• Title/Summary/Keyword: Hydrogen treatment

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The Study on Bleaching of Kenaf Fibers (Part I) -Effect of Bleaching- (케냐프 섬유의 표백에 대한 연구 (제1보) -표백효과를 중심으로-)

  • Jang Hyunsook;Lee Hyeja;Yoo Hyeja;Han Youngsook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.9_10 s.146
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    • pp.1295-1305
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    • 2005
  • The study was based on a three-stage, non-repetitive factorial experiment in which chemical-rotted kenaf fibers were treated separately with hydrogen peroxide concentrations of $0.5\%,\;1\%\;and\;2\%$, with pH solutions of 7, 9 and 11, and treatment times of 30, 60 and 90 minutes. Under optimal conditions, the study was conducted to determine the bleaching efficiency by the addition of chelators, penetrants and surfactants. The bleaching effects on the kenaf fibers were high in high hydrogen peroxide concentration, high in alkali solution pH, low in long treatment time. The optimal level of hydrogen peroxide on bleaching effects were at $2\%$ hydrogen peroxide concentration, with pH of 11 and treatment time of 60 minutes. Under the conditions of $2\%$ hydrogen peroxide concentration, pH 11 and treatment time of 60 minutes, the addition of chelator: Sodim Pyrophosphate(SP), Citric Acid(CA) made the bleaching effects of the kenaf fibers high.

Effect of DNA Repair Inhibitors and Iron on the Chromosome Aberration Induced by Bleomycin and Hydrogen Peroxide in CHO Cells (DNA 회복합성저해제 및 철이 Bleomycin과 과산화수소에 의해 유발된 CHO 세포의 염색체 이상빈도에 미치는 영향)

  • 정해원;유은경
    • Journal of Environmental Health Sciences
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    • v.19 no.4
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    • pp.59-66
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    • 1993
  • The cellular toxicity and antitumor effects of bleomycin are thought to be occurred by formation of O$_2$-Fe$^{2+}$-bleomycin complexes that degrade DNA and release O$_2^-$ and $^{\cdot}$OH radicals. Hydroxyl radicals derived from hydrogen peroxide seem most likely to be involved in the various stages of carcinogenesis, and transition metals such as iron play a central role in activation of bleomycin and in formation of hydroxyl radicals. This study was performed to investigate whether treatment with ferrous sulfate increase chromosome aberration induced by bleomycin and hydrogen peroxide, and whether there is different repair mechanism for DNA damage induced by those chemicals. Treatment with 3AB, Ara C, during G$_1$ and post-treatment with caffeine, and Hu during G$_2$ increased the frequency of chromosome aberration induced by bleomycin but post-treatment with caffeine only did function that way when hydrogen peroxide was treated. When 6.6X 10$^{-7}$ M of bleomycin or 5.0X10$^{-5}$M of hydrogen peroxide were treated simultaneously with iron, the frequency of chromosome aberration was reduced, if compared with the results by bleomycin or hydrogen per oxide alone.

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Hydrogen Embrittlement Properties of Austenitic Fe-30Mn-0.2C(-1.5Al) High-Manganese Steels for Cryogenic Applications (극저온용 오스테나이트계 Fe-30Mn-0.2C(-1.5Al) 고망간강의 수소 취화 특성)

  • Lee, Sang-In;Lee, Ji-Min;Hwang, Byoungchul
    • Journal of the Korean Society for Heat Treatment
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    • v.31 no.6
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    • pp.283-289
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    • 2018
  • This present study deals with the hydrogen embrittlement properties of austenitic Fe-30Mn-0.2C(-1.5Al) high-manganese steels for cryogenic applications. They were electrochemically charged with hydrogen and then subjected to tensile tests for evaluating hydrogen embrittlement behavior. Tensile test results showed that after hydrogen charging the tensile strength and elongation of the Al-free steel were more remarkably decreased with increasing current density when compared to the Al-added steel. After hydrogen charging of the Al-added steel, it was found that the measured hydrogen content was small and silver particles were relatively less decorated. Therefore, the Al-added steel has a superior hydrogen embrittlement resistance to the Al-free steel because the addition of Al suppresses the injection of hydrogen during electrochemical hydrogen charging.

Hydrogen Treatment Protects against Cell Death and Senescence Induced by Oxidative Damage

  • Han, A Lum;Park, Seong-Hoon;Park, Mi Sung
    • Journal of Microbiology and Biotechnology
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    • v.27 no.2
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    • pp.365-371
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    • 2017
  • Hydrogen has potential for preventive and therapeutic applications as an antioxidant. However, micro- and macroparticles of hydrogen in water disappear easily over time. In order to eliminate reactive oxygen species (ROS) related with the aging process, we used functional water containing nanoparticle hydrogen. Nanoparticle hydrogen does not disappear easily and collapse under water after long periods of time. We used murine embryonic fibroblasts that were isolated from 12.5-day embryos of C57BL/6 mice. We investigated the ability of nanoparticle hydrogen in water to suppress hydroxyurea-induced ROS production, cytotoxicity, and the accumulation of ${\beta}-galactosidase$ (an indicator of aging), and promote cell proliferation. The accumulation of ${\beta}-galactosidase$ in the cytoplasm and the appearance of abnormal nuclei were inhibited by daily treatment of cells with hydrogen water. When the aging process was accelerated by hydroxyurea-induced oxidative stress, the effect of hydrogen water was even more remarkable. Thus, this study showed the antioxidant and anti-senescence effects of hydrogen water. Nanoparticle hydrogen water is potentially a potent anti-aging agent.

A Study on the Pd-Ni Alloy Hydrogen Membrane using the Porous Nickel Metal Support (다공성 Ni 금속 지지체를 사용한 Pd-Ni 합금 수소 분리막 연구)

  • Kim Dong-Won;Um Ki-Youn;Kim Sang-Ho;Park Jong-Su
    • Journal of the Korean institute of surface engineering
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    • v.37 no.5
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    • pp.289-295
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    • 2004
  • A dense palladium-nikel (Pd-Ni) alloy composite membrane has been fabricated on microporous nickel support mixed with submicron/micron nickel powder instead of mesoporous stainless steel support. Plasma treatment process is introduced as pre-treatment process instead of HCI activation. Pd-Ni alloy composite membrane prepared by electro plating was fairly a uniform and dense surface morphology. The membrane was characterized by permeation experiments with hydrogen and nitrogen gases at temperature 773 K and pressure 2.2 psi. The results showed that hydrogen ($H_2$) permeance was 27 ml/$\textrm{cm}^2$ㆍatmㆍmin and hydrogen/ nitrogen ($_H2$$N_2$) selectivity was 8 at 773 K.

Effects of Hydrogen Injection by In-Situ and Plasma Post-Treatment on Properties of a ZnO Channel Layer in Transparent Thin Film Transistors (증착시 및 플라즈마 후처리에 의한 수소 주입이 투명 박막 트랜지스터에서 산화아연 채널층의 물성에 미치는 영향)

  • Bang, Jung-Hwan;Kim, Won;Uhm, Hyun-Seok;Park, Jin-Seok
    • Journal of the Semiconductor & Display Technology
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    • v.9 no.1
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    • pp.35-40
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    • 2010
  • We have investigated the effects of hydrogen injection via in-situ gas addition ($O_2$, $H_2$, or $O_2$ + $H_2$ gas) and plasma post-treatment (Ar or Ar + H plasma) on material properties of ZnO that is considered to be as a channel layer in transparent thin film transistors. The variations in the electrical resistivity, optical transmittance and bandgap energy, and crystal quality of ZnO thin films were characterized in terms of the methods and conditions used in hydrogen injection. The resistivity was significantly decreased by injection of hydrogen; approximately $10^6\;{\Omega}cm$ for as-grown, $1.2\;{\times}\;10^2\;{\Omega}cm$ for in-situ with $O_2/H_2\;=\;2/3$ addition, and $0.1\;{\Omega}cm$ after Ar + H plasma treatment of 90 min. The average transmittance of ZnO films measured at a wavelength of 400-700 nm was gradually increased by increasing the post-treatment time in Ar + H plasma. The optical bandgap energy of ZnO films was almost monotonically increased by decreasing the $O_2/H_2$ ratio in in-situ gas addition or by increasing the post-treatment time in Ar + H plasma, while the post-treatment using Ar plasma hardly affected the bandgap energy. The role of hydrogen in ZnO was discussed by considering the creation and annihilation of oxygen vacancies as well as the formation of shallow donors by hydrogen.

Effect of Heat Treatment Conditions on Corrosion and Hydrogen Diffusion Behaviors of Ultra-Strong Steel Used for Automotive Applications

  • Park, Jin-seong;Seong, Hwan Goo;Kim, Sung Jin
    • Corrosion Science and Technology
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    • v.18 no.6
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    • pp.267-276
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    • 2019
  • The purpose of this study was to examine the influence of conditions for quenching and/or tempering on the corrosion and hydrogen diffusion behavior of ultra-strong automotive steel in terms of the localized plastic strain related to the dislocation density, and the precipitation of iron carbide. In this study, a range of analytical and experimental methods were deployed, such as field emission-scanning electron microscopy, electron back scatter diffraction, electrochemical permeation technique, slow-strain rate test (SSRT), and electrochemical polarization test. The results showed that the hydrogen diffusion parameters involving the diffusion kinetics and hydrogen solubility, obtained from the permeation experiment, could not be directly indicative of the resistance to hydrogen embrittlement (HE) occurring under the condition with low hydrogen concentration. The SSRT results showed that the partitioning process, leading to decrease in localized plastic strain and dislocation density in the sample, results in a high resistance to HE-induced by aqueous corrosion. Conversely, coarse iron carbide, precipitated during heat treatment, weakened the long-term corrosion resistance. This can also be a controlling factor for the development of ultra-strong steel with superior corrosion and HE resistance.

Performance and Microbial Characteristics of Bio-hydrogen Production from Food Waste with Thermal Pre-treatment (음식물류 폐기물의 혐기성 수소 발효 시 열처리에 따른 성능 및 미생물 특성 평가)

  • Lee, Chaeyoung;Choi, Jaemin
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.1
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    • pp.11-18
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    • 2014
  • This study was conducted to investigate the effect of thermal pre-treatment on bio-hydrogen from food waste. Two continuous reactors operated and VFAs(volatile fatty acids) production and microbial communities were analyzed. The average hydrogen yield was 0.50 and 0.33mol $H_2/mol$ $hexose_{added}$ in thermally treated food added reactor(R1) and control(R2), respectively. Butyrate concentration was similarly 7,500mg/L in both reactors, but two times higher lactate concentration was observed in R2(3,800mg/L). The results of FISH(fluorescence in situ hybridization) showed that the relative microorganism to hydrogen producing bacteria was 78 and 27% in R1 and R2, respectively.

Non volatile memory device using mobile proton in gate insulator by hydrogen neutral beam treatment

  • Yun, Jang-Won;Jang, Jin-Nyeong;Hong, Mun-Pyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.192.1-192.1
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    • 2015
  • We demonstrated the nonvolatile memory functionality of nano-crystalline silicon (nc-Si) and InGaZnOxide (IGZO) thin film transistors (TFTs) using mobile protons that are generated by very short time hydrogen neutral beam (H-NB) treatment in gate insulator (SiO2). The whole memory fabrication process kept under $50^{\circ}C$ (except SiO2 deposition process; $300^{\circ}C$). These devices exhibited reproducible hysteresis, reversible switching, and nonvolatile memory behaviors in comparison with those of the conventional FET devices. We also executed hydrogen treatment in order to figure out the difference of mobile proton generation between PECVD and H-NB CVD that we modified. Our study will further provide a vision of creating memory functionality and incorporating proton-based storage elements onto a probability of next generation flexible memorable electronics such as low power consumption flexible display panel.

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Elctrokinetic-Fenton 기법 적용시 토질조건과 오염원의 종류에 따른 과산화수소의 주입특성

  • 김정환;김병일;한상재;김수삼
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.30-33
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    • 2002
  • In this study, feasibility of using hydrogen peroxide as a chemical oxidant for in-situ treatment by EK-Fenton technology were investigated. Kaolinite, kaolinite/sand mixture and illitic soil spiked by phenol and phenanathrene were used and variation of electrochemical characteristics were examined by EK-Fenton test. For kaolinite that having low buffer capacity, hydrogen peroxide was injected effectively from anode reservoir. However illitic soil that having relatively higher buffer capacity had low hydrogen peroxide introducing efficiency. The test results showed that Hydrogen ions generated by current increased during the treatment decreased under pH 3 in the most of kaolinite specimen. Therefore, stabilized hydrogen oxide was injected more effectively in the kaolinite specimen. This study suggests that efficiency of hydrogen peroxide injection by EK-Fenton thechnoloty is dependent of variation of pH in the soil

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