• Journal of Advanced Marine Engineering and Technology
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• v.32 no.8
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• pp.1116-1122
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• 2008

The reciprocating type hydrogen compressor has a pulsation due to the reciprocative characteristics which results in noise and vibration. Snubber is installed for the relaxation of pulsation, but it causes reduction of compressor efficiency because of pressure loss. Five types of snubber were modeled for the numerical investigation of the effect of the relative position of inlet and outlet and buffer angle on the pulsation amplitude and pressure loss. MSC/NASTRAN is used as a numerical tool to identify the vibration characteristic of each type. Frequency responses in forced vibration mode are compared for various cases and buffer angles.

• 한국연소학회:학술대회논문집
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• 2005.10a
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• pp.305-313
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• 2005

Measurements of flame length, width and NOx emissions have been conducted to investigate the effect of an acoustic excitation on flame structure in turbulent hydrogen diffusion flames with coaxial air. The resonance frequency of oscillations was varied between 259 ,514 and 728 Hz with power rate of 0.405 and 2.88w. When these frequencies imposed to hydrogen flames, dramatic reduction of flame length and NOx emission was achieved. And acetone planar laser-induced fluorescence technique was used to measure a concentration of the near field of driven axisymmetric jet. The air-fuel stoichiometric line was plotted to investigate the mixing layer and development of air entrainment to fuel jet. Consequently, acoustic excitation on flame could enhance the air-fuel mixing resulting in abatement of NOx emission quantitatively.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.231-234
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• 2002

According to recent investigations regarding Fenton-like reaction, it was reported that there was a key factor to decompose organic materials by not only the hydoroxyl radical but also several reductants which were superoxide anion and hydroperoxide anion. This research was focused on an investigation of the decomposition of carbon tetrachloride(CT) by reductants which were generated by pyrolusite with hydrogen peroxide. Generally, CT decomposition rate increased with raising pH values. Especially,, CT was decomposed over 60 percent by 10,000 ppm of hydrogen peroxide within 10 minutes in neutral condition. In addition, the decomposition of chlorinated compounds would be accelerated in alkaline condition, even with low concentration of hydrogen peroxide.

• Nuclear Engineering and Technology
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• v.53 no.6
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• pp.2066-2073
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• 2021

The use of nuclear reactors is a large studied possible solution for thermochemical water splitting cycles. Nevertheless, there are several problems that have to be solved. One of them is to increase the efficiency of the cycles. Hence, in this paper, a thermal energy optimization of a Sulfur-Iodine nuclear hydrogen production cycle was performed by means a heuristic method with the aim of minimizing the energy targets of the heat exchanger network at different minimum temperature differences. With this method, four different heat exchanger networks are proposed. A reduction of the energy requirements for cooling ranges between 58.9-59.8% and 52.6-53.3% heating, compared to the reference design with no heat exchanger network. With this reduction, the thermal efficiency of the cycle increased in about 10% in average compared to the reference efficiency. This improves the use of thermal energy of the cycle.

• Transactions of Materials Processing
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• v.33 no.3
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• pp.185-192
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• 2024

This study examined how varying tempering temperatures affect the susceptibility of Cr-Mo low alloy steels to hydrogen embrittlement. A slow strain-rate test (SSRT) was carried out on the steels electrochemically pre-charged with hydrogen in order to examine the hydrogen embrittlement behavior. The results showed that the hydrogen embrittlement resistance of the Cr-Mo low alloy steels improved with increasing tempering temperature. Thermal desorption analysis (TDA) revealed that diffusible hydrogen content decreased with increasing tempering temperature, accompanied by a slight increase in the peak temperature. This decrease in hydrogen content was likely due to a reduction in dislocation density which served as reversible hydrogen trap sites. These findings underline the significant role of tempering temperature in enhancing the hydrogen embrittlement resistance of Cr-Mo low alloy steels.

• Resources Recycling
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• v.31 no.1
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• pp.29-36
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• 2022

The hydrogen reduction behavior of molybdenum oxides was studied using a horizontal-tube reactor. Reduction was carried out in two stages: MoO₃ → MoO₂ and MoO₂ → Mo. In the first stage, a mixed gas composed of 30 vol% H₂ and 70 vol% Ar was selected for the MoO₃ reduction because of its highly exothermic reaction. The temperature ranged from 550 to 600 ℃, and the residence time ranged from 30 to 150 min. In the second step, pure H₂ gas was used for the MoO₂ reduction, and the temperature and residence time ranges were 700-750 ℃ and 30-150 min, respectively. The hydrogen reduction behavior of molybdenum oxides was found to be somewhat different between the two stages. For the first stage, a temperature dependence of the reaction rate was observed, and the best curve fittings were obtained with a surface reaction control mechanism, despite the presence of intermediate oxides under the conditions of this study. Based on this mechanism, the activation energy and pre-exponential were calculated as 85.0 kJ/mol and 9.18 × 10⁷, respectively. In addition, the pore size within a particle increases with the temperature and residence time. In the second stage, a temperature dependence of the reaction rate was also observed; however, the surface reaction control mechanism fit only the early part, which can be ascribed to the degradation of the oxide crystals by a volume change as the MoO₂ → Mo phase transformation proceeded in the later part.

• Journal of Korean Society of Water and Wastewater
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• v.18 no.4
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• pp.508-514
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• 2004

Industrial and municipal wastewater treatment plants produce large amounts of sludge cakes for final disposal. This problem is an inevitable drawback inherent to the activated sludge process. Both the reduction of the amount of sludge produced and improvement of its dewaterability are presently very important issue also in Korea. So many pre-treatment processes have been developed in order to improve sludge dewatering efficiency. In this study the effects of hydrogen peroxide and paper sludge mixing processes were considered as reasonable alternatives to enhance sludge dewaterability. The CST of sludge was significantly decreased, and dewaterability improved by hydrogen peroxide oxidation treatment. The optimum dosage of hydrogen peroxide was proved to be 10mg/g-TS (when TS of sludge was 2%) with the conditions of pH 4 and only 1~2 minutes of reaction time. The mixing of paper sludge with sewage sludge was turned out to be very effective in reduction of sludge cake; 30% of sludge cake reduction was accomplished. Optimum mixing ratio of paper sludge was about 30%(v/v). This process also could save 25% of polymer to be required. These two alternatives are somewhat realistic, but it was concluded that paper sludge mixing process will be the best choice.

• Korean Journal of Materials Research
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• v.12 no.6
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• pp.488-492
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• 2002

Magnetic properties of nanostructured materials are affected in complicated manner by their microstructure such as grain size, internal strain and crystal structure. Thus, studies on the synthesis of nanostructured materials with controlled microstructure are necessary for a significant improvement in magnetic properties. It is well known that when Fe-Co alloy undergoes ordering transformation, soft magnetic properties could be obtained. There are many reports that the magnetic properties of the materials can be changed with variation of grain size. In the present work, nanostructured Fe-50at.%Co alloy powder produced by hydrogen reduction process (HRP) starting with two oxide powder mixtures of $Fe_2O_3\;and\; Co_3O_4$. The mean grain size of the HRP powders was about 40 nm and coercivity of the: powders was about 43 Oe.

• Journal of Powder Materials
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• v.17 no.2
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• pp.136-141
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• 2010

Bismuth-telluride based $(Bi_{0.2}Sb_{0.8})_2Te_3$ thermoelectric powders were fabricated by two-step planetary milling process which produces bimodal size distribution ranging $400\;nm\;{\sim}\;2\;{\mu}m$. The powders were reduced in hydrogen atmosphere to minimize oxygen contents which cause degradation of thermoelectric performance by decreasing electrical conductivity. Oxygen contents were decreased from 0.48% to 0.25% by the reduction process. In this study, both the as-synthesized and the reduced powders were consolidated by the spark plasma sintering process at $350^{\circ}C$ for 10 min at the heating rate of $100^{\circ}C/min$ and then their thermoelectric properties were investigated. The sintered samples using the reduced p-type thermoelectric powders show 15% lower specific electrical resistivity ($0.8\;m{\Omega}{\cdot}cm$) than those of the as-synthesized powders while Seebeck coefficient and thermal conductivity do not change a lot. The results confirmed that ZT value of thermoelectric performance at room temperature was improved by 15% due to high electric conductivity caused by the controlled oxygen contents present at bismuth telluride materials.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.5
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• pp.693-700
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• 2006

The important factor for the development of burner is the achievement of low emissions with maintaining combustibility. In case of maintaining high temperature flame and excess air to increase the combustibility, it is possible to achieve high combustion efficiency, due to the reduction of UHC(unborn hydrocarbon), carbon monoxide and soot. However, it is difficult to reduce the thermal NOx produced in the high temperature flame. To solve this problem, we developed externally oscillated oil burner which is possible for the high efficiency combustion and low NOx emission, simultaneously. The experiment of flame characteristics and NOx reduction were achieved according to the variation of frequency, amplitude and air velocity. Frequency, amplitude and air velocity are the most important parameter. The optimum operating conditions are frequency 1,900 Hz, amplitude 3 $V_{pp.}$ and air velocity 6.8 m/s. Reduction of NOx and CO are 47% and 22%, respectively.