• Title/Summary/Keyword: I-V polarization

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Analysis of Aging Insulation Characteristics of 3.3[kV] Class Induction Motor with AC Breakdown Test (절연파괴시험법을 이용한 3.3[kV] 유도전동기의 절연물 열화특성 분석)

  • Lee, Ju;Kim, Hyun-Il;Kim, Youn-Hyun;Son, Yeoung-Gyu
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.21 no.10
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    • pp.141-149
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    • 2007
  • This paper introduce to improve the reliability of the expected service life and the insulation condition evaluation of the high voltage induction motors by assessing, comparing and analyzing the correlation between the dielectric properties of the off-line insulation diagnostic test and dielectric strength on the insulation breakdown test. The insulation diagnostic tests include insulation resistance, polarization index(P.I.), dissipation factor($tan{\delta}$), maximum partial discharges($Q_{max}$) and AC breakdown test. This study evaluated the correlation between insulation diagnostic test and AC breakdown test for stator winding of high voltage induction motor. On the basis of these test results, we expect that this study can be used for effectively assessing the results of insulation diagnostic tests for similar class induction motors in service at industrial field.

Numerical Analysis of the Prediction of Zincate Concentration at a Zinc Electrode with Electrolyte Flow Conditions in a Zinc Air Fuel Cell (전해질 유동 조건에 따른 아연공기전지 아연극 표면의 Zincate 이온 농도 예측을 위한 수치해석적 연구)

  • Kim, Jung-Yun;Lee, Ho-Il;Oh, Tae-Young;Park, Sang-Min
    • Journal of the Korean Electrochemical Society
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    • v.14 no.4
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    • pp.231-238
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    • 2011
  • In this work, the numerical analysis for the zincate behavior at a zinc electrode with an electrolyte flow was carried out for a ZAFC. The Nernst-Planck equation with a boundary condition of Butler-Volmer type was adopted to describe electrochemical effects of mass transfer, migration, kinetics of electrode. The Navier-Stokes equation, coupling to the Nernst-Planck equation, is also applied to describe the internal electrolyte flow fields. The validity of the numerical model is proved through the comparative analysis between numerical and experimental results. The concentration of zincate and the current density were also investigated at a zinc anode according to various electrolyte velocities. We have found the concentration of zincate decreased and the current density increased with an increase in the electrolyte velocity.

VALIDATION OF SEA ICE MOTION DERIVED FROM AMSR-E AND SSM/I DATA USING MODIS DATA

  • Yaguchi, Ryota;Cho, Ko-Hei
    • Proceedings of the KSRS Conference
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    • 2008.10a
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    • pp.301-304
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    • 2008
  • Since longer wavelength microwave radiation can penetrate clouds, satellite passive microwave sensors can observe sea ice of the entire polar region on a daily basis. Thus, it is becoming popular to derive sea ice motion vectors from a pair of satellite passive microwave sensor images observed at one or few day interval. Usually, the accuracies of derived vectors are validated by comparing with the position data of drifting buoys. However, the number of buoys for validation is always quite limited compared to a large number of vectors derived from satellite images. In this study, the sea ice motion vectors automatically derived from pairs of AMSR-E 89GHz images (IFOV = 3.5 ${\times}$ 5.9km) by an image-to-image cross correlation were validated by comparing with sea ice motion vectors manually derived from pairs of cloudless MODIS images (IFOV=250 ${\times}$ 250m). Since AMSR-E and MODIS are both on the same Aqua satellite of NASA, the observation time of both sensors are the same. The relative errors of AMSR-E vectors against MODIS vectors were calculated. The accuracy validation has been conducted for 5 scenes. If we accept relative error of less than 30% as correct vectors, 75% to 92% of AMSR-E vectors derived from one scene were correct. On the other hand, the percentage of correct sea ice vectors derived from a pair of SSM/I 85GHz images (IFOV = 15 ${\times}$ 13km) observed nearly simultaneously with one of the AMSR-E images was 46%. The difference of the accuracy between AMSR-E and SSM/I is reflecting the difference of IFOV. The accuracies of H and V polarization were different from scene to scene, which may reflect the difference of sea ice distributions and their snow cover of each scene.

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Ferroelectric and Structural Properties of Nd-substituted $Bi_4Ti_3O_{12}$ Thin Films Fabricated by MOCVD

  • Kang, Dong-Kyun;Park, Won-Tae;Kim, Byong-Ho
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2006.10a
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    • pp.166-169
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    • 2006
  • A promising capacitor, which has conformable step coverage and good uniformity of thickness and composition, is needed to manufacture high-density non-volatile FeRAM capacitors with a stacked cell structure. In this study, ferroelectric $Bi_{3.61}Nd_{0.39}Ti_3O_{12}$ (BNT) thin films were prepared on $Pt(111)/Ti/SiO_2/Si$ substrates by the liquid delivery system MOCVD method. In these experiments, $Bi(ph)_3$, $Nd(TMHD)_3$ and $Ti(O^iPr)_2(TMHD)_2$ were used as the precursors and were dissolved in n-butyl acetate. The BNT thin films were deposited at a substrate temperature and reactor pressure of approximately $600^{\circ}C$ and 4.8 Torr, respectively. The microstructure of the layered perovskite phase was observed by XRD and SEM. The remanent polarization value (2Pr) of the BNT thin film was $31.67\;{\mu}C/cm^2$ at an applied voltage of 5 V.

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Effect of Composition on Electrical Properties of SBT Thin Films Deposited by Reactive Sputtering (Reactive Sputtering으로 제조된 /SrBi_2Ta_2O_9$박막의 전기적 특성에 미치는 조성의 영향)

  • Park, Sang-Sik;Yang, Cheol-Hun;Chae, Su-Jin;Yun, Son-Gil;Kim, Ho-Gi
    • Korean Journal of Materials Research
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    • v.6 no.9
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    • pp.931-936
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    • 1996
  • 비휘발성 메모리 소자에의 적용을 위한 SrBi2Ta2O9(SBT)박막이 고순도의 Sr, Bi, Ti 금속타겟을 사용하여 Pt/Ti/SiO2/Si 기판 위에 reactive sputtering 법에 의해 증착되었다. 조성의 영향을 평가하기 위하여 Bi 타겟에 인가되는 전원의 변화와 열처리에 따른 C-F(capacitance-frequency), P-E(polarization-electric field), I-V(current-voltage)등의 전기적 특성이 조사되었다. Bi의 양이 증가함에 따라 Bi layer 구조를 나타내는 (105)회절 피크가 증가하였고 $700^{\circ}C$, 산소분위기에서 1시간 동안 열처리후 Sr과 Bi가 심하게 휘발되었으며 박막의 미세구조는 다공질이 되었다. 이러한 이유로 열처리된 박막의 누설 전류 밀도는 증가하였다. 열처리된 시편의 조성은 거의 화학양론비를 이루었으며 4.5$\mu$C/$\textrm{cm}^2$의 Pr값을 갖는 강유전(ferroelectric)특성을 나타내었다.

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Effects of environmental temperature on the performance of direct methanol fuel cell for vehicles (외부온도가 수송용 메탄올연료전지 성능에 미치는 영향)

  • Han, Chang-Hwa;Jung, Dae-Seung;Choi, Ji-Sun;Han, Sang-Hun;Lee, Joong-Hee
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.176-179
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    • 2009
  • The performance of direct methanol fuel cells is affected by operating conditions such as, methanol feeding temperatures, methanol concentrations, and methanol flow rates during the operation in different environmental conditions. In this study, effects of the environmental temperature on performance of direct methanol fuel cells have been investigated in order to test a applicability of direct methanol fuel cell to the vehicle. The environmental temperature (ET) was varied from $-20^{\circ}C$ to $+30^{\circ}C$. The inside fuel cell temperature (CT) during test at various operating conditions was monitored and the performance of fuel cell was measured in the I-V polarization curve. With increasing the ET, the performance of the fuel cell was significantly improved and the CT also almost linearly increased. However, at below $0^{\circ}C$ ET, the DMFC showed very poor performance and needed to control CT or methanol feeding temperature (MFT), methanol flow rate(MFR) to obtain enough power of the vehicle.

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A Study on the Electrode Charcteristics of the Fluornated AB$_2$ Type Hydrogen Storage Alloys (불화 처리된 AB$_2$계 수소저장합금의 전극특성에 관한 연구)

  • 박호영;이명호;조원일;조병래;이성래;주재백;윤경석
    • Journal of the Korean institute of surface engineering
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    • v.30 no.4
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    • pp.262-271
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    • 1997
  • Nickel-matal hydride(Ni-MH) batteries are receiving attention as non-pollunting. high performance rehargeable energy stoage system. The performance of Ni-Mh is significantly influenced by the hydrogen storage alloy materiels used as an anode material. Recently, having discharge capacities higher than the $AB_5$-type hydrogen storage alloys, the Zr-based $AB_2$-Type hydrogen storage alloys has remaining problems regarding cycle life and self-dischareg. These problems need to be solved by improvements in the alloy design and/or surface treatment. This work investiggates the effects the effects of surface property by fluorination on $Zr_{0.7}Ti_{0.3}V_{0.4}Mn_{0.4}Ni{1.2}$ composittion $AB_2$-Type hydrogen storage alloys. EPMA, SEM and AES techniques were used for surface analysis, and the crystal structure was characterized by constant current cycling test and potential sweep methods. Fluorination was found to be effective when La-was incorporated into the alloy, and has unique morphology, higher reactivity, and at the same time formed a protective film. Through, fluorination, the cycle life of an electrode was found to increase significantly, charge/discharge characteristics of the electrode the potential difference between the charge/discharge plateau, i.e polarization(overpotential)were improved.

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Degradation of Polymer Electrolyte Membrane under Low Current/Low Humidity Conditions (저전류/저가습 조건에서 고분자전해질 막 열화)

  • Kim, Tae-Hee;Lee, Jung-Hun;Lee, Ho;Lim, Tae-Won;Park, Kwon-Pil
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.2
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    • pp.157-163
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    • 2007
  • During PEMFC operation, low current and low humidity conditions accelerate the degradation of perfluorosulfonic acid membrane. But, there have been no studies that clearly explain why these conditions accelerate the membrane degradation. In this study, the hydrogen permeability through the membrane, I-V polarization of MEA, fluoride emission rate(FER) in effluent water were measured during cell operation under low current densities and low relative humidity(RH). The experimental results were evaluated with oxygen radical mechanism the most commonly known for membrane degradation. It seems that low RH of anode is a good condition for $H{\cdot}$ radical formation on the Pt catalyst and the low current condition accelerates the $H{\cdot}$ to form $HO_2{\cdot}$ radical attacking the polymer membrane.

Fabrication of Nd-Substituted Bi4Ti3O12 Thin Films by Metal Organic Chemical Vapor Deposition and Their Ferroelectrical Characterization

  • Kim, Hyoeng-Ki;Kang, Dong-Kyun;Kim, Byong-Ho
    • Journal of the Korean Ceramic Society
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    • v.42 no.4
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    • pp.219-223
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    • 2005
  • A promising capacitor, which has conformable step coverage and good uniformity of thickness and composition, is needed to manufacture high-density non-volatile FeRAM capacitors with a stacked cell structure. In this study, ferroelectric $Bi_{3.61}Nd_{0.39}Ti_3O_{12}$ (BNdT) thin films were prepared on $Pt(111)/TiO_2/SiO_2/Si$ substrates by the liquid delivery system MOCVD method. In these experiments, $Bi(ph)_{3}$, $Nd(TMHD)\_{3}$ and $Ti(O^iPr)_{2}(TMHD)_{2}$ were used as the precursors and were dissolved in n-butyl acetate. The BNdT thin films were deposited at a substrate temperature and reactor pressure of approximately $600^{\circ}C$ and 4.8 Torr, respectively. The microstructure of the layered perovskite phase was observed by XRD and SEM. The remanent polarization value (2Pr) of the BNdT thin film was $31.67\;{\mu}C/cm^{2}$ at an applied voltage of 5 V.

Mechanical and Electrical Performance of Anode-Supported Solid Oxide Fuel Cells during Thermal Cyclic Operation (열 사이클에 따른 고체산화물 연료전지의 기계적 및 전기적 특성)

  • Yang, Su-Yong;Park, Jae-Keun;Lee, Tae-Hee;Yu, Jung-Dae;Yoo, Young-Sung;Park, Jin-Woo
    • Journal of the Korean Ceramic Society
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    • v.43 no.12 s.295
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    • pp.775-780
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    • 2006
  • Mechanical and electrical performance of anode-supported SOFC single cells were analyzed after thermal cyclic operation. The experiments of thermal cyclic cell-operation were carried out four times and performance of each cell was measured at different temperatures of 650, 700, and $750^{\circ}C$, respectively. As increasing the number of thermal cycle test, single cells showed poor I-V characteristics and lower 4-point bending strength. The anode polarization was also measured by AC-impedance analysis. The observation of the microstructure of the anodes in single cells proved that the average particle size of Ni decreased and the porosity of anode increased. It is thought that the thermal cycle caused the degradation of performance of single cells by reducing the density of three-phase boundary region.