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Metal Complexes of Ambidentate Ligand (V). Nickel(II) Complexes of Bis(isonitrosobenzoylacetone)diimine Derivatives (Ambidentate 리간드의 금속착물 (제 5 보). Bis(isonitrosobenzoylacetone)diimine 유도체를 리간드로 하는 니켈(II)착물)

  • Jun Young-Sook;Baek Jae-Bum;Lee Man-Ho
    • Journal of the Korean Chemical Society
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    • v.35 no.1
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    • pp.46-50
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    • 1991
  • Some nickel(II) complexes have been derived from the condensation of isonitrosobenzoylacetone and diamine(ethylenediamine and propylenediamine) in the presence of metal ion. It is suggested that an isonitroso group(=N-O) of the ligand coordinates to metal through nitrogen atom to form a five-membered ring while other =N-O coordinates to metal through oxygen atom to form a six-membered ring in Ni(IBN)$_2$-en ((IBA)$_2$-en = N,N'-propylenebis(isonitrosobenzoylacetone imino)). But both isonitroso groups of the ligand coordinate to metal through nitrogen atoms to form five-membered rings in Ni(IBA)$_2$-pn ((IBA)$_2$-pn = N,N'-propylenebis(isonitrosobenzoylacetone imino)).

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An Extended UTAUT2 model to Explain the Adoption of Virtual Reality Technology in Health Centers: An Empirical Study Based in Riyadh

  • Algahtani, Manar;Altameem, Abdullah;Baig, Abdul Rauf
    • International Journal of Computer Science & Network Security
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    • v.21 no.3
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    • pp.219-228
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    • 2021
  • The adoption of new technology in any organization will represent change, and such change needs user acceptance for its successful implementation. Saudi Arabian health centers are no exception; therefore, the current study will investigate the adoption of new technology, namely that of virtual reality (VR), within health centers in Saudi Arabia and specifically in Riyadh City. This study explores the current state of VR technology adoption, factors that influence such adoption, and the extent of this technology's efficiency when it is used for vaccinating children. The data were collected from two samples: workers in vaccination clinics who responded to a survey and a group of children who participated in the VR technology experiment. The current study proposed a model based on the unified theory of acceptance and use of technology 2 (UTAUT2), with the addition of two variables: personal innovativeness and satisfaction. The results indicated that the respondents' perceptions regarding the health centers' infrastructure in terms of adopting VR were moderate. Among the factors affecting VR adoption, satisfaction, personal innovativeness, and behavioral intention were identified as vastly influential factors. From the eight hypotheses, six were found to be supported, with their factors significantly influencing behavioral intention with regard to VR technology adoption. Besides, the experiment concerning the use of VR technology on children verified the technique's high efficiency in terms of providing pain management and fear removal. These findings support the continuity of VR technology use, expand its future application fields, and integrate this study into the literature on technology acceptance models for VR adoption, as limited studies have covered this topic; consequently, this will benefit future research in this field.

Dose metrology: TLD/OSL dose accuracy and energy response performance

  • Omaima Essaad Belhaj;Hamid Boukhal;El Mahjoub Chakir;Meryeme Bellahsaouia;Siham Belhaj;Younes Sadeq;Mohammed Tazi;Tahar El Khoukhi;Maryam Hadouachi;Khaoula Laazouzi
    • Nuclear Engineering and Technology
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    • v.55 no.2
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    • pp.717-724
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    • 2023
  • An essential step in evaluating and comparing the performance of two passive radiation dosimeter types, thermosluminescent (TLD) and optically stimulated luminescence (OSL), used by workers in environments with ionizing radiation for individual radiological monitoring and control of external exposure at various times (cumulative dose for 1 month), is to compare the measured dose accuracy, energy response, and coefficient of variation. In fact this performance study consists in determining the accuracy of both R(10) and R(0.07) which are considered as the ratios of the measured dose (Hp(10) or Hp(0.07)) to the delivered dose (Hp(10) or Hp(0.07)) for each photon energy. The validity of the results of this test is based on the acceptance limits of the ICRP and the international standard IEC-62387. The relative energy response used is normalized to the 137Cs 662 keV energy to find which energy response is closest to the ideal case, and the coefficient of variation that allows to determine the statistical fluctuation of the Hp(10) and Hp(0.07) doses. The results of the accuracy test for the OSL and TLD dosimeters are acceptable because they fall within the ICRP limits. For the energy response, the OSL performs better than the TLD for Hp(10) and Hp(0.07), and for the coefficient of variation, the OSL satisfies the requirements of ISO 62387 for both Hp(10) and Hp(0.07), while the TLD satisfies these requirements only for the measurement of Hp (0.07).

Examination of the Impact of Substituting Germanium for Bismuth on the Energy Density and Electrical Conductivity of the Se60Ge40-xBix Alloy

  • Kareem Ali Jasim;Haider Sahi Hussein;Shaymaa Hashim Aneed;Ebtisam Mohammed Taqi Salman
    • Korean Journal of Materials Research
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    • v.34 no.6
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    • pp.267-274
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    • 2024
  • In this study, four different samples of Se60Ge40-xBix chalcogenides glasses were synthesized by heating the melt for 18 h in vacuum Pyrex ampoules (under a 10-4 Torre vacuum), each with a different concentration (x = 0, 10, 15, and 20) of high purity starting materials. The results of direct current (DC) electrical conductivity measurements against a 1,000/T plot for all chalcogenide samples revealed two linear areas at medium and high temperatures, each with a different slope and with different activation energies (E1 and E2). In other words, these samples contain two electrical conduction mechanisms: a localized conduction at middle temperatures and extended conduction at high temperatures. The results showed the local and extended state parameters changed due to the effective partial substitution of germanium by bismuth. The density of extended states N(Eext) and localized states N(Eloc) as a function of bismuth concentration was used to gauge this effect. While the density of the localized states decreased from 1.6 × 1014 to 4.2 × 1012 (ev-1 cm-3) as the bismuth concentration increased from 0 to 15, the density of the extended states generally increased from 3.552 × 1021 to 5.86 × 1021 (ev-1 cm-3), indicating a reduction in the mullet's randomness. This makes these alloys more widely useful in electronic applications due to the decrease in the cost of manufacturing.

Static analysis of the FGM plate with porosities

  • Benferhat, R.;Hassaine Daouadji, T.;Hadji, L.;Said Mansour, M.
    • Steel and Composite Structures
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    • v.21 no.1
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    • pp.123-136
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    • 2016
  • This work focuses on the behavior of the static analysis of functionally graded plates materials (FGMs) with porosities that may possibly occur inside the functionally graded materials (FGMs) during their fabrication. For this purpose a new refined plate theory is used in this work, it contains only four unknowns, unlike five unknowns for other theories. This new model meets the nullity of the transverse shear stress at the upper and lower surfaces of the plate. The parabolic distribution of transverse shear stresses along the thickness of the plate is taken into account in this analysis; the material properties of the FGM plate vary a power law distribution in terms of volume fraction of the constituents. The rule of mixture is modified to describe and approximate material properties of the FG plates with porosity phases. The validity of this theory is studied by comparing some of the present results with other higher-order theories reported in the literature, the influence of material parameter, the volume fraction of porosity and the thickness ratio on the behavior mechanical P-FGM plate are represented by numerical examples.

Free vibration of functionally graded plates resting on elastic foundations based on quasi-3D hybrid-type higher order shear deformation theory

  • Zaoui, Fatima Zohra;Tounsi, Abdelouahed;Ouinas, Djamel
    • Smart Structures and Systems
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    • v.20 no.4
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    • pp.509-524
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    • 2017
  • In this article, a free vibration analysis of functionally graded (FG) plates resting on elastic foundations is presented using a quasi-3D hybrid-type higher order shear deformation theory. Undetermined integral terms are employed in the proposed displacement field and modeled based on a hybrid-type (sinusoidal and parabolic) quasi-3D HSDT with five unknowns in which the stretching effect is taken into account. Thus, it can be said that the significant feature of this theory is that it deals with only 5 unknowns as the first order shear deformation theory (FSDT). The elastic foundation parameters are introduced in the present formulation by following the Pasternak (two-parameter) mathematical model. Equations of motion are obtained via the Hamilton's principles and solved using Navier's method. Accuracy of the proposed theory is confirmed by comparing the results of numerical examples with the ones available in literature.