• Title/Summary/Keyword: Hydrogen safety

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SAFETY STUDIES ON HYDROGEN PRODUCTION SYSTEM WITH A HIGH TEMPERATURE GAS-COOLED REACTOR

  • TAKEDA TETSUAKI
    • Nuclear Engineering and Technology
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    • v.37 no.6
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    • pp.537-556
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    • 2005
  • A primary-pipe rupture accident is one of the design-basis accidents of a High-Temperature Gas-cooled Reactor (HTGR). When the primary-pipe rupture accident occurs, air is expected to enter the reactor core from the breach and oxidize in-core graphite structures. This paper describes an experiment and analysis of the air ingress phenomena and the method fur the prevention of air ingress into the reactor during the primary-pipe rupture accident. The numerical results are in good agreement with the experimental ones regarding the density of the gas mixture, the concentration of each gas species produced by the graphite oxidation reaction and the onset time of the natural circulation of air. A hydrogen production system connected to the High-Temperature Engineering Test Reactor (HTTR) Is being designed to be able to produce hydrogen by themo-chemical iodine-Sulfur process, using a nuclear heat of 10 MW supplied by the HTTR. The HTTR hydrogen production system is first connected to a nuclear reactor in the world; hence a permeation test of hydrogen isotopes through heat exchanger is carried out to obtain detailed data for safety review and development of analytical codes. This paper also describes an overview of the hydrogen permeation test and permeability of hydrogen and deuterium of Hastelloy XR.

Improvement of Fire Safety Management Plan in Response to Hydrogen Chloride Leak (염화수소 누출에 따른 소방계획서 개선방안)

  • Boohyun Baek;Hasung Kong
    • Journal of the Korea Safety Management & Science
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    • v.26 no.3
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    • pp.39-49
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    • 2024
  • This study aims to propose an improvement of fire safety management plans for buildings, such as apartment complexes and schools, within a 10 km radius of industrial complexes. It utilizes an off-site consequence analysis program to reflect the toxic impact on national industrial complexes and surrounding areas. The ALOHA program was utilized to analyze the impact of toxicity due to a hydrogen chloride leak, a hazardous material. The results showed that the area with AEGL-2 and above ranged from 3.1 km to 10 km, the AEGL-3 area ranged from 1.9 km to 7.3 km. The ASET was measured to be between 3 and 24 minutes. Due to the impact of toxicity, it is necessary to prepare fire safety management plans for buildings, such as apartment complexes and schools that are within a 10 km radius from industrial complexes. These safety plans incorporate the hydrogen chloride risk assessment results, ASET, weather conditions, and coordination with the local community.

A Numerical Study on the Flame Arrestor for Safety Valve of Hydrogen (수소 안전밸브용 역화방지기의 성능 평가에 대한 수치해석 연구)

  • OH, SEUNG JUN;YOON, JEONG HWAN;KIM, SI POM;CHOI, JEONGJU
    • Journal of Hydrogen and New Energy
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    • v.33 no.4
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    • pp.391-399
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    • 2022
  • Hydrogen is one of the energy carriers and has high energy efficiency relative to mass. It is an eco-friendly fuel that makes only water (H2O) as a by-product after use. In order to use hydrogen conveniently and safely, development of production, storage and transfer technologies is required and attempts are being made to apply hydrogen as an energy source in various fields through the development of the technology. For transporting and storing hydrogen include high-pressure hydrogen gas storage, a type of storage technologies consist of cryogenic hydrogen liquid storage, hydrogen storage alloy, chemical storage by adsorbents and high-pressure hydrogen storage containers have been developed in a total of four stages. The biggest issue in charging high-pressure hydrogen gas which is a combustible gas is safety and the backfire prevention device is that prevents external flames from entering the tank and prevents explosion and is essential to use hydrogen safely. This study conducted a numerical analysis to analyze the performance of suppressing flame propagation of 2, 3 inch flame arrestor. As a result, it is determined that, where the flame arrestor is attached, the temperature would be lowered below the temperature of spontaneous combustion of hydrogen to suppress flame propagation.

Safety Assessment for Hydrogen Gas Production Facilities (Steam Reforming) (Steam Reforming방법을 이용한 수소제조설비의 안전성 평가)

  • Rhie Kwang Won;Kim Tae Hun;Kim Jung Keun;Han Seung Yong
    • Journal of the Korean Institute of Gas
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    • v.9 no.4 s.29
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    • pp.44-49
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    • 2005
  • In this study, a process safety evaluation is implemented, in which the process hazards are investigated systematically about hydrogen production plants. Be used qualitative Safety management method such as HAZOP and FMEA. Were analysed potential hazards (human errors or operating failures of every processing steps) about parameters that flow, pressure, temperature of hydrogen production plants through HAZOP that making deviations applied signified guide words. Analysed to using FMEA mainly about bad components or troubles that equipments breakdown and malfunction in facilities and then propose its influences, and counterproposal.

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Evacuation Safety Evaluation of High School according to Hydrogen Fluoride Leakage

  • Boohyun Baek;Sanghun Han;Hasung Kong
    • International Journal of Internet, Broadcasting and Communication
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    • v.16 no.2
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    • pp.255-266
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    • 2024
  • The purpose is to evaluate evacuation safety by simulating the toxic effects of hydrogen fluoride leaks in areas surrounding national industrial complexes and to suggest alternatives for areas that do not satisfy evacuation safety. For human casualties caused by hydrogen fluoride leakage accidents, Available Safe Egress Time (ASET) is calculated by the toxic effects quantified with the Areal Locations of Hazardous Atmospheres (ALOHA), an off-site consequence assessment program. The Required Safe Egress Time (RSET) is calculated through Pathfinder, an evacuation simulation program. Evacuation safety is assessed by comparing ASET and RSET. The ALOHA program was used to evaluate the time to reach AEGL-2 concentration in 12 scenarios. The Pathfinder program was used to assess the total evacuation time of the high school among specific fire-fighting objects. Of the 12 accident scenarios, ASET was larger than RSET in the worst-case scenarios 1 and 9. For the remaining 10 accident scenarios, the ASET is smaller than the RSET, so we found that evacuation safety is not guaranteed, and countermeasures are required. Since evacuation safety is not satisfactory, we proposed to set up an evacuation area equipped with positive pressure equipment and air respirators inside specific fire-fighting objects such as the high school.

Study on the Evaluation Method of Electrical Isolation Property for Hydrogen Fuel Cell Vehicle (수소연료전지자동차의 절연성능 평가방법에 관한 고찰)

  • Lee, Ki-Yeon;Kim, Dong-Ook;Kim, Hyang-Kon
    • Journal of Hydrogen and New Energy
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    • v.22 no.6
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    • pp.810-818
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    • 2011
  • This paper analyzed the suitability about the isolation performance criteria which was based on human impedance and effect of current in IEC 60479-1 on the safety of human being was examined. The method of evaluation by megger and DC voltmeter was analyzed. The differences of isolation performance according to design of high-voltage system were analyzed. The factors which affect the insulation performance were analyzed for HFCV, EV, HEV, etc. through analysis of the isolation performance evaluation method. Finally, design for improved isolation performance was proposed.

A Study on the Analysis of the Leakage Characteristics and the Selection of Leakage Scenarios of the Blending Hydrogen into Natural Gas Pipeline (수소혼입 천연가스 배관망의 누출 특성 분석 및 누출 시나리오 선정에 관한 연구)

  • Song Su Tak;Ki Seop Lim
    • Journal of the Korean Society of Safety
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    • v.39 no.1
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    • pp.27-32
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    • 2024
  • This study analyzed cases of hydrogen (H2) and natural gas (CH4) leakage from a hydrogen-blended natural gas pipeline to determine a range of leakage characteristics, including leakage type, pipe material, pipe diameter, pressure, and damage size. Based on the results of this analysis, five hydrogen-blended natural gas leakage scenarios were selected. The national vision for a carbon-neutral society by 2050 is a very important strategic objective and promotes environmentally sustainable economic development in the age of the climate crisis. Accordingly, zero-carbon and low-carbon policies are being promoted in various fields, including energy production, consumption, and industrial processes. Hydrogen-blended natural gas is eco-friendly and is considered an important step towards carbon neutrality, with various countries including the United States and several European countries conducting empirical research to further investigate its potential. In Korea, a national research project commenced in April 2023 to verify and demonstrate the life cycle safety of blending hydrogen into the natural gas network. The results of this study will provide important data for the analysis of the damage impacts caused by the leakage of hydrogen-blended natural gas, such as the diffusion of gas clouds, fires, and gas explosions.

Analysis of Safety by Expansion of Hydrogen Charging Station Facilities (수소충전소 설비 증설에 따른 안전성 해석)

  • Park, Woo-Il;Kang, Seung-Kyu
    • Journal of the Korean Institute of Gas
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    • v.24 no.6
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    • pp.83-90
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    • 2020
  • This study conducted a risk assessment using the HyKoRAM program created by international joint research. Risk assessment was conducted based on accident scenarios and worst-case scenarios that could occur in the facility, reflecting design specifications of major facilities and components such as compressors, storage tanks, and hydrogen pipes in the hydrogen charging station, and environmental conditions around the demonstration complex. By identifying potential risks of hydrogen charging stations, we are going to derive the worst leakage, fire, explosion, and accident scenarios that can occur in hydrogen storage tanks, treatment facilities, storage facilities, and analyze the possibility of accidents and the effects of damage on human bodies and surrounding facilities to review safety.

Development and validation of diffusion based CFD model for modelling of hydrogen and carbon monoxide recombination in passive autocatalytic recombiner

  • Bhuvaneshwar Gera;Vishnu Verma;Jayanta Chattopadhyay
    • Nuclear Engineering and Technology
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    • v.55 no.9
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    • pp.3194-3201
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    • 2023
  • In water-cooled power reactor, hydrogen is generated in case of steam zirconium reaction during severe accident condition and later on in addition to hydrogen; CO is also generated during molten corium concrete interaction after reactor pressure vessel failure. Passive Autocatalytic Recombiners (PARs) are provided in the containment for hydrogen management. The performance of the PARs in presence of hydrogen and carbon monoxide along with air has been evaluated. Depending on the conditions, CO may either react with oxygen to form carbon dioxide (CO2) or act as catalyst poison, reducing the catalyst activity and hence the hydrogen conversion efficiency. CFD analysis has been carried out to determine the effect of CO on catalyst plate temperature for 2 & 4% v/v H2 and 1-4% v/v CO with air at the recombiner inlet for a reported experiment. The results of CFD simulations have been compared with the reported experimental data for the model validation. The reaction at the recombiner plate is modelled based on diffusion theory. The developed CFD model has been used to predict the maximum catalyst temperature and outlet species concentration for different inlet velocity and temperatures of the mixture gas. The obtained results were used to fit a correlation for obtaining removal rate of carbon monoxide inside PAR as a function of inlet velocity and concentrations.

Analysis of Operation Data Monitoring for LPG-Hydrogen Multi-Fueling Station (LPG-수소복합충전소 운영데이터 모니터링 분석)

  • Park, Songhyun;Kim, Donghwan;Ku, Yeonjin;Kim, Piljong;Huh, Yunsil
    • Journal of Energy Engineering
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    • v.28 no.4
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    • pp.1-7
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    • 2019
  • In response to the recent increase in demand for hydrogen stations, the Ministry of Trade and Industry has enacted and promulgated special notifications to enable the installation of hydrogen stations in the form of the combined complex in existing automotive fuel supply facilities such as LPG, CNG, and gas stations. Hydrogen multi energy filling stations haven't been operated yet in Korea till the establishment of special standards, so it is necessary create special standards by considering all Korean environmental characteristics such as four seasons and daily crossings. In this study, we collected and analyzed the charging data of Ulsan LPG-Hydrogen Multi Fueling Station installed for the first time in Korea. The data are hourly temperature and pressure data from compressors, storage vessels and dispensers. We used the data collected for a year, including the highest temperature and the lowest temperature in Ulsan to compare seasonal characteristics. As a result, it was found that the change of the outside temperature affects the initial temperature of the vehicle's container of the hydrogen car, which finally affects the charging time and the charging speed of the vehicle. There was no effect on vehicle containers because the limit temperature suggested by the Korean Hydrogen Station Standard(KGS FP217) and the US Filling Protocol(SAE J2601) was not exceeded.