• Progress in Superconductivity and Cryogenics
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• v.24 no.3
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• pp.62-67
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• 2022

Liquid hydrogen (LH₂) has a higher density than gaseous hydrogen, so it has high transport efficiency and can be stored at relatively low pressure. In order to use efficient bulk hydrogen in the industry, research for the LH₂ supply system is needed. In the high-pressure hydrogen station based on LH₂ currently being developed in Korea, a heat exchanger is used to heat up supercritical hydrogen at 700 bar and 60 K, which is pressurized by a cryogenic high-pressure pump, to gas hydrogen at 700 bar and 300 K. Accordingly, the heat exchanger used in the hydrogen station should consider the design of high-pressure tubes, miniaturization, and freezing prevention. A helical heat exchanger generates secondary flow due to the curvature characteristics of a curved tube and can be miniaturized compared to a straight one on the same heat transfer length. This paper evaluates the heat transfer performance through parametric study on the distance between coils, guide effect, and anti-icing design of helical heat exchanger. The helical heat exchanger has better heat transfer performance than the straight tube exchanger due to the influence of the secondary flow. When the distance between the coils is uniform, the heat transfer is enhanced. The guide between coils increases the heat transfer performance by increasing the heat transfer length of the shell side fluid. The freezing is observed around the inlet of distribution tube wall, and to solve this problem, an anti-icing structure and a modified operating condition are suggested.

• 한국신재생에너지학회:학술대회논문집
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• 2006.11a
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• pp.451-454
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• 2006

WGS reaction over Mo2C and ceria based catalysts was investigated to develop an alternative commercial Cu-Zn/Al2O3 catalyst for fuel processor and hydrogen station. The Mo2C catalysts were prepared by a temperature programmed method and the various metal supported cerium oxide catalysts were prepared by an Impregnation method. The catalysts were characterized by the N2 physisorption, Co chemisorption, XRD, TEM and TPR. It was found that Mo2C and 0.2wt% Pt-40wt%, Ni/CeO2 catalysts had higher activity and stability than the Cu-Zn/Al203 above $260^{\circ}C$. Moreover, CO conversion of more than 85% was observed at $280{\sim}300^{\circ}C$. But all catalysts were deactivated during the thermal cycling runs. The results suggest that these catalysts are an attractive candidate for the alternative Cu-Zn/Al2O3 catalyst for fuel processor and hydrogen station applications.

• Journal of Hydrogen and New Energy
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• v.33 no.6
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• pp.607-615
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• 2022

In this study, economic analysis program was developed for economic evaluation of hydrogen production, storage/delivery, and utilization technologies as well as overseas import of hydrogen. Economic analysis program can be used for the estimation of the levelized cost of hydrogen for hydrogen supply chain technologies. This program include five hydrogen production technology on steam methane reforming and water electrolysis, two hydrogen storage technologies (high compressed gas and liquid hydrogen storage), three hydrogen delivery technologies (compressed gas delivery using tube trailer, liquid hydrogen, and pipeline transportation) and six hydrogen utilization technologies on hydrogen refueling station and stationary fuel cell system. In the case of overseas import hydrogen, it was considered to be imported from five countries (Austraila, Chile, India, Morocco, and UAE), and the transportation methods was based on liquid hydrogen, ammonia, and liquid organic hydrogen carrier. Economic analysis program that was developed in this study can be expected to utilize for planning a detailed implementation methods and hydrogen supply strategies for the hydrogen economy road map of government.

• 한국신재생에너지학회:학술대회논문집
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• 2009.11a
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• pp.209-212
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• 2009

수소에너지의 무궁한 가능성 때문에 관련 기술은 미래 국가 경쟁력을 좌우할 것이며, 이러한 수소에너지의 핵심으로 수소제조공정 및 수소스테이션 관련 기술은 국가연료전지 시장을 비롯한 수소연료전지자동차 산업 전반에 커다란 영향을 미칠 것으로 예상되고 있다. 그러므로 세계 각국은 수소에너지를 미래에너지원으로 개발하기 위하여 대규모로 기술개발 및 실증연구를 실시하고 있으며, 주로 수소연료전지자동차 개발과 아울러 수소스테이션 개발에 대한 인프라 구축에 대해 이루어지고 있다. 국내에서도 국가주도로 수소스테이션 건설이 이루어지고 있으며, 본 연구에서는 수소연료전지자동차를 이용하여 수소인프라와의 모니터링에 대한 현황에 대해 논의하고자 한다.

• Explosives and Blasting
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• v.40 no.3
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• pp.19-32
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• 2022

Hydrogen is a fuel having the highest energy compared with other common fuels. This means hydrogen is a clean energy source for the future. However, using hydrogen as a fuel has implication regarding carrier and storage issues, as hydrogen is highly inflammable and unstable gas susceptible to explosion. Explosions resulting from hydrogen-air mixtures have already been encountered and well documented in research experiments. However, there are still large gaps in this research field as the use of numerical tools and field experiments are required to fully understand the safety measures necessary to prevent hydrogen explosions. The purpose of this present study is to develop and simulate 3D numerical modelling of an existing hydrogen gas station in Jeonju by using handheld LiDAR and Ansys AUTODYN, as well as the processing of point cloud scans and use of cloud dataset to develop FEM 3D meshed model for the numerical simulation to predict peak-over pressures. The results show that the Lidar scanning technique combined with the ANSYS AUTODYN can help to determine the safety distance and as well as construct, simulate and predict the peak over-pressures for hydrogen refueling station explosions.

• Journal of Hydrogen and New Energy
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• v.22 no.4
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• pp.559-567
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• 2011

This paper deals with an economic evaluation of domestic low-temperature water electrolysis hydrogen production. We evaluate the economic feasibility of on-site hydrogen fueling stations with the hydrogen production capacity of 30 $Nm^3/hr$ by the alkaline and the polymer electrolyte membrane water electrolysis. The hydrogen production prices of the alkaline water electrolysis, the polymer electrolyte membrane water electrolysis, and the steam methane reforming hydrogen fueling stations with the hydrogen production capacity of 30 $Nm^3/hr$ were estimated as 18,403 $won/kgH_2$, 22,945 $won/kgH_2$, 21,412 $won/kgH_2$, respectively. Domestic alkaline water electrolysis hydrogen production is evaluated as economical for small on-site hydrogen fueling stations, and we need to further study the economic evaluation of low-temperature water electrolysis hydrogen production for medium and large scale on-site hydrogen fueling stations.

• Journal of Hydrogen and New Energy
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• v.25 no.3
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• pp.255-263
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• 2014

This paper deals with a construction plan of hydrogen fueling stations on express highways using geographic information system. We analyzed the existing hydrogen fueling stations and production facilities to construct the hydrogen supply system to satisfy the hydrogen demands. Also, we suggested the necessary number and locations of hydrogen fueling stations on express highways for operating fuel cell vehicles. As a result, we need to construct at least 6 hydrogen stations on express highways in 2020 and 14 hydrogen stations in 2025. In 2030, when fuel cell vehicles are expected to spread over the whole nation, 114 hydrogen stations are needed to construct on express highways. This study mainly utilized the information of distances between hydrogen production facilities and fueling stations. However, we need to analyze the other factors such as traffic and income data. Also, it is necessary to make a suitable construction plan of hydrogen fueling stations that should be constructed on each district using geographic information system.

• Journal of Energy Engineering
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• v.28 no.4
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• pp.48-60
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• 2019

After the Paris Agreement in 2015, the government has been promoting various policies such as 'Hydrogen-Economy Roadmap(2019)' to supply hydrogen. As part of this, the government announced the goal of building 310 hydrogen refueling stations(HRS) until 2022. To this end, special case standard for the introduction of complex, packaged, and mobile hydrogen refueling stations(MHRS) have been enacted and promulgated. The MHRS has the advantage of being able to supply hydrogen to multiple regions. However, due to the movement and close distance between facilities, it is necessary to secure proper installation standards and operational safety through safety analysis. In this study, the possibility of introduction was investigated by designing a standard model and quantitative risk assessment(QRA). As a result of QRA, personal and social risk were acceptable, and the empirical test direction and implications were derived.

• Journal of Hydrogen and New Energy
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• v.15 no.4
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• pp.274-282
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• 2004

This study focused on the development of high performance catalyst for autothermal reforming (ATR) of gasoline to produce hydrogen. The ATR was carried out over MgO/Al2O3 supported metal catalysts prepared under various experimental conditions. The catalysts before and after reaction were characterized by N2-physisorption, CO-chemisorption, SEM and XRD. The performance of supported multi-metal catalysts were better than that of supported mono-metal catalysts. Especially, it was observed that the conversion of iso-octane over prepared Ni/Fe/MgO/Al2O3 catalyst was 99.9 % comparable with commercial catalyst (ICI) and the selectivity of hydrogen over the prepared catalyst was 65% higher than ICI catalyst. Furthermore, it was identified that the sulfur tolerance of prepared catalyst was much better than ICI catalyst based on the ATR reaction of iso-octane containing sulfur of 100 ppm. Therefore, Ni/Fe/MgO/Al2O3 catalyst can be applied for a fuel reformer, hydrogen station and on-board reformer in furl cell powered vehicles.

• Journal of the Korean Institute of Gas
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• v.25 no.2
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• pp.28-33
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• 2021

With the recent growing interest in eco-friendly cars, as interest in eco-friendly cars increases, interest and purchase of hydrogen fuel cell vehicles that do not emit pollutants are increasing. Recently, the government is supporting the expansion of hydrogen charging station and localization of core parts according to the government's hydrogen energy dissemination policy. In this study, the flow characteristics of the hydrogen flow control valve were investigated. As the differential pressure increases, the mass flow rate and flow coefficient tend to be different from the volume flow rate. And it was confirmed that it affects the hydrogen temperature due to the nozzle effect in the bottleneck section, and the change in density affects the mass flow rate.