• Title/Summary/Keyword: Hydrogen Recirculation Ratio

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Experimental Study on the Partial Oxidation Reforming of CH4/O2 Mixture in Two-Section Porous Media (CH4/O2 혼합기의 2단 다공체 내 부분산화 개질에 관한 실험적 연구)

  • Guahk, Young Tae;Lee, Dae Keun;Ko, Chang-Bog
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.249-251
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    • 2014
  • Synthesis gas such as hydrogen and carbon monoxide was produced from $CH_4//oxygen$ mixture using two-section porous media combustor. Heat recirculation through the inner foam structure could extend the flow velocity of stable region over the laminar burning velocity. $H_2/CO$ ratio and module M from concentration of flue gas measured by Gas Chromatography was similar to those calculated by equilibrium. But it was made sure that the heat loss effect becomes more influential than heat recirculation effect as the mixture gets richer. To generate synthesis gas appropriate for methanol production, insulated pressurized porous media combustor will be designed and built in the future.

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Numerical Investigation on Cavity-Enhanced-Supersonic Combustion Engine of Upstream Fuel Injection in Cavity (공동내부 연료분사방식 초음속 연소기의 수치해석 연구)

  • Jeong, Eun-Ju;Jeung, In-Seuck
    • 한국연소학회:학술대회논문집
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    • 2003.05a
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    • pp.35-39
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    • 2003
  • A numerical study is carried out to investigate combustion phenomena in a model SCRamjet engine, which has been experimentally studied at the Australian National University using a T3 free-piston shock tunnel. The Mach number is 3.8, the static pressure 110kPa and the static temperature 1100K in the main air flow. The fuel is hydrogen, which is injected in the cavity. Equivalence ratio is set to either 0.25 or 0.5 to access its effect on the fuel-air mixing combustion phenomena. The results show that the cavity generates several recirculation zones, which increase the fuel-air mixing. Self ignition occurs near the point of fuel injection. The flame is anchored by the cavity and generates the precombustion shock on the step. For a high equivalence ratio, the recirculation zones are bigger and the flame is present throughout the combustor.

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Characterization of Nitrogen Gas Crossover in PEM Fuel Cell Stacks (고분자 연료전지 스택에서 질소 크로스오버 특성에 관한 연구)

  • Baik, Kyung-Don;Kim, Min-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.3
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    • pp.207-214
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    • 2009
  • Crossover of nitrogen from cathode to anode is inevitable in typical membranes used in PEM fuel cells. This crossovered nitrogen normally accumulates in the hydrogen recirculation system at anode side channels. Excessive buildup of nitrogen in the anode side lowers the relative hydrogen concentration and finally affects the performance of fuel cell stack. So it is very important to analysis the nitrogen gas crossover at various operating conditions. In this study, characterization of nitrogen gas crossover in PEM fuel cell stack was investigated. The mass spectroscopy (MS) has been applied to measure the amount of the crossovered nitrogen gas at the anode exit. Results show that nitrogen gas crossover rate was affected by current density, anode and cathode stoichiometric ratio and operating pressure. Current density, anode stoichiometric ratio and anode operating pressure do not affect nitrogen crossover rate but anode exit concentration of nitrogen. Cathode pressure and stoichiometric ratio largely affect the nitrogen crossover rate.

Development and Application of Two-Dimensional Hydrogen Mixing Model in Containment Subcompartment Under Severe Accidents

  • Lee, Byung-Chul;Cho, Jae-Seon;Park, Goon-Cherl;Chung, Chang-Hyun
    • Nuclear Engineering and Technology
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    • v.29 no.2
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    • pp.110-126
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    • 1997
  • A two-dimensional continuum model for the hydrogen mining phenomena in the containment subcompartment under severe accident conditions has been developed to predict the spatial distribution of the hydrogen concentration. The model can predict the distribution of time-dependent hydrogen concentration for HEDL experiments well. For the simulation of these experiments, the hydrogen is mixed uniform within the test compartment. To predict the extent of non-uniform distribution, the dominant factors such as the geometrical shape of obstacle and velocity of source injection in mixing phenomena are investigated. If the obstacle disturbing the flow of gas mixture exists in the compartment, the uniform distribution of hydrogen might be not guaranteed. The convective circulation of gas flow is separately formed up and down of the obstacle position, which makes a difference of hydrogen concentration between the upper and lower region of the compartment. The recirculation flow must have a considerable mass flow rate relative to velocity of the source injection to sustain the well-mixed conditions of hydrogen. Finally, in order to account for non-uniform distribution of the hydrogen due to the geometrical configuration the maximum-to-average ratio is functionalized.

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Experimental Study on the Partial Oxidation Reforming of CH4/O2 Mixture in Two-Section Porous Media at High Pressure Conditions (고압 분위기에서 CH4/O2 혼합기의 2단 다공체 내 부분산화 개질에 관한 실험적 연구)

  • Guahk, Young Tae;Lee, Dae Keun;Kim, Seung Gon;Ko, Chang-Bog;Park, Jong-Ho
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.73-74
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    • 2015
  • Synthesis gas such as hydrogen and carbon monoxide was produced from $CH_4/oxygen$ mixture using insulated pressurized porous media combustor. Experimentally, two cylindrical SiC foams with the different pore density were piled up in a quartz tube and fully premixed mixture was supplied in the axial direction. After stabilizing fuel-rich flame at the interface of the two foams at several pressure conditions, mole fractions of synthesis gases were measured by gas chromatography. Heat recirculation through the inner foam structure could extend the flow velocity of stable region over the laminar burning velocity. As the pressure increased, the rich flammability limit, $H_2/CO$ ratio, and module M increased.

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The Design and Test of Ejectors for a 75-kW Fuel Cell System (75kW급 연료전지 시스템의 이젝터 설계 및 시험)

  • Kim, Beom-Joo;Kim, Do-Hyeong;Lim, Hee-Chun
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.5
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    • pp.678-685
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    • 2011
  • An Ejector enhances system efficiency, are easily operated, have a mechanically simple structure, and do not require a power supply. Because of these advantages, the ejector has been applied to a variety of industrial fields such as refrigerators, power plants and oil plants. In this work, an ejector was used to safely recycle anode tail gas in a 75-kW Molten Carbonate Fuel Cell (MCFC) system at KEPCO Research Institute. In this system, the ejector is placed at mixing point between the anode tail gas and the cathode tail gas or the fresh air. Commercial ejectors are not designed for the actual operating conditions for our fuel cell system. A new ejector was therefore designed for use beyond conventional operating limits. In the first place, a few sample ejectors were manufacured and the entrainment ratio was measured at a dummy stack. Through this experiment, the optimum ejector was chosen. The 75-kW MCFC system equipped with this optimum ejector was operated successfully.

Development and Verification Test of a Bi-propellant Thruster Using Hydrogen Peroxide and Kerosene

  • Yu, I Sang;Kim, Tae Woan;Ko, Young Sung;Jeon, Jun Su;Kim, Sun Jin
    • International Journal of Aeronautical and Space Sciences
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    • v.18 no.2
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    • pp.270-278
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    • 2017
  • This paper describes development procedure and verification test results of a bi-propellant thruster using hydrogen peroxide and kerosene. The design thrust of the thruster is about 500 N and six swirl type coaxial injectors were used. The passage type manifolds were employed for the injector head to reduce the response time. The passage was designed to minimize stagnation points and recirculation region to ensure uniform flow distribution and sufficient cooling performance through flow analysis using Fluent. A catalytic igniter using hydrogen peroxide was installed at the center of the injector head. The propellant feeding and spray characteristics were confirmed by hydraulic tests. Combustion tests were performed on design and off-design points to analyze combustion characteristics under various mixture ratio conditions. The combustion test results show that combustion efficiency was over 95 % and chamber pressure fluctuation were less than 1.5 % under all test conditions.

The Ejector Design and Test for 5kW Molten Carbonate Fuel Cell (5kW 용융탄산염 연료전지 이젝터 설계 및 시험)

  • Kim, Beom-Joo;Kim, Do-Hyung;Lee, Jung-Hyun;Jung, Sang-Chun;Lee, Sung-Yoon;Kang, Seung-Won;Lim, Hee-Chun
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.53-56
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    • 2008
  • An ejector is a fluid machinery to be utilized for mixing fluids, maintaining vacuum, and transporting them. The Ejector is applied for a variety of industrial fields such as refrigerators and power plants. It is adopted to recycle anode off gas safely in 5kW Molten Carbonate Fuel Cell system of KEPRI(Korea Electric Power Research Institute). The ejector is placed at mixing point between the anode off gas and the cathode off gas or the fresh air. In this study, the entrainment ratio is measured according to the diametrical ratio of nozzle to throat. In addition, the performance curve of the ejector and the differential pressure in diffuser is observed.

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Partial Oxidation Reformer in a Plasma-Recuperative Burner (플라즈마-축열버너 부분산화 개질장치)

  • AN, JUNE;CHUN, YOUNG NAM
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.1
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    • pp.68-76
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    • 2021
  • Climate change problems occur during the use of fossil fuel and the process of biogas production. Research continues to convert carbon dioxide and methane, the major causes of climate change, into high-quality energy sources. in order to present the performance potential for the novel plasma-recuperative burner reformer, the reforming characteristics for each variable were indentified. The optimal operating condition of was an O2/C ratio of 1.0 and a total gas supply of 20 L/min. At this time, CH4 conversion was 64%, H2 selectivity was 39%, and H2/CO ratio was 1.13, which were the results applicable to the solid oxide fuel cell fuel stack for RPG, or Residential Power Generator. Recirculation of reformed gas increases the amount of H2 and CO, which are combustible gases, especially the amount of H2. As a result, the H2 selectivity is improved, and high-quality gas can be produced.

A Study on the Characteristic of Conversion Efficiency for Three-way Catalyst in Hydrogen-Natural Gas Blend Fueled Engine (수소-천연가스 혼합연료 엔진의 삼원촉매 전환효율 특성 연구)

  • Park, Cheol-Woong;Yi, Ui-Hyung;Kim, Chang-Gi;Lee, Janghee
    • Journal of the Korean Institute of Gas
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    • v.20 no.6
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    • pp.23-30
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    • 2016
  • The conventional natural gas engine realized lean combustion for the improved efficiency. However, in order to cope with exhaust gas regulations enforced gradually, the interest has shifted at the stoichiometric mixture combustion system. The stoichiometric mixture combustion method has the advantage of a three-way catalyst utilization whose purification efficiency is high, but the problem of thermal durability and the fuel economy remains as a challenge. Hydrogen-natural gas blend fuel (HCNG) can increase the rate of exhaust gas recirculation (EGR) because the hydrogen increases burning speed and lean flammability limit. The increase in the EGR rate can have a positive impact on heat resistance of the engine due to the decreased combustion temperature, and further can increase the compression ratio for efficient combustion. In this study, to minimize the exhaust emission developed HCNG engine with stoichiometric combustion method, developed three-way catalyst was applied to evaluate the conversion characteristics. The tests were carried out during the steady state and transient operating conditions, and the results were compared for both the conventional and proto-three-way catalyst of HCNG engine for city buses.