 대학과 기업연구소에서 많은 연구가 진행중이다. 본 논문에서는 ITO/PEDOT:PSS/MEH-PPV/Al 구조를 갖는 고분자 OLED를 제작하고 발광메커니즘에 대한 고찰과 계면특성 및 전기$\cdot$광학적 특성을 조사하였다. 정공수송물질인 PEDOT:PSS은 박막의 표면상태를 부드럽게하고 ITO와 MEH-PPV 사이의 접착을 좋게하며 ITO 로부터 정공을 원활하게 MEH-PPV로 전달하여 효율을 향상시킨다. 제작된 소자는 발광효율을 극대화시키기 위하여 정공수송층인 PEDOT:PSS을 첨가시킨 다층구조로서 각각의 박막을 열처리 및 MEH-PPV의 농도를 0.1, 0.3, 0.5, 0.7, 0.9, 1.5wt$\%$로 변화시켜 농도별 표면상태와 전기$\cdot$광학적 특성을 관찰하여 고효율 OLED소자 제작에 가장 적합한 MEH-PPV의 농도에 대하여 고찰하였다.

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The Etching Properties of Indium Tin Oxide Thin Films in O2/BCl3/Ar Gas Mixture Using Inductively Coupled Plasma (유도결합플라즈마를 이용한 O2/BCl3/Ar가스에 따른 Indium Tin Oxide 박막의 식각 특성 연구)

  • Wi, Jae-Hyung;Woo, Jong-Chang;Kim, Chang-Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.10
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    • pp.752-758
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    • 2010
  • The etching characteristics of indium tin oxide (ITO) thin films in an $O_2/BCl_3/Ar$ plasma were investigated. The etch rate of ITO thin films increased with increasing $O_2$ content from 0 to 2 sccm in $BCl_3$/Ar plasma, whereas that of ITO decreased with increasing $O_2$ content from 2 sccm to 6 sccm in $BCl_3$/Ar plasma. The maximum etch rate of 65.9 nm/m in for the ITO thin films was obtained at 2 sccm $O_2$ addition. The etch conditions were the RF power of 500 W, the bias power of 200 W, the process pressure of 15 mTorr, and the substrate temperature of $40^{\circ}C$. The analysis of x-ray photo electron spectroscopy (XPS) was carried out to investigate the chemical reactions between the surfaces of ITO thin films and etch species.

A Study on the Performance Improvement for Flexible PCDTBT : PC71BM Organic Thin Film Solar Cell by Ozone Surface Treatment of ITO Electrode (ITO 전극의 오존 표면처리에 의한 플렉시블 PCDTBT : PC71BM 유기박막 태양전지의 성능 개선에 관한 연구)

  • No, Im-Jun;Lim, Young-Taek;Shin, Paik-Kyun
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.26 no.11
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    • pp.104-108
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    • 2012
  • Flexible organic thin film solar cell device with Bulk Hetero-Junction (BHJ) structure was fabricated with blended conjugated polymer of PCDTBT : $PC_{71}BM$ as active layer. Surface of ITO anode for the organic solar cell device was treated with ozone. The organic solar cell device with bare ITO showed short circuit current density ($J_{sc}$) of $8.2mA/cm^2$, open-circuit voltage ($V_{oc}$) of 0.73V, fill factor (FF) of 0.36, and power conversion efficiency (PCE) of 2.16%, respectively. The organic solar cell device with ozone treated ITO anode revealed distinctively improved performance parameters:$J_{sc}$ of $9.8mA/cm^2$, $V_{oc}$ of 0.82V, FF of 0.43, PCE(${\eta}$) of 3.42%.

Overlapping Rates of Laser Spots on the Laser Direct Patterning of ITO Electrode in the Double-layer Structure of Thin Film (이층 박막 구조에서 ITO 전극의 레이저 직접 패터닝 시레이저 식각 패턴 중첩 비율의 변화)

  • Wang, Jian-Xun;Park, Jung-Cheul;Kwon, Sang-Jik;Cho, Eou-Sik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.5
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    • pp.377-380
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    • 2012
  • Laser direct patterning of indium tin oxide(ITO) is one of new methods of direct etching process to replace the conventional photolithography. A diode pumped Q-switched Nd:$YVO_4$ (${\lambda}$= 1,064 nm) laser was used to produce ITO electrode on various transparent oxide semiconductor films such as zinc oxide(ZnO). The laser direct etched ITO patterns on ZnO were compared with those on glass substrate and were considered in terms of the overlapping rate of laser beam. In case of the laser etching on double-layer, it was possible to obtain the higher overlapping rate of laser beam.