• Title/Summary/Keyword: II-VI

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Preparation and Characterization of Dinuclear and Trinuclear Metal Complexes, $[(PPh_3)_2(CO)M({\mu}-E)M(CO)(PPh_3)_2]X_2$ (M=Rh, Ir; E=Pyrazine, 4,4'-Bipyridyl, $X=SO_3CF_3$; $E=Pd(CN)_4$, $Pt(CN)_4$, X=none)

  • Ko Jaejung;Lee Myunggab;Kim Moonsik;Kang Sang Ook
    • Bulletin of the Korean Chemical Society
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    • v.13 no.2
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    • pp.158-162
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    • 1992
  • Hydrocarbon solution of $(PPh_3)_2(CO)MOSO_2CF_3(M=Rh$, Ir)reacts rapidly with Pyrazine or 4,4'-bipyridyl to yield dinuclear metal complexes $[(PPh_3)_3(CO)M({\mu}-pyrazine)M(CO)(PPh_3)_2](SO_3CF_3)_2$ (I: M= RhH; III: M=Ir) or [$(PPh_3)_2$(CO)M(${\mu}$-44'-bipyridyl)M(CO)$(PPh_3)_2](SO_3CF_3)_2$, (II: M=Rh; IV: M=Ir), respectively. Compounds, I, II, III, and IV were characterized by $^1H-NMR$, $^{13}C-NMR$, $^{31}P-NMR$, and infrared spectrum. Ethanol solution of $(PPh_3)_2(CO)MOSO_2CF_3$ (M=Rh, Ir) also reacts with $(TBA)_2$M'$(CN)_4$ (M'=Pd, Pt) to yield trinuclear metal complexes [$(PPh_3)_2$(CO)dM-NCM'$(CN)_2$CN-M(CO)$(PPh_3)_2]$ (V : M=Rh, M'=Pd; VI : M=Rh, M'=Pt; VII: M=Ir, M'=Pd; VIII: M=Ir, M'=Pt). The trinuclear metal complexes V, VI, VII, and VIII are bridged by the cyanide groups. The infrared spectrum of V, VI, VII, and VIII supports the presence of the bridged cyanide and terminal cyanide group.

Groundwater Flow Analysis Using Finite Difference Method in Volcanic Island (화산도서에서 유한차분법을 이용한 지하수 유동해석)

  • Choe, Yun-Yeong;Lee, Sun-Tak
    • Journal of Korea Water Resources Association
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    • v.33 no.5
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    • pp.611-622
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    • 2000
  • In this study, MODFLOW model is used to analyze the groundwater flow system of Seoguipo area in Cheju island, The final parameters of permeability coefficient and storage coefficient of target area can be obtained by trial and error method using the measured data of pumping rate as initial values. And it is found that the applicability for groundwater flow system is reflected well from the simulation result of the model. Seoguipo area spring water is thought to appear by relatively stable groundwater recharge below EL. 400m according to head distribution through the analysis of observed data considering topographic and geological characteristics, Lee's study(996), and the simulation result. Also it is known that point II, III, and VI show relatively large velocity vectors, and groundwater flows through the movement path which is distributed in various directions of I, II, III, IV, V, VI, and VIl form the result of velocity vector analysis using head distribution result values to analyze the groundwater flow path under unsteady flow condition.dition.

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A study of Immobilizing Heavy metals by pellets manufactured from Coal tailings and Iron oxide (선탄경석(選炭硬石)과 광산화물(鑛酸化物)로 제조(製造)한 담체(擔體)의 중금속(重金屬) 불용화(不溶化) 특성연구(特性硏究))

  • Lee, Gye-Seung;Song, Young-Jun
    • Resources Recycling
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    • v.21 no.1
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    • pp.75-81
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    • 2012
  • Porous pellets for immobilizing heavy metals were manufactured from coal tailings and iron oxide powder. Coal tailings was pulverized and mixed with iron oxide powder. The mixed powder was granulated into spherical pellets and roasted. Over $1100^{\circ}C$, residual coal in coal tailings reduced iron oxide to ZVI(Zero-Valent Iron). The pellets have 34.63% of porosity, 1.31 g/mL of bulk density, and 9.82.urn median pore diameter. The pellets were reacted with synthetic solutions containing each heavy metals: arsenic(V), copper(II), chrome(VI), and cadmium(II), respectively. On the test of immobilizing heavy metal, the pellets made at $1100^{\circ}C$ were superior to the other pellets made under $1000^{\circ}C$. Immobilizing over 99.9% of 10ppm heavy metal solutions required I hour for arsenic, 2 hours for chrome, and 4 hours for copper. However, immobilizing capacity of cadmium was inferior to that of the other metals and it was decreased in reversely proportion to initial concentration of the solutions.

Analysis of the Stumpage Valuation for Pinus koraiensis Stands in the Research Forest of Kangwon National University

  • Woo, Hee-Sung;Choi, Sang-Hyun;Ahn, Seung-Il;Woo, Jong-Choon
    • Journal of Forest and Environmental Science
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    • v.28 no.1
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    • pp.24-29
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    • 2012
  • This paper assesses the stmpage value of Korean white pine (Pinus koraiensis) stands in the Research Forest of Kangwon National University. Assessment was done by means of the cost value method (Faustmann formula) for age class I, Glaser method for age class II-V, and inversion market method for age class over VI. Generally the value of stumpage is calculated by the inversion market method in the market. However, immature trees and middle age class trees are not assessed in market, and the Korean forest is not old enough to harvest. So, when forests are damaged by attacks from forest fire, blight and harmful insects, the forest cannot be compensated for the loss from the government or insurance company. For this reason, the value of all-age class trees are calculated by using appropriate methods. As a result, the value of age I class stands (0.3 ha) is calculated as 1,786,305 (won), age II-Vclass stands (22.1 ha) 206,677,975 (won) and age VI class and over stands (24.8 ha) 523,789,603 (won).

The Analysis of the Forest Community Structure of Mt. Minjuji (민주지산의 산림군집구조분석)

  • 최송현;조현서;이경재
    • Korean Journal of Environment and Ecology
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    • v.11 no.1
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    • pp.111-125
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    • 1997
  • To investigate the climax forest structure and to construct the ecological basic data, forty nine plots were set up and surveyed in Mt. Minjuji, Chungchongpukdo. According to the analysis of classification by TWINSPAN, the community was divided by seven groups of Pinus densiflora-Carpinus laxiflora-Quercus serrata(community I), Q. mongolica-Q. serrata-Platycarya strobilacea(community II), Q. mongolica(community III), Fraxinus mandshurica-Acer mono(community IV), Cornus controversa-F. mandshurica(community V), F. mandshurica-Carpinus cordata(community VI), and F. mandshurica-C. laxiflora(community VII). In the results of the analysis of species structure, similarity, diversity and DBH, except for community I~III, it was founede out broadleaves-mixed-climax forest. Constructed basic data will be applied to sustainable development such as ecotourism, nature trail etc.

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Newborn Screening for Lysosomal Storage Diseases in Taiwan

  • Lin, Hsiang-Yu;Chuang, Chih-Kuang;Lin, Shuan-Pei
    • Journal of mucopolysaccharidosis and rare diseases
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    • v.3 no.1
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    • pp.14-19
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    • 2017
  • Lysosomal storage diseases (LSDs) are a group of rare inherited metabolic disorders caused by the deficiency of specific lysosomal enzymes and subsequent accumulation of substrates. Enzyme deficiency leads to progressive intra-lysosomal accumulation of the incompletely degraded substances, which cause dysfunction and destruction of the cell and eventually multiple organ damage. Patients have a broad spectrum of clinical phenotypes which are generally not specific for some LSDs, leading to missed or delayed diagnosis. Due to the availability of treatment including enzyme replacement therapy (ERT) and hematopoietic stem cell transplantation for some LSDs, early diagnosis is important. ERT products have been approved with optimal outcomes for some LSDs in the recent decades, including Gaucher, Fabry, mucopolysaccharidosis (MPS) I, Pompe, MPS VI, MPS II, and MPS IVA diseases. ERT can stabilize the clinical condition, prevent disease progression, and improve the long-term outcome of these diseases, especially if started prior to irreversible organ damage. Based on the availability of therapy and suitable screening methods in the recent years, some LSDs, including Pompe, Fabry, Gaucher, MPS I, MPS II, and MPS VI diseases have been incorporated into nationwide newborn screening panels in Taiwan.

Effect of Rapid Thermal Process on Properties of CdS Thin Films for II-VI Compound Solar Cell (급속열처리 조건에 따른 II-VI 화합물 태양전지용 CdS 박막의 특성변화)

  • Choi, Si-Hyuk;Park, Seung-Beum;Kim, Jeong-Yeon;Song, Woo-Chang;Lim, Dong-Gun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.110-111
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    • 2009
  • 상온에서 밴드갭이 2.42 eV의 에너지를 가지며 직접 에너지 밴드갭을 갖는 고감도의 광전도체로 태양전지의 광투과 물질로 각광을 받고 있으며 광전도 cell로 연구되고 있는 CdS(Cadmium sulfide)를 용액 성장법(CBD)으로 제조하여 박막의 결정립의 향상과 박막내의 결함 등을 제거하기 위해 RTP(Rapid Thermal Process)를 이용하여 열처리 분위기 $N_2$, 처리시간 10분을 기준으로 열처리온도 ($300\;^{\circ}C$, $400\;^{\circ}C$, $500\;^{\circ}C$)를 변화시키며 박막의 전기적, 광학적 특성을 조사하였다. 캐리어 밀도가 급격히 낮아지고 이동도가 증가한 $500\;^{\circ}C$에서 $1.29\times10^3\;{\Omega} m$ 비저항을 나타냈다. 가시광선 영역에서 76.28%의 투과율을 보이는 특성을 나타내었다.

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CYTOTOXIC EFFECT OF SALVIA MILTIORRHJZA ROOT AGAINST L1210 CELL (단삼의 L1210 세포에 대한 세포 독성의 연구)

  • Sun Jung-Key;Shin Min-Kyo
    • Journal of Oriental Neuropsychiatry
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    • v.3 no.1
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    • pp.84-90
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    • 1992
  • Solvent and TLC-fractionations of the root of Salvia miltiorrhiza have yielded the results as follows ; Solvent fractions Petr. ether Ether Ethy1 acetate Water Control 100uL 0 0.2 35.1 41.9 43.0 50ul 0.7 3.7 37.2 42.0 TLC-fractionation and the Cytotoxic activity Fractions I II III IV V VI Petr. ehter Control 100uL13.0 7.1 16.8 1.2 30.9 23.2 0.5 48.3 50uL 37.1 26.1 30.0 20.1 45.7 27.2 29.7 Among the solvent fractions the petroleum ehter fraction corresponding to the concentration of 20ug/ml has showed the strongest Cytotoxic activity. (no cell survived) A double dilution of the fraction(10ug/ml) still showed strong activity.(0.2 cells survived) The ether fraction contained strong activity. Of the fraction which have veen obtained by a prcparative silicagel TLC I, II, III & IV were cytotoxic, but V and VI were inactive Howevcr, it is worthwhile to note that no one of these has no strong Cytotoxicity as the pertoleum ether fraction itself. This observation says that the active fractions could be additive or synergic to each other. The most active fraction, IV, was scrached out from the TLC and its UV-spectrum taken. The absorption maxima were 207 and 272 nm, indicating the presence of a flavanone strucuture.

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An Immunohistochemical study on the endocrine cells in the gastrointestinal tract of the snakehead, Ophicephalus argus (가물치 위장관 내분비세포에 관한 면역조직학적 관찰)

  • Kim, Jeong-mi;Lee, Jae-hyun
    • Korean Journal of Veterinary Research
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    • v.32 no.3
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    • pp.333-339
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    • 1992
  • The regional distribution and relative frequency of occurrence of endocrine cells in nine segments of the gastrointestinal(GI) tract of snakehead(Ophicephalus argus) were investigated by immunohistochemical methods using specific antisera against 5- hydroxyptrytamine(5-HT), somatostatin, gastrin/cholecystokinin(GAS/CCK), glucagon, bovine chromogranin, porcine chromogranin and insulin. Four types of immunoreactive cells for 5-HT, somatostatin, GAS/CCK and glucagon were observed in the GI tract. These cells were generally appeared in the mucosal epithelia or located at the interface of the mucosal epithelial layer and intestinal glandular region. 5-HT-immunoreactive(IR) cells were found in segment II, III, IV, V and VI, and the most numerous in segment IV. Somatostatin-IR cells were found in segment II, III, IV and V, and the most numerous in segment III. GAS/CCK-IR cells in segment VI, VII and glucagon-IR cells in segment III, IV, V were detected but a few in these segments. No bovine chromogranin-, porcine chromogranin- and insulin-IR cells were detected throughout the GI tract of the snakehead.

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Depositional Environments and Sequence Stratigraphy of estuary of the Nakdong River (낙동강 하구 점성토 지층의 층서와 퇴적환경)

  • Kim, Sung-Wook;Lee, Seung-Won;Lee, Jeong-Wan;Jo, Ki-Young;Kim, Yun-Tae;Kim, Jin-Seop
    • Proceedings of the Korean Geotechical Society Conference
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    • 2006.03a
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    • pp.882-887
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    • 2006
  • Sedimentological, geochemical, geophysical and micropaleontological analyses of 10 borehole cores were carried out to understand depositional environment and sequence stratigraphy of late Quaternary sedimentation in the estuary of the Nakdong River. Holocene Formation in study area is classified into five sedimentary units. Early Holocene freshwater lower pebbly sandy deposit(Unit I), lower muddy deposit(Unit II), middle thin sandy deposit(Unit III), upper muddy deposit(Unit VI), and upper sandy deposit(Unit V), in ascending order contolled by global sea-level change since interglacial period(about 15,000 yrs B.P.). Unit I deposited in erosional environments before marine trangression. Unit II and Unit VI composed of clay were deposited in cold and worm currents for marine trangression., respectively.

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