• Journal of the Korean Solar Energy Society
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• v.35 no.4
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• pp.17-24
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• 2015

The formation of heat islands causes high energy demand for space cooling and peak cooling loads in conditioned buildings. High-temperature fluctuations on a building roof may cause mechanical stress and increase surface deterioration. Thermal energy storage (TES) systems using microencapsulated phase-change materials (MPCMs) have been recognized as one of the most advanced energy technologies for enhancing the energy efficiency and sustainability of buildings. In this study, we prepared MPCM/paint composites for mitigating the heat island effect and reducing peak temperature. In addition, we carried out thermal and physical analysis of prepared MPCM composite samples by means of SEM, FTIR spectroscopy, DSC, and TGA. Further, we evaluated the dynamic heat transfer performance of heat-storage tiles painted with 10 g of heat-storage paint. From the obtained results, we deduced that MPCM/hydrophilic paint composites are more applicable to various fields, including the building sector, than MPCM/hydrophobic paint composites. On the basis of SEM and FTIR spectroscopy results, we concluded that materials with hydrophilic properties are more compatible with MPCMs than those with hydrophobic properties. In addition, DSC analysis results revealed that MPCM/hydrophilic paint composites have better compatibility, higher latent heat capacity, and better thermal properties than other composites. TGA results showed that hydrophilic-paint-based composites have higher thermal durability than hydrophobic-paint-based composites. Finally, a lot of MPCM-loaded heat-storage tiles showed lower peak temperatures at all measurement positions.

• Journal of Korean Society on Water Environment
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• v.30 no.6
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• pp.605-611
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• 2014

This research was carried out to examine the concentration and fate of dissolved organic matter due to the increased detention time in middle and down stream of the Nakdong River. Aldo the characteristics of biodegradation of DOM were investigated according to the various water sources. The approaches used to characterize DOM biodegradability include the changes in DOC concentration and DOM fraction. Long-term biodegradation test for each organic source was also conducted. As the result, maximum 50% of DOC was reduced during the first 30 days of biodegradation tests. After 30 days, biodegradation of organic matter was continuously progressed, as showing continuous reduction of DOC. While DOC concentration was reduced, SUVA values for the organic matters were increased. Properties of dissolved organic matter by water sources also showed decreasing hydrophilic components while showing increased hydrophobic components. The more rapid reduction of the hydrophilic components than hydrophobic components might be due to the preferential degradation of the hydrophilic components by microorganisms during biodegradation process.

• Journal of Hydrogen and New Energy
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• v.17 no.4
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• pp.379-388
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• 2006

Two mesophilic trickling bed bioreactors filled with two different types of media, hydrophilic- and hydrophobic-cubes, were designed and conducted for hydrogen production under the anaerobic fermentation of sucrose. Each bioreactor consisted of the column packed with polymeric cubes and inoculated with heat-treated sludge obtained from anaerobic digestion tank. A defined medium containing sucrose was fed by the different hydraulic retention time(HRT), and recycle rate. Hydrogen concentrations in gas-phase were constant, averaging 40% of biogas throughout the operation. Hydrogen production rate was increased till $10.5\;L{\cdot}h^{-1}{\cdot}L^{-1}$ of bioreactor when influent sucrose concentrations and recycle rates were varied. At the same time, the hydrogen production rate with hydrophobic media application was higher than its hydrophilic media application. No methane was detected when the reactor was under a normal operation. The major fermentation by-products in the liquid effluent of the both trickling biofilters were acetate, butyrate and lactate. In order to run in the long term operation of both reactor filled with hydrophilic and hydrophobic media, biofilm accumulation on hydrophilic media and biogas produced should be controlled through some process such as periodical backwashing or gas-purging. Four sample were collected from each reactor on the opposite hydrogen production rate, and their bacterial communities were compared by terminal restriction fragment length polymorphism (T-RFLP) analysis of PCR products generated using bacterial 16s rRNA gene primers (8f and 926r). It was expressed a marked difference in bacterial communities of both reactors. The trickling bed bioreactor with hydrophobic media demonstrates the feasibility of the process to produce hydrogen gas. A likely application of this reactor technology can be hydrogen gas recovery from pre-treatment of high carbohydrate-containing wastewaters.

• Korean Chemical Engineering Research
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• v.45 no.5
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• pp.500-505
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• 2007

The objectives of this research were to (1) identify the membrane fouling potential due to different fractions of NOM (2) correlate the physicochemical properties of NOM and membranes with the adsorption of humic substances on membrane (4) find out the effect of membrane physical and chemical washing according to membrane material. The static adsorption test and adsorption test showed that hydrophobic organics adsorbed much more quickly than hydrophilic organics. In case of the effect of membrane properties on the adsorption of organic fractions, the adsorption rate ratio(a) of hydrophobic membrane (0.016, 0.077) was greater than that of hydrophilic membrane (0.010, 0.033) regardless of the kind of organic fractions. This suggests that the UF membrane fouling were occurred mainly by internal pore size decreasing due to adsorption of organic into pore surface for hydrophobic membrane, and by sieving of organics and forming a gel layer on the membrane surface for hydrophilic membrane. In conclusion, the decrease in the pore volume, which was caused by the organic adsorption into the internal pore, was greater with the hydrophobic membrane than with the hydrophilic membrane. In case of the effect of membrane properties on permeate flux, the rate of flux decline for the hydrophobic membrane was significantly greater than that for the hydrophilic membrane.

• Proceedings of the KSME Conference
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• 2008.11a
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• pp.1742-1746
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• 2008

An EHD (Electro-Hydro-Dynamic) jet for electrostatic inkjet head shows advantages to print micro-size patterns using various inks because it can generate sub-micron droplets and can use highly viscous inks. Thus, many researchers in industrial fields are concerned about the EHD jet in these days. Since the basic principle of the EHD jet is to form a droplet from an apex of meniscus at the end of the nozzle, the ejection mechanism can be changed by the shape of the meniscus. The stable ejection of the droplet is greatly affected by the shape of the meniscus which is also influenced by surface characteristics of the nozzle, electric potential and ink properties. Experiments have been performed using the nozzles with hydrophilic and hydrophobic coatings in this study. The hydrophobic nozzle forms the stable droplets in wider range of the electric potential than the hydrophilic nozzle does.

• Journal of the Korean Society for Marine Environment & Energy
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• v.16 no.2
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• pp.82-87
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• 2013

Effects of material surface property, hydrophobic or hydrophilic, on the bio-fouling occurred on the bodies submerged in the sea water are investigated experimentally. 4 test models are used in the experiment, which includes aluminum foil in common use, AAO applied hydrophobic surface, HDFS coated hydrophobic surface and hydrophilic surface. Hydrophobic surfaces with numerous micro & nano-scale pillars on it seems to play very important role of preventing them from fouling in initial stage while the effects disappear in long term sense of fouling process. It is concluded that the surface hydrophobicity retards the initial fouling until the fouling thickness is smaller than the heights of the pillars on it but the effects diminish with the fouling proceeds so that the thickness grows bigger than the pillar heights.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.19 no.6
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• pp.288-292
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• 2009

Hydrophobic/hydrophilic patterned substrates were fabricated on a glass substrate by a liquid phase deposition (LPD) method. Hydrophobic surface was obtained by modifying ZnO thin films with a rough surface using a fluoroalkyltrimethoxysilane (FAS) and hydrophilic surface was prepared by decomposing FAS on an exposed to UV light. The hexagonal ZnO rods were perpendicularly grown by LPD method on glass substrates with a ZnO seed layer. The diameter and thickness of hexagonal ZnO rods were increased as a function of increases of immersion time. The surface morphology, thickness, crystal structure, transmittance and contact angle of prepared ZnO thin films were measured by field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), UV-visible spectrophotometer (UV-vis) and contact angle measurement. Hydrophilic ZnO thin films with a contact angle of $20^{\circ}{\sim}30^{\circ}$ were changed to a hydrophobic surface with a contact angle of $145^{\circ}{\sim}161^{\circ}$ by a FAS surface treatment. Prepared hydrophobic surface was pattered by an irradiation of UV light using shadow mask with $300\;{\mu}m$ or 3 mm dot size. Finally, the hydrophobic surface exposed to UV light was changed to a hydrophilic surface.

• Journal of Korean Society on Water Environment
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• v.26 no.6
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• pp.976-985
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• 2010

In this study, characteristics of dissolved organic matter (DOM) from Lake Paldang and seven other DOM sources (lake plankton, plants, soil, composite, treated sewage) were studied using XAD resin fractionation and 28-day microbial incubation experiment. Distribution patterns of DOM-fractions, which include hydrophilic acids (HiA), hydrophilic bases (HiB), hydrophilic neutrals (HiN), hydrophobic acids (HoA), hydrophobic neutrals (HoN) and the extent of DOM biodegradation (i.e., biodegradability) were different depending on the origins of the DOM samples. The DOM distribution pattern and the biodegradability were found to be effective for distinguishing the different DOM sources. The biodegradability (%) had negative correlations with the content (%) of hydrophobic fractions (Ho) and specific UV absorbance of DOM, which indicate that the Ho fractions contain more aromatic carbon structures and relatively stable during biodegradation, irrespective of the sources. To gain additional insight into the microbial transformation of the DOM, we also investigated the changes in the fraction's distribution for plankton, leaf litter and composite samples after the incubation. The results showed that biodegradation of hydrophilic fraction (Hi) causes an increase in the proportion of Ho (HoA, HoN), while biodegradation of HoA increases the HoN production.

• Journal of the Korean Geosynthetics Society
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• v.21 no.4
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• pp.93-100
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• 2022

This study describes the evaluation results on the effect of soil particle surfaces coated with various hydrophobic conditions on spectral information according to water content. Wettability test and spectral information evaluation test were performed on the hydrophobic coated standard sand. When the standard sand was coated with 1%, 3%, and 5% hydrophobic, the contact angles of sand-water interface were 130°~143°, 129°~144°, and 131°~144°, respectively. This means that the contact angle increased as the degree of hydrophobic coating increased at the same drying time, but the range of the contact angle had the same wettability. This means that the contact angle increases as the hydrophobic coating degree increases at the same drying time, whereas the contact angle range has the same wettability. As a result of spectral information evaluation, the maximum spectral reflectance of the dried sand with hydrophobic condition decreased compared to that of the hydrophilic sand, as the degree of hydrophobic increased. However, the maximum spectral reflectance was increased by increasing the degree of hydrophobic under the same water content conditions.

• Journal of Pharmaceutical Investigation
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• v.39 no.1
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• pp.1-6
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• 2009

To overcome the stability problem of hydrophilic quantum dot (Q-dot), cellular uptake of hydrophobic instead of hydrophilic Q-dot was studied in the hope to find a simple method to use Q-dot as a cellular imaging probe. Hydrophobic Q-dot and poly-L-lactic acid (PLLA) were co-dissolved in chloroform to prepare stable films. Due to the cellular compatibility of PLLA, adherent cells were cultured on the film to observe the degree of Q-dot uptake and cytotoxicity of the prepared films. The results show that Q-dots were absorbed into NIH3T3 and EMT6 cells. Cellular uptake was also observed when hydrophobic Q-dots were coated directly on a glass plate. PLLA/Q-dot film and Q-dot coated on glass plate did not show major cytotoxicity. In vivo tumor model was also used to show the uptake of Q-dot from the PLLA/Q-dot film to the tumor site.