• Korean Journal of Materials Research
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• v.24 no.10
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• pp.532-537
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• 2014

In this study, highly sensitive hydrogen micro gas sensors of the multi-layer and micro-heater type were designed and fabricated using the micro electro mechanical system (MEMS) process and palladium catalytic metal. The dimensions of the fabricated hydrogen gas sensor were about $5mm{\times}4mm$ and the sensing layer of palladium metal was deposited in the middle of the device. The sensing palladium films were modified to be nano-honeycomb and nano-hemisphere structures using an anodic aluminum oxide (AAO) template and nano-sized polystyrene beads, respectively. The sensitivities (Rs), which are the ratio of the relative resistance were significantly improved and reached levels of 0.783% and 1.045 % with 2,000 ppm H2 at $70^{\circ}C$ for nano-honeycomb and nano-hemisphere structured Pd films, respectively, on the other hand, the sensitivity was 0.638% for the plain Pd thin film. The improvement of sensitivities for the nano-honeycomb and nano-hemisphere structured Pd films with respect to the plain Pd-thin film was thought to be due to the nanoporous surface topographies of AAO and nano-sized polystyrene beads.

• Journal of ILASS-Korea
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• v.27 no.4
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• pp.181-187
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• 2022

For carbon neutrality, direct-injection hydrogen engines are attracting attention as a future power source. It is essential to estimate the transient injection rate of hydrogen for the optimization of hydrogen injection in direct injection engines. However, conventional injection rate measurement techniques for liquid fuels based on the injection-induced fuel pressure change in a test section are difficult to be applied to gaseous fuels due to the compressibility of the gas and the sealing issue of the components. In this study, a momentum flux measurement technique is introduced to obtain the transient injection rate of gaseous fuels using a force sensor. The injection rate calculation models associated with the momentum flux measurement technique are presented first. Then, the volumetric injection rates are estimated based on the momentum flux data and the calculation models and compared with those measured by a volumetric flow rate meter. The results showed that the momentum flux measurement can detect the injection start and end timings and the transient and steady regimes of the fuel injection. However, the estimated volumetric injection rates showed a large difference from the measured injection rates. An alternative method is suggested that corrects the estimated injection rate results based on the measured mean volumetric flow rates.

• Journal of Sensor Science and Technology
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• v.31 no.3
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• pp.168-174
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• 2022

Hydrogen sulfide(H₂S) gas is a high-risk gas that can cause suffocation or death in severe cases, depending on the concentration of exposure. Various studies to detect this gas are still in progress. In this study, we demonstrate a colorimetric sensor that can detect H₂S gas using its direct color change. The proposed nanofiber sensor containing a dye material named Lead(II) acetate, which changes its color according to H₂S gas reaction, is fabricated by electrospinning. The performance of this sensor is evaluated by measuring RGB changes, ΔE value, and gas selectivity. It has a ΔE value of 5.75 × 10^-3 ΔE/s·ppm, showing improved sensitivity up to 1.4 times that of the existing H₂S color change detection sensor, which is a result of the large surface area of the nanofibers. The selectivity for H₂S gas is confirmed to be an excellent value of almost 70 %.

• Proceedings of the KSME Conference
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• 2008.11a
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• pp.1829-1832
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• 2008

This paper reports a novel gas sensing method by using a thermoelectric device, thermopile in this case, with an embedded tin oxide catalyst. By using a thin catalyst film, the response time and recovery time were remarkably improved. The fabricated gas sensor was characterized through detecting NOx gas with various concentrations.

• Proceedings of the Korean Institute of Intelligent Systems Conference
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• 1993.06a
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• pp.1285-1288
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• 1993

We tried gas identification by using one semiconductive gas sensor. As a method of gas identification, we used the fuzzy reasoning with fuzzy set of slope of gas pattern which is divided into arbitary interval. As a result, we got a good successful rate for hydrogen 66.6%, propane 79.1%, butane 100%, methane 100%, city gas 79.1% and alcohol 91.6%, respectively.

• Journal of Sensor Science and Technology
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• v.29 no.6
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• pp.369-373
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• 2020

A hydrogen sensor was fabricated by utilizing a bundle of metal oxide nanostructures whose growth positions were selectively controlled by utilizing graphene, which is a carbon of atomic-unit thickness. To verify the reducing ability of graphene, it was confirmed that the multi-composition metal oxide V₂O₅ was converted into VO₂ on the graphene surface. Because of the role of graphene as a reducing catalyst, it was confirmed that ZnO and MoO₃ nanostructures were grown at high density only on the graphene surface. The fabricated gas sensor showed excellent sensitivity.

• Journal of the Korean institute of surface engineering
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• v.50 no.2
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• pp.125-130
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• 2017

ZnO nanowires were synthesized and annealed at various temperatures of $500-800^{\circ}C$ in oxygen atmosphere to investigate hydrogen gas sensing properties. The diameter and length of the synthesized ZnO nanowires were approximately 50-100 nm and a few $10s\;{\mu}m$, respectively. $H_2$ gas sensing performance of the ZnO nanowires sensor was measured with electrical resistance changes caused by $H_2$ gas with a concentration of 0.1-2.0%. The response of ZnO nanowires at room temperature to 2.0% $H_2$ gas is found to be two times enhanced by annealing process in $O_2$ atmosphere at $800^{\circ}C$. In the current study, the effect of heat treatment in $O_2$ atmosphere on the gas sensing performance of ZnO nanowires was studied. And the underlying mechanism for the sensing improvement of the ZnO nanowires was also discussed.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.3
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• pp.298-305
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• 2016

In this study, we treated pitch-based activated carbon fibers (ACFs) in hydrogen peroxide using electron beam (E-beam) irradiation to improve nitrogen monoxide (NO) sensing ability as an electrode material of gas sensor. The specific surface area of ACFs treated by E-beam irradiation with 400 kGy increased from $885m^2/g$ (pristine) to $1160m^2/g$ without any changes in structural property and functional group. The increase in specific surface area of the E-beam irradiated ACFs enhanced NO gas sensing properties such as response time and sensitivity. When the ACFs irradiated with 400 kGy, response time was remarkably reduced from 360 s to 210 s and sensitivity was increased by 4.5%, compared to the pristine ACFs. These results demonstrate convincingly that surface modification of ACFs using E-beam in hydrogen peroxide solution can enhance textural properties of ACFs and NO gas sensing ability of gas sensor at room temperature.

• Transactions of the Korean hydrogen and new energy society
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• v.16 no.1
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• pp.9-16
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• 2005

We studied the electrochromic properties of hydrated amorphous ruthenium oxide ($RuO_2{\cdot}xH_2O$) thin films using in-situ Raman spectroscopy during electrochemical charging/discharging cycles. We have found that the principal effect of hydrogen insertion into $RuO_2{\cdot}xH_2O$ is reduction of $Ru^{4+}\;to\;Ru^{3+}$, and not formation of new bonds involving hydrogen. We compared the changes in the Raman spectrum of a gasochromic $Pd/RuO_2{\cdot}xH_2O$ film as it is exposed to hydrogen gas with that of electrochemical hydrogen insertion. We tested the changes in the optical transmission of the $Pd/RuO_2{\cdot}xH_2O$ film when exposed to hydrogen gas.

• Journal of Sensor Science and Technology
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• v.18 no.3
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• pp.202-206
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• 2009

Flat type catalytic combustible hydrogen sensors were fabricated using platinum micro-heaters and sensing material pastes. The platinum micro-heater was formed on an alumina substrate by sputtering method. The paste for the sensing materials was prepared using ${\gamma}-Al_2O_3$ 30 wt%, $SnO_2$ 35 wt%, and Pd/Pt 30 wt% and coated on the platinum micro-heater. The sensing performances were tested for the prepared sensors with different substrate sizes. The micro catalytic combustible hydrogen sensors showed quick response time, high reliability, and good selectivity against various gases(CO, $C_3H_8,\;CH_4$) at low operating temperature of $156^{\circ}\C$.