• Title/Summary/Keyword: IDA

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A Study on the Pb-contaminated Soil Remediation by Organic Acid Washing (유기산을 이용한 납 오염토양의 복원에 관한 연구)

  • 정의덕
    • Journal of Environmental Science International
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    • v.9 no.5
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    • pp.437-441
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    • 2000
  • A study on the removal of Pb ion from Pb-contaminated soil was carried out using ex-site extraction process. Tartaric acid (TA) and iminodiacetic acid sodium salt(IDA) as a washing agent were evaluated as a function of concentration reaction time mixing ratio of washing agent and recycling of washing agent. TA showed a better extraction performance than IDA. The optimum washing condition of TA and IDA were in the ratio of 1:15 and 1:20 between soil and acid solution during 1 hr reaction. The total concentrations of Pb ion by TA and IDA at three repeated extraction were 368.8 ppm and 267.5 ppm respectively. The recovery of Pb ion from washing solution was achieved by adding calcium hydroxide and sodium sulfide form the precipitation of lead hydroxide and lead sulfide and optimum amounts of sodium sulfide and calcium hydroxide were 7 g/$\ell$ for the TA washing solution and 4 g/$\ell$, 5g/$\ell$ for the IDA washing solution respectively. The efficiency of recycle for TA and IDA washing solution were 78.8% , 95.1%, and 89.2%, 96.6% at third extractions under $Na_2S$ and $Ca(OH)_2$, respectively.

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Weaning food practice in children with iron deficiency anemia (철결핍빈혈 영유아의 식이력 조사 및 이유지식의 평가)

  • Chang, Joo Hee;Cheong, Woo Sik;Jun, Yong Hoon;Kim, Soon Ki;Kim, Hung Sik;Park, Sang Kyu;Ryu, Kyung Ha;Yoo, Eun Sun;Lyu, Chuhl Joo;Lee, Kun soo;Lee, Kwang Chul;Lim, Jae Young;Choi, Du Young;Choe, Byung Kyu;Choi, Eun Jin;Choi, Bong Soon
    • Clinical and Experimental Pediatrics
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    • v.52 no.2
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    • pp.159-166
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    • 2009
  • Purpose : Iron deficiency anemia (IDA) is one of the most common nutritional deficiencies in children on a weaning diet. We investigated weaning practices in infants and children, as well as their mothers' knowledge about weaning. Methods : We investigated 129 children with IDA and 166 without IDA (aged 6-36 months) who had visited 10 university hospitals between March 2006 and July 2007. We investigated the hematologic values of both groups. A questionnaire on weaning was answered by the mothers of these children. Results : The hematologic values in the IDA group showed a significant difference from those in the comparison group (P<0.05). Children who were solely breastfed until 6 months of age were 85%, 34% (P<0.05), and weaning was started by 6.3, 6.4 months, respectively (P>0.05). Rice gruel, boiled rice, and fruit juice accounted for approximately 80% of the starting foods in both groups (P>0.05). Only 40% of the children in the IDA group had a balanced diet within a month, versus 38% in the comparison group. In response to questions about the necessity of iron-fortified foods for breast-fed infants, less than 50% of mothers in both groups answered correctly. In the IDA group, 42% showed serum ferritin less than 10 ng/mL, while 92% showed serum MCV less than 72 fL. Conclusion : In conclusion, collection of information on history should be thorough for feeding and selective examinations for IDA in high-risk groups. Considering the adaptation period, we suggest beginning children on a weaning diet at 45 months. In addition, we need to educate mothers on weaning practice, especially on the necessity of iron-fortified foods for breast-fed infants.

Prevalence and risk factors for vitamin D deficiency in children with iron deficiency anemia

  • Yoon, Jung Won;Kim, Sung Woo;Yoo, Eun Gyong;Kim, Moon Kyu
    • Clinical and Experimental Pediatrics
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    • v.55 no.6
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    • pp.206-211
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    • 2012
  • Purpose: The increasing prevalence of breast feeding has led to concerns about vitamin D deficiency (VDD) and iron deficiency anemia (IDA) in children. We evaluated the prevalence of VDD in a population of Korean children with IDA and assessed the risk factors for VDD in these children. Methods: A total of 79 children who were diagnosed with IDA were prospectively surveyed from April 2010 to March 2011. Data were collected by questionnaire, medical assessment, and laboratory tests, including measurement of 25-hydroxyvitamin D (25OHD), hemoglobin, and wrist radiography. Results: The median age was 22 months and 30% of the subjects were female. Over a half of subjects (58%) had subnormal vitamin D level (25OHD<30 ng/mL), and VDD (25OHD<20 ng/mL) was present in 39% of children. There was no difference in serum hemoglobin level between IDA patients with VDD and those without VDD. Most subjects (89%) were currently or had recently been breastfed and almost all subjects (97%) who had VDD received breastfeeding. Children with VDD were more likely to be younger than 2 years, to have been breastfed, and to have been tested in winter or spring. Multivariable analysis indicated seasonal variation was a significant independent risk factor for VDD in our IDA patients. Conclusion: Our results demonstrated that VDD has a high prevalence in Korean children with IDA. Primary care physicians should be aware of the possibility of VDD in children with IDA and should supplement the vitamin D as well as iron.

Developing a modified IDA-based methodology for investigation of influencing factors on seismic collapse risk of steel intermediate moment resisting frames

  • Maddah, Mohammad M.;Eshghi, Sassan
    • Earthquakes and Structures
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    • v.18 no.3
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    • pp.367-377
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    • 2020
  • Incremental dynamic analysis (IDA) widely uses for the collapse risk assessment procedures of buildings. In this study, an IDA-based collapse risk assessment methodology is proposed, which employs a novel approach for detecting the near-collapse (NC) limit state. The proposed approach uses the modal pushover analysis results to calculate the maximum inter-story drift ratio of the structure. This value, which is used as the upper-bound limit in the IDA process, depends on the structural characteristics and global seismic responses of the structure. In this paper, steel midrise intermediate moment resisting frames (IMRFs) have selected as case studies, and their collapse risk parameters are evaluated by the suggested methodology. The composite action of a concrete floor slab and steel beams, and the interaction between the infill walls and the frames could change the collapse mechanism of the structure. In this study, the influences of the metal deck floor and autoclaved aerated concrete (AAC) masonry infill walls with uniform distribution are investigated on the seismic collapse risk of the IMRFs using the proposed methodology. The results demonstrate that the suggested modified IDA method can accurately discover the near-collapse limit state. Also, this method leads to much fewer steps and lower calculation costs rather than the current IDA method. Moreover, the results show that the concrete slab and the AAC infill walls can change the collapse parameters of the structure and should be considered in the analytical modeling and the collapse assessment process of the steel mid-rise intermediate moment resisting frames.

Phosphoprotein Partitioning in Metal-Affinity Aqueous Two-Phase Systems and Prediction of Partitioning Behavior (금속 친화성 액 이상분계 시스템에서 Phsphoprotein분배 및 분배예측)

  • 정봉현
    • KSBB Journal
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    • v.9 no.3
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    • pp.279-286
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    • 1994
  • A mathematical model has been derived and used to describe phosphoprotein partitioning in Fe(III) IDA-PEG/dextran two-phase systems. This model includes the inhibitory effects of hydrogen and hydroxyl ion concentrations on protein partitioning. For aqueous two-phase partitioning experiments, the Al and A2 subcomponents of ovalbumin carrying two and one surface phosphoryl group(s) were purified using an immobilized metal ion affinity chromatography (IMAC). The ratio of partition coefficients in the presence and absence of Fe(III)IDA-PEG, K/Ko, increased in the pH range of 3.0 to 5.0 due to deprotonation of the second oxygen of the phosphoryl group, and above pH 5.0 declined steeply by the inhibitory binding of hydroxyl ions to the metal ion. This partitioning behavior was well described by the mathematical model. The binding constants for formation of the complex between the phosphoryl group and the Fe(III)IDA-PEG were found to be $6.1{\times}10^3M^{-1} and 2.3{\times}10^4M^{-1}$ in the top and bottom phases, respectively. These values are 3-5 times those for interaction of Cu(II)IDA-PEG with a single surface-accessible histidine.

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Seismic Fragility Functions for Steel Moment Resisting Frames using Incremental Dynamic Analyses (증분동적해석을 이용한 철골모멘트골조의 지진취약도 함수)

  • Lee, Seung-Won;Yi, Waon-Ho;Kim, Hyung-Joon
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.27 no.6
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    • pp.509-516
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    • 2014
  • Accuracy of seismic response evaluated by a capacity spectrum method (CSM) is generally known to be less than that by Incremental dynamic analysis (IDA). In this paper, a procedure for IDA based seismic fragility curves for steel moment resisting frames was suggested. This study compares seismic fragility curves using the suggested method (IDA method) with those using a CSM and intends to verify the validity of the IDA method. The shapes of both seismic fragility curves are similar in slight and moderate damage states. However, in the case of extensive and complete damage states, the fragility curves obtained from the IDA method presents a more steep slope due to less variation (or uncertainties). This is due to the fact that the IDA method can properly capture the structural response beyond yielding rather than the CSM.

Iron deficiency anemia as a predictor of coronary artery abnormalities in Kawasaki disease

  • Kim, Sohyun;Eun, Lucy Youngmin
    • Clinical and Experimental Pediatrics
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    • v.62 no.8
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    • pp.301-306
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    • 2019
  • Purpose: Coronary artery abnormalities (CAA) are the most important complications of Kawasaki disease (KD). Iron deficiency anemia (IDA) is a prevalent micronutrient deficiency and its association with KD remains unknown. We hypothesized that presence of IDA could be a predictor of CAA. Methods: This retrospective study included 173 KD patients, divided into 2 groups according to absence (group 1) and presence (group 2) of CAA. Odds ratios (ORs) with 95% confidence intervals (CIs) were calculated using a logistic regression model to estimate the association between CAA and other indicators. Due to collinearity between indicators of IDA, each indicator was paired with anemia in 3 models. Results: Serum iron, iron saturation, and ferritin concentration, the 3 indicators of IDA, were significantly higher in group 1 than in group 2. Three sets of models including anemia with iron indicators produced the OR of CAA of 3.513, 3.171, and 2.256, respectively. The 3 indicators of IDA were negatively associated with CAA, by OR of 0.965, 0.914, and 0.944, respectively. The areas under the curve (AUCs) of ferritin concentration, iron saturation, serum iron, anemia, and Kobayashi score were 0.907 (95% CI, 0.851-0.963), 0.729 (95% CI, 0.648-0.810), 0.711 (95% CI, 0.629-0.793), 0.638 (95% CI, 0.545-0.731), and 0.563 (95% CI, 0.489-0.636), respectively. Conclusion: Indicators of IDA, especially ferritin, were highly associated with CAA; therefore, they were stronger predictors of CAA than Kobayashi scores. IDA indicators can be used to predict CAA development and to suggest requirements for early interventions.

Anhydrous Polymer Electrolyte Membranes Prepared From Polystyrene-b-Poly (hydroxyl ethyl methacrylate) Block Copolymer (Polystyrene-b-Poly(hydroxyl ethyl methacrylate) 블록 공중합체를 이용한 무가습 고분자 전해질막)

  • Kim, Jong-Hak;Seo, Jin-Ah;Lee, Do-Kyung;Roh, Dong-Kyu;Shul, Yong-Gun
    • Membrane Journal
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    • v.19 no.4
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    • pp.302-309
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    • 2009
  • A block copolymer of polystyrene-b-poly (hydroxyl ethyl methacrylate), PS-b-PHEMA, was synthesized via atom transfer radical polymerization (ATRP) and crosslinked with 4,5-imidazole dicarboxylic acid (IDA) via esterification of the -OH groups of PHEMA in the block copolymer and the -COOH groups of IDA. Upon doping with $H_3PO_4$ to form imidazole-$H_3PO_4$ complexes, the proton conductivity of the membranes continuously increased as the content of $H_3PO_4$ increased. In addition, both the tensile strength and the elongation at break increased with IDA content. A proton conductivity of 0.01 S/cm at $100^{\circ}C$ was obtained for the PS-b-PHEMA/IDA/$H_3PO_4$ membrane with [HEMA]:[IDA]:[$H_3PO_4$] = 3:4:4 under anhydrous conditions. All of the PS-b-PHEMA/IDA/$H_3PO_4$ membranes were thermally stable up to $350^{\circ}C$, as revealed by thermal gravimetric analysis (TGA).

Enhanced Partitioning of Proteins in Metal-Affinity Aqueous Two-Phase Systems (금속 친화성 액 이상분계 시스템에서 단백질의 분배 향상)

  • Chung, Bong-Hyun;Park, Young-Hoon
    • Microbiology and Biotechnology Letters
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    • v.21 no.4
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    • pp.336-341
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    • 1993
  • In metal-affinify aqueous two-phase systems, protein partitioning is affected by a variety of parameters such as pH, the number of surface-accessible histidines, and the amount and partition coefficient of metallated polythylene glyco(PEG) ligand. To enhance partitioning of proteins with surface-accessible histidines, we have synthesized and used a (Cu(II)-ininodiacetic acid)$_2$-PEG20,000($Cu(II)_2IDA_2$-PEG20,000) as well as Cu(II)IDA-PEG5,000 as an affinity ligand. The partition coefficient of $Cu(II)_2-IDA_2$-PEG20,000 in a PEG5,000/dextran two-phase system was 30.1, which corresponded to a 3.8-fold increase over that of Cu(II)IDA-PEG5,000. The partitioning experiments were performed on four proteins, horse cytochrome c, S. cerevisiae cytochrome c, horse myoglobin, and sheep myoglobin. Partitioning of proteins which convey surface-accessible histidines was enhanced dramatically by the addition of $Cu(II)_2IDA_2$-PEG20,000 ligand. These results demonstrate that enhanced partitioning of metal-binding proteins in an aqueous two -phase system can by achieved by using an appropriate metallated PEG ligand.

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$^{51}V$ NMR and Cyclic Voltammetry Studies on the Interaction of Vanadate and N-Benzyliminodiacetate in Aqueous Solution (Vanadate와 N-Benzyliminodiacetate 리간드의 상호작용에 대한 $^{51}V$ 핵자기공명분광법과 순환전압 - 전류법 연구)

  • Park, Chul-Jin;Park, Sam-Su;Lee, Man-Ho
    • Analytical Science and Technology
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    • v.12 no.3
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    • pp.184-189
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    • 1999
  • $^{51}V$ NMR and cyclic voltammetry studies on the interaction of vanadate and N-benzyliminodiacetate (Bz-IDA) in aqueous solution have been studied. From the NMR spectra two $^{51}V$ NMR peaks resulting at -515.5 and -500.1 ppm, due to the complexations between vanadate(V) and Bz-IDA at pH 5. has been observed. From the cyclic voltammograms the reduction-oxidation of the vanadate(V) complex has been found to be one-electron reaction.

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