• 제목/요약/키워드: Hydroperoxide

검색결과 283건 처리시간 0.026초

수용성 절삭유의 Copper Alloy Metal Fiber에 의한 항균 특성에 관한 연구 (A Study on the Antimicrobial Activity of Copper Alloy Metal Fiber on Water Soluble Metal Working Fluids)

  • 송주영;이상호;박근호
    • 한국응용과학기술학회지
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    • 제24권3호
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    • pp.233-237
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    • 2007
  • This study is focused on the possibility of copper alloy metal fiber for an antimicrobial activity in the water soluble metal working fluids. Electrochemical potential of Cu/Zn ion is -268mV, and easily makes radicals with molecular oxygen. Especially, hydroperoxide radical shows strong toxicity to the strains. Plasma membrane causes conformational change when hydroperoxide radical binds to plasma membrane. Elution of copper ion from copper alloy metal fiber is detected in metal working fluid. As a result antimicrobial activity of copper alloy metal fiber in metal working fluid is superior to that of copper fiber.

Oxidation of Dibenzothiophene Catalyzed by Surfactant-Hemoprotein Complexes in Anhydrous Nonpolar Organic Solvents

  • Ryu, Keun-Garp;Chae, Young-Rae;Kwon, O-Yul
    • Journal of Microbiology and Biotechnology
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    • 제13권5호
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    • pp.647-650
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    • 2003
  • In anhydrous organic solvents, the complexes formed between AOT (dodecylbenzene sulfuric acid sodium salt) and hemoproteins, such as hemoglobin, myoglobin, or cytochrome c, displayed remarkably higher activity than the hemoprotein powders to oxidize dibenzothiophene, a model compound of organic sulfurs contained in fossil fuels. In slightly hydrophobic organic solvents, such as ethyl acetate and butyl acetate, dibenzothiophene was completely oxidized catalytically by the cytochrome c-AOT complex with cumene hydroperoxide (${\alpha},{\alpha}-dimethylbenzyl$ hydroperoxide) as an oxidant. In highly hydrophobic organic solvents, such as decane and hexadecane, however, the activity of the cytochrome c-AOT complex decreased, presumably due to the aggregation of the hemoprotein-AOT complex in these solvents.

산화적 스트레스에 대한 Bacillus subtilis의 thiol peroxidase 유전자의 생리적인 기능 (Physiological Roles of Bacillus subtilis thiol peroxidase gene in response to oxidative stress)

  • 김하근;김성진
    • 자연과학논문집
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    • 제15권1호
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    • pp.57-67
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    • 2005
  • 산화적 스트레스에 대한 Bacillus subtilis의 thiol peroxidase 유전자의 생리적인 기능을 연구하기 위해 thiol peroxidase 유전자의 기능이 손상된 녹아웃 돌연변이주를 상동성 재조합에 의해 제조하였다. 호기적 조건에서 배양할 때 야생형과 녹아웃 돌연변이주 사이에는 성장속도에서 차이를 관찰할 수 없었다. 그러나 paraquat 처리할 때와는 달리 $H_2O_2$와 cumene hydroperoxide (CHP)에 의한 산화적 스트레스에 대해 역할을 하고 있음을 시사하는 결과이다.

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리놀레산 과산화물이 펩신 활성도에 미치는 영향 (Effect of Linoleate Hydroperoxide on Pepsin Activity)

  • 최갑성;김재욱;문태화
    • 한국식품과학회지
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    • 제23권2호
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    • pp.224-228
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    • 1991
  • 리놀레산 과산화물이 펩신의 활성도에 미치는 영향을 실험한 결과 여러 온도와 pH 조건하에서 리놀레산 과산화물에 의해 펩신 활성도는 감소되었다. 또한, 각종 라디칼 소거제와 금속 이온 존재하에서 펩신 활성을 측정한 결과와 전기영동 결과에 비추에 볼 때 효소의 활성감소는 시스템내에 존재했던 라디칼에 의한 효소자체의 손상에서 비롯된 것으로 생각되었다.

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Erythrocyte Ghost의 광산화반응에 미치는 인삼추출물의 영향 (Effect of Ginseng Extracts on Photosensitized Peroxidation of Human Erythrocyte Ghosts)

  • 백태홍;천현자;강병수
    • Journal of Ginseng Research
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    • 제14권1호
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    • pp.30-35
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    • 1990
  • The photooxidation of human erythrocyte ghosts has been studied and the effects of ginseng water extract on it have been investigated. In the presence of photosensitizer, rose bengal, human erythrocyte ghosts have caused photooxidation by lO2 and produced lip)id hydroperoxides. Ginseng water extract and d-${\alpha}$-tocofherol have inhibited photooxidation, ,whereas ascorbic acid has developed in low concentrations but inhibited in high concentrations. On the other hand, amounts of lipid hydroperoxide produced by photooxidation were decreased by addition of catalase after irradiation and according to sequential addition of ginseng water extract into it, the formation of lipid hydrolleroxide was decreased simultaneously.

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유기 과산화물에 의한 메탄올 폭발 사례 연구 (A case study of methanol explosion by metal hydroperoxid)

  • 원유존;강경식
    • 대한안전경영과학회지
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    • 제7권5호
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    • pp.119-133
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    • 2005
  • In the June, 1991, there was the explosion in which methanol rectified column as a part of the new surface active agent's manufacturing processes. The type of explosion was estimated as the 'detonation'. The methanol rectified column was ruined, and broken pieces of the column were scattered within 900m. Also, there were victims such as the two deads and thirteen wounded persons. The cause of the explosion was heat explosion by being concentrated locally from 0.1% to several tens% of supply fluid at Metal Hydroperoxide, which was produced by methanol and hydrogen peroxide used as the bleach of surface active agent, during the operation stoppage process of methanol rectified column.

Protective Effect of Stilbenes on Oxidative Damage

  • Na, Min-Kyun;Min, Byung-Sun;Bae, Ki-Hwan
    • Natural Product Sciences
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    • 제13권4호
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    • pp.369-372
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    • 2007
  • Oxidative stress induced by reactive oxygen species (ROS) has been suggested to be the cause of various degenerative diseases as well as aging. To evaluate the antioxidant potential of stilbenes, we have investigated the cytoprotective effect of 10 stilbenes derived from plants on the oxidative stress induced by tertiary butyl hydroperoxide (t-BuOOH). Of the stilbenes tested, piceatannol (3) showed the most potent activity, which was further investigated using an animal model. When 3 (30 or 10 mg/kg) was topically administered prior to UVB irradiation, the amount of the thiobarbituric acid reactive substances (TBARS) was significantly reduced compared to that of the control (vehicle). Our findings suggest that piceatannol is capable of protecting cells and tissues from oxidative stress.

율무 지방빌의 자동산화에 의해서 형성된 Hydroperoxides 이성체 조성 (Isomeric Composition of Hydroperoxides Formed by Autoxidation of Adlay Lipid and Triglyceride)

  • 한지숙;이숙희;최홍식
    • 한국식품영양과학회지
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    • 제19권3호
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    • pp.229-233
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    • 1990
  • The compositions of hydroperoxy fatty acid components of lipid in raw adlay powder(RAP) and processed adlay powder(PAP) stored at 35$^{\circ}C$ and PAP lipid and triglyceride(TG) autoxi야-zed 35$^{\circ}C$ were studied. During autoxidation the time taken to reach 100 of peroxide and 13-hydroperoxide isomers were the major hydroperoxy fatty acids found in oxidized adlay lipid. Lower levels of 8-. 10-, 11-, 12- and 16-hydroperoxide isomer were also observed. The composi-tions of hydroperoxy fatty acid componets obtained from sutoxidized RAP lipid and TG were similar to those of hydroperoxy fatty acid components is lipid extracted from stored RAP and PAP.

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