• Title/Summary/Keyword: Hydrogen gas in oil

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Gas Chromatographic Determination of Flavor Stability of Cooking Oils (가스크로마토그래피에 의한 식용유의 향미 안정성 측정)

  • Kim, In-Hwan;Yoon, Suk-Hoo
    • Korean Journal of Food Science and Technology
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    • v.20 no.5
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    • pp.732-735
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    • 1988
  • Flavor stability of cooking oils such as rice bran oil, double fractionated palm olefin and soybean oil were determined by headspace analysis using gas chromatography. In the headspace, the contents of volatile compounds, oxygen and hydrogen were measured. The hydrogen content in the headspace correlated well with the contents of volatile compound (r > 0.95). Therefore, it is proposed that a single measurement of hydrogen and oxygen is used as a index of flavor stability of cooking oils instead of separate measurement of volatile compounds and oxygen. which have conventionally been used.

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Gas detection charracteristic of Transformer Oil Gas Detector (변압기 절연유중 가스 검출장치의 가스 감지 특성)

  • Hwang, Kyu-Hyun;Seo, Ho-Joon;Lee, Suck-Woo;Rhie, Dong-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.323-324
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    • 2005
  • To found out the degradation characteristic of transformer insulation, insulation materials and electrodes are deposited into transformer oil. They used to heated and make flashover. Due to the thermal and electrical stress added to insulation materials, the density of carbon dioxide and hydrogen included in transformer oil was increased. The gas density can measured by using the gas density detection equipment of gas sensor and air circulation method.

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Pre-feasibility Study in Mongolia Tavan Tolgoi Coal Bed Methane (Tavan Tolgoi Coal Bed Methane에 대한 몽골에서의 타당성 조사)

  • CHO, WONJUN;YU, HYEJIN;LEE, JESEOL;LEE, HYUN CHAN;JU, WOO SUNG;LIM, OCKTAEK
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.1
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    • pp.124-129
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    • 2018
  • Methane is the cleanest fuel and supplies by many distributed type: liquefaction natural gas (LNG), compressed natural gas (CNG), and pipeline natural gas (PNG). Natural gas is mainly composed by methane and has been discovered in the oil and gas fields. Coal bed methane (CBM) is also one of them which reserved in coalbed. This significant new energy sources has emerge to convert an energy source, hydrogen and hydrogen-driven chemicals. For this CBM, this paper was written to analyze the geological analysis and reserves in Mongolian Tavan Tolgoi CBM coal mine and to examine the application field. This paper is mainly a preliminary feasibility report analyzing the business of Tavan Tolgoi CBM and its exploitable gas.

A Study on Syngas Co-Combustion Characteristics in a 0.7 MWth Water-Tube Boiler with Single Heavy Oil Burner (중유 싱글 버너 수관식 보일러에서의 합성가스 혼합연소 특성 연구)

  • Choi, Sin-Yeong;Yang, Dong-Jin;Bang, Byoung-Yeol;Yang, Won
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.5
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    • pp.452-459
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    • 2010
  • This study is aimed to investigate changes of combustion characteristics and heat efficiency when syngas from gasification process using low-rank fuel such as waste and/or biomass is applied partially to an industrial boiler. An experimental study on syngas co-combustion was performed in a 0.7 MW (1 ton steam/hr) water tube boiler using heavy oil as a main fuel. Three kinds of syngas were used as an alternative fuel: mixture gas of pure carbon monoxide and hydrogen, syngas of low calorific value generated from an air-blown gasification process, and syngas of high calorific value produced from an oxygen-blown gasification process. Effects of co-combustion ratio (0~20%) for each syngas on flue gas composition were investigated through syngas injection through the nozzles installed in the side wall of the boiler and measuring $O_2$, $CO_2$, CO and NOx concentrations in the flue gas. When syngas co-combustion was applied, injected syngas was observed to be burned completely and NOx concentration was decreased because nitrogen-containing-heavy oil was partially replaced by the syngas. However, heat efficiency of the boiler was observed to be decreased due to inert compounds in the syngas and the more significant decrease was found when syngas of lower calorific value was used. However, the decrease of the efficiency was under 10% of the heat replacement by syngas.

The Study on the Mechanical Characteristics of Hydrogen Embrittlement for the Weld Zone of Ferrite Stainless Steel (페라이트 스테인리스강 용접부에 대한 수소취성의 기계적 특성에 관한 연구)

  • Choi, Byung-Il;Lim, Uh-Joh
    • Journal of the Korean Institute of Gas
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    • v.9 no.4 s.29
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    • pp.11-16
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    • 2005
  • In this paper, the hydrogen osmosis test and the mechanical tensile test were carried out to examine hydrogen cracking behavior of STS444 with welding conditions. In $0.5MH_2SO_4+0.001M \;As_2O_3$ solution, the hydrogen embrittlement characteristics of weld zone of STS444 added to load of $1,400 kg/cm^2$ together with hydrogen osmosis by current of $30mA/cm^2$ for 60 min. was considered. As a result of study on the hydrogen embrittlement and mechanical characteristics of STS444외와 with welding conditions the tensile stress and elongation of STS444 get lower by the absorption of oil or water before welding. Also, the reduction rate of tensile stress and elongation of STS444 is larger because of hydrogen embrittlement by the absorption of oil or water. STS444 by the absorption of water before welding is more sensitive to hydrogen embrittlement than oil.

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Diagnosis for the Transformer depend on Moisture and Furfural Detecting in Oil (절열유중의 수분 및 Furfural 검출을 이용한 유입변압기 상태진단)

  • Choi Gwang-beom;Eo Soo-young;Kweon Dong-jin;Lee Dong-joon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.12
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    • pp.546-552
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    • 2005
  • In this paper, a present condition with gas-in-oil diagnosis which used to condition analysis for oil insulated transformer is investigated and reason why hydrogen used to basic diagnosis for the transformer is described. This paper gives an overview of background knowledge that should to consider as moisture detecting of oil immersed paper and how could we approach to life expectancy of oil insulated transformer through detecting furfural compound.

CO2 Capture from the Petroleum Refining Industry (정유 산업에서의 온실가스 포집)

  • Hong, Yeon Ki
    • Journal of Institute of Convergence Technology
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    • v.11 no.1
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    • pp.13-18
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    • 2021
  • It is widely accepted that the prevention of global warming requires significant reductions in greenhouse gases, particularly CO2 emissions. Although fossil fuel-based power plants account for the majority of CO2 emissions, it is urgent to reduce CO2 emissions in industries that emit large amounts of CO2 such as steel, petrochemical, and oil refining. This paper examines the current status of CO2 emission in the domestic oil refining industry and CO2 emission sources in each unit process in the oil refining industry. Focusing on the previously developed CO2 capture process, cases and applicability of greenhouse gas reduction in FCC and hydrogen manufacturing processes, which are major processes constituting the oil refining industry, are reviewed.

Study on EEC and SSC of the Electric Resistance Welded Linepipe Steel

  • Kim, Wan Keun;Koh, Seong Ung;Yang, Boo Young;Kim, Kyoo Young
    • Corrosion Science and Technology
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    • v.6 no.3
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    • pp.96-102
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    • 2007
  • The resistance of the linepipe steel to hydrogen-induced cracking (HIC) and sulfide stress cracking (SSC) is very important for steel to be used in sour oil/gas environments. Welding of steels is necessary to the construction of pipe-line transporting oil/gas. In this study, HIC and SSC resistance of an electric resistance welded (ERW) steel plate which belongs to API X70 grade was evaluated by using NACE TM0284-96A and NACE TM0177-96A methods. HIC and SSC fracturing behavior was investigated by observing fractured surfaces using optical microscopy (OM) and scanning electron microscopy (SEM). It was discussed in terms of metallurgical parameters such as the distribution of primary microstructure, second phases and inclusions. Results showed that the weld joint of ERW steel is more sensitive than base metal to HIC and SSC. This is due to difference in the contribution of metallurgical parameters to HIC and SSC nucleation and propagation.

A Experimental Study on a Pressure Variation in the Cavity of Hydrogen Diaphragm Compressor (다이아프램식 수소압축기의 캐비티 내 압력특성 변화에 관한 실험적 연구)

  • Shin, Young-Il;Park, Hyun-Woo;Lee, Young-Jun;Song, Ju-Hun;Chang, Young-June;Jeon, Chung-Hwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.769-772
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    • 2009
  • Diaphragm compressors are used for a hydrogen compression because it can achieve high gas pressure with high purity. But diaphragm's lifetime may depend on the shape of the cavity and deflection from fluctuation the pressure change, which is necessary to monitored. In this study, the gas and hydraulic oil pressure in the cavity were measured as piston speed varies for diaphragm compressor. The results show pressure change quantities were reduced and maximum pressure points are delayed as the piston moves faster. And the hydraulic pressure were elevated as gas pressure elevated. And the compression period was more faster than expansion period.

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The Effect of Promotor and Reaction Condition for FT Oil Synthesis over 12wt% Co-based Catalyst (12wt% Co 담지 촉매에서 합성오일 제조시 조촉매 효과 및 반응조건 영향 분석)

  • Park, Yonhee;Lee, Jiyoon;Jung, Jongtae;Lee, Jongyeol;Cho, Wonjun;Baek, Youngsoon
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.3
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    • pp.247-254
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    • 2014
  • The synthesis of Fischer-Tropsch oil is the catalytic hydrogenation of CO to give a range of products, which can be used for the production of high-quality diesel fuel, gasoline and linear chemicals. Our cobalt based catalyst was prepared Co/alumina, silica and titania by the incipient wet impregnation of the nitrates of cobalt and promoter with supports. Cobalt catalysts was calcined at $350^{\circ}C$ before being loaded into the FT reactors. After the reduction of catalyst has been carried out under $450^{\circ}C$ for 24hrs, FT reaction of the catalyst has been carried out at GHSV of 4,000/hr under $200^{\circ}C$ and 20atm. From these test results, we have obtained the results as following ; in case of 12wt% Co-supported $Al_2O_3$, $SiO_2$ and $TiO_2$ catalysts, maximum activities of the catalysts were appeared at the promoters of Mn, Mo and Ce respectively. The activity of 12wt% $Co/Al_2O_3$ added a Mn promoter was about 3 times as high as that of 12wt% $Co/Al_2O_3$ catalyst without promoters. When it has been the experiment at the range of reaction temperature of $200{\sim}220^{\circ}C$ and GHSV of 1,546~5,000/hr, the results have shown generally increasing the activities with the increase of reaction temperature and GHSV.