• 제목/요약/키워드: Hydrogen issue

검색결과 103건 처리시간 0.023초

플라즈마발생기의 이온분율 측정 장치 설계 및 제작 (The design and fabricationt for ion fraction measurement of plasma generator)

  • 이찬영
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.368-368
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    • 2008
  • Ion implantation has been widely developed during the past decades to become a standard industrial tool. To comply with the growing needs in ion implantation, innovative technology for the control of ion beam parameters is required. Beam current, beam profile, ion fractions are of great interest when uniformity of the implant is an issue. Especially, it is important to measure the spatial distribution of beam power and also the energy distribution of accelerated ions. This energy distribution is influenced by the proportion of mass for ion in the plasma generator(ion source) and by charge exchange and dissociation within the accelerator structure and also by possible collective effects in the neutralizer which may affect the energy and divergence of ions. Hydrogen atom has been the object of a good study to investigate the energy distribution. Hydrogen ion sources typically produce multi-momentum beams consisting of atomic ion ($H^+$) and molecular ion ($H_2^+$ and $H_3^+$). In the beam injector, the molecular ions pass through a charge-exchanges gas cell and break up into atomic with one-half (from $H_2^+$) or one-third (from $H_3^+$) according to their accelerated energy. Burrell et al. have observed the Doppler shifted lines from incident $H^+$, $H_2^+$, and $H_3^+$ using a Doppler shift spectroscopy. Several authors have measured the proportion of mass for hydrogen ion and deuterium using an ion source equipped with a magnetic dipole filter. We developed an ion implanter with 50-KeV and 20-mA ion source and 100-keV accelerator tube, aiming at commercial uses. In order to measure the proportion of mass for ions, we designed a filter system which can be used to measure the ion fraction in any type of ion source. The hydrogen and helium ion species compositions are used a filter system with the two magnets configurations.

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Inconel 617 재료의 소형펀치 실험을 이용한 수소취화처리재의 탄-소성 거동 및 파괴인성 유추 (Estimation of Elastic Plastic Behavior Fracture Toughness Under Hydrogen Condition of Inconel 617 from Small Punch Test)

  • 김낙현;김윤재;윤기봉;마영화
    • 대한기계학회논문집A
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    • 제37권6호
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    • pp.753-760
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    • 2013
  • 금속 재료의 수소취화 현상에 대한 분석은 수소플랜트의 안전성 평가를 위해 매우 중요하다. 수소환경하 취화된 재료의 기계적 물성과 파괴인성은 구조 건전성 평가에 가장 기본적이며 중요한 자료이다. 본 논문은 최근에 개발된 유한요소 해석 기반 현상학적 손상해석을 소형펀치 실험에 적용하고 Inconel 617 재료의 대기 중 소형펀치 실험결과와 비교 함으로써 손상해석 기법의 적용 타당성을 보였다. 또한 역변환 기법을 사용하여 소형펀치 실험으로부터 인장물성을 예측하고 인장실험으로부터 구한 재료 물성과 비교하여 적용 가능성을 검증하였다. 검증된 결과를 바탕으로 수소취화된 시편에 대한 소형펀치 실험결과에 역변환 기법과 손상해석을 적용하여 수소취화 된 재료의 기계적물성과 파괴인성을 예측하였다.

잠호용접부 균열방지를 위한 용접 플락스 및 시공기법 개발 (Development of Welding Flux and Process for Prevention of Cold Cracking in SAW Weld Metal)

  • 최기영;김찬;김영필
    • 대한조선학회 특별논문집
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    • 대한조선학회 2007년도 특별논문집
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    • pp.118-127
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    • 2007
  • SAW(Submerged Arc Welding) process is generally applied to a wide range of welding area in the fabrication of steel structure. This process has a good characteristic properties such as the high quality of welds and the high deposition rates, but in case of welding on a thick steel plate, it also has higher cold crack susceptibility than that of a thin steel plate. The purpose of this research is to find the main factor of crack generation and clarify the countermeasure for crack prevention, and then establish the optimum welding condition in a heavy thick steel plate. The results of this study are as follows, 1. The cause of crack generation is found the diffusible hydrogen penetrated into weld metal by decomposition of the remained moisture in SAW flux during welding. 2. For the removal of diffusible hydrogen, the raw materials of SAW flux are to be dehydrated at the high temperature in the initial manufacturing stage. 3. Mechanical properties of weld metal welded with the dehydrated SAW flux were evaluated very excellent, furthermore the weld metal has been proved to have low diffusible hydrogen content with 3.1ml /100g. 4. The weldability and quality welded with thick steel plates were improved by establishing the new optimum welding condition.

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시동 특성, 수소 생산 및 선택성 향상을 위한 자열개질기의 이론 및 수치해석적 연구 (Theoretical and numerical study to investigate characteristics of light-off and steady state of methane autothermal reactor for efficient light-off, high hydrogen yield and selectivity)

  • 이신구;배중면
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회B
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    • pp.3353-3358
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    • 2007
  • The present paper is devoted to investigate dynamic effect and steady-state performance of methane autothermal reformer theoretically and numerically. In order to simplify the complicated phenomena in the system, axisymmetric heterogeneous reactor model is developed. As autothermal reaction takes places on catalyst surface between bulk gas and catalyst, volume averaging method is incorporated using porous medium approach. To understand the start-up process which occurs in the reactor is highly important. Therefore, in this paper we get various goverining equations to find out transient and steady solutions and time scale for start-up introducing dimensionless variables. Start-up is a significant issue in reforming reaction for automobile system and fueling of SOFC-based auxiliary power units. This paper deals with characteristics of heat and mass transfer and predicted light-off time in the reformer as oxygen to carbon ratio ($O_2$/C) and amount of feeding gas.

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Design of a Monolithic Photoelectrochemical Tandem Cell for Solar Water Splitting with a Dye-sensitized Solar Cell and WO3/BiVO4 Photoanode

  • Chae, Sang Youn;Jung, Hejin;Joo, Oh-Shim;Hwang, Yun Jeong
    • Rapid Communication in Photoscience
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    • 제4권4호
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    • pp.82-85
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    • 2015
  • Photoelectrochemical cell (PEC) is one of the attractive ways to produce clean and renewable energy. However, solar to hydrogen production via PEC system generally requires high external bias, because of material's innate electronic band potential relative to hydrogen reduction potential and/or charge separation issue. For spontaneous photo-water splitting, here, we design dye-sensitized solar cell (DSSC) and their monolithic tandem cell incorporated with a $BiVO_4$ photoanode. $BiVO_4$ has high conduction band edge potential and suitable band gap (2.4eV) to absorb visible light. To achieve efficient $BiVO_4$ photoanode system, electron and hole mobility should be improved, and we demonstrate a tandem cell in which $BiVO_4/WO_3$ film is connected to cobalt complex based DSSC.

Flat Burner 위에 설치된 Ceramic Honeycomb의 축열성능 연구 (A Study on the Heat Accumulation Performance of Ceramic Honeycomb located on the Flat Burner)

  • 박재민;허수빈;윤봉석;이도형
    • Journal of Advanced Marine Engineering and Technology
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    • 제36권2호
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    • pp.244-249
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    • 2012
  • 최근 화석연료 사용으로 인한 에너지 위기와 환경오염 문제가 사회적 문제점으로 떠오르고 있어 친환경 에너지 개발에 대한 연구가 활발히 진행되고 있다. PEMFC는 기본적으로 수증기 개질반응을 통해 고순도 수소를 얻고 있지만 운전 시 기동시간이 길고 빠른 기동을 필요로 하는 곳에는 문제가 있다. 따라서 본 연구실에서는 1KW급 평판형 STR 반응기에 적용할 연소기의 고효율 및 균일가열을 목표로 세라믹 허니컴을 적용하는 가능성을 알아본다. 한편, 축열체의 열량 보존시간에 대한 실험결과는 마일드연소기 개발에서 공기의 고온화를 위한 기초자료로 활용하고자 한다.

The Effect of Overexpression of Rat Clusterin in L929 Fibroblasts

  • PARK , JUNG-HYUN;JU, SUNG-KYU;PARK, JEE-SUN;PARK, YOO-KYOUNG;KANG, MYUNG-HEE;YOU, KWAN-HEE
    • Journal of Microbiology and Biotechnology
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    • 제14권6호
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    • pp.1333-1337
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    • 2004
  • Oxidants such as hydrogen peroxide are powerful inducers of cell damage, ageing, and apoptosis. Since clusterin, a 75-80 kDa mammalian glycoprotein, is frequently found to be inducible in apoptotic cells and tissues, this study inquired into whether this would be a protective mechanism against further cell death. The aim was to find out whether overexpression of clusterin could protect cells from oxidant­induced stress and apoptosis. To clarify this issue, we generated and analyzed stable cell lines expressing fusion proteins of a rat clusterin with an enhanced green fluorescent protein (EGFP). When treated with varying concentrations of hydrogen peroxides, clusterin transfectants indeed showed increased resistance to apoptosis and exhibited a much higher survival rate than mock-transfected cells. On the other hand, neither intracellular re-distribution nor local concentration of clusterin-EGFP was observed, which leaves the question open about its anti-apoptotic mechanism. In conclusion, the overexpression of clusterin provides a means for protecting cells against oxidative stress and subsequent cell death.

내구성 향상을 위한 연료전지 촉매 개발 (Synthesis and Durability of Carbon-Supported Catalysts for PEMFC)

  • 이미혜;최진성;노범욱
    • 한국수소및신에너지학회논문집
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    • 제26권4호
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    • pp.318-323
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    • 2015
  • For commercialization of fuel cell electric vehicles, one of the key objectives is to improve durability of MEA and electrocatalysts. Regarding electrocatalysts, the major issue is to reduce carbon corrosion and dissolution of Pt caused by harsh conditions, for example, SU/SD (Start-up/Shut-down). In this research, OER (Oxygen Evolution Reaction) catalyst has been developed improvement of durability. A modified polyol process is developed by controlling the pH of the solvent to synthesize the PtIr nanocatalysts on carbon supports. Each performance of the MEAs applying PtIr and Pt are equivalent because PtIrnanocatalysts have both ORR and OER activity. Breadboard test for catalyst durability in harsh conditions and high potentialsis found that the MEA applying PtIrnanocatalysts durability is improved more than the MEA applying Pt nanocatalysts.

Flexural wave를 이용한 고분자 전해질 연료전지 공기극 내에서의 플러딩 제거 (Removal of Flooding in a PEM Fuel Cell at Cathode by Flexural Wave)

  • 김경록;한성호;안득균;최영돈
    • 한국수소및신에너지학회논문집
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    • 제21권1호
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    • pp.35-41
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    • 2010
  • Water management is an important issue of PEM fuel cell operation. Water is the product of the electrochemical reactions inside fuel cell. If liquid water accumulation becomes excessive in a fuel cell, water columns will clog the gas flow channel. This condition is referred to as flooding. A number of researchers have examined the water removal methods in order to improve the performance. In this paper, a new water removal method that investigates the use of vibro-acoutic methods is presented. Piezo-actuators which are devices to generate the flexural wave are attached at the end of a cathode bipolar plate. Flexural wave is used to impart energy to resting droplets and thus cause movement of the droplets in the direction of the traveling wave.

ENVIRONMENTAL FATIGUE OF METALLIC MATERIALS IN NUCLEAR POWER PLANTS - A REVIEW OF KOREAN TEST PROGRAMS

  • Jang, Changheui;Jang, Hun;Hong, Jong-Dae;Cho, Hyunchul;Kim, Tae Soon;Lee, Jae-Gon
    • Nuclear Engineering and Technology
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    • 제45권7호
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    • pp.929-940
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    • 2013
  • Environmental fatigue of the metallic components in light water reactors has been the subject of extensive research and regulatory interest in Korea and abroad. Especially, it was one of the key domestic issues for the license renewal of operating reactors and licensing of advanced reactors during the early 2000s. To deal with the environmental fatigue issue domestically, a systematic test program has been initiated and is still underway. The materials tested were SA508 Gr.1a low alloy steels, 316LN stainless steels, cast stainless steels, and an Alloy 690 and 52M weld. Through tests and subsequent analysis, the mechanisms of reduced low cycle fatigue life have been investigated for those alloys. In addition, the effects of temperature, dissolved oxygen level, and dissolved hydrogen level on low cycle fatigue behaviors have been investigated. In this paper, the test results and key analysis results are briefly summarized. Finally, an on-going test program for hot-bending of 347 stainless steel is introduced.