• Title/Summary/Keyword: Hydrocarbon Fuels

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Exhaust and Combustion Characteristics of Premixed Swirl Burner for Steam Reforming System (선회류 예혼합버너를 적용한 개질기용 연소시스템의 배기 및 연소특성)

  • Cha, Chun Loon;Hwang, Sang Soon
    • Journal of the Korean Society of Combustion
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    • v.19 no.3
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    • pp.34-43
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    • 2014
  • The reformer system is a method for hydrogen production from hydrocarbon fuels such as natural gas under high temperature environment($about{\sim}1,000^{\circ}C$). The premixed swirl burner with mixing swirler and combustion swirler designed to deliver fuel cell electric output from 0.5 kW to 1.5 kW. Premixed swirl burner experiments using natural gas and mixture of natural gas and anode off gas were carried out to analyse flame patterns and stability by equivalence ratio respectively. The results show that the stable swirl flame can be established for all cases of fuels type using the premixed swirl burner. The swirl flame had a wide stability region and it showed very low CO(50 ppm) and $NO_x$(20 ppm) emission at different fuel type and various equivalence ratio conditions. The operating range of premixed swirl burner for stable swirl flame is found to exist between equivalence ratio of 0.70 to 0.90 for turn down ratio of 3:1.

Lubricating Characteristics of Diesel Fuel (경유의 윤활특성)

  • 신성철;강익중
    • Tribology and Lubricants
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    • v.16 no.5
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    • pp.332-340
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    • 2000
  • The reduction of sulfur content in the diesel fuel has caused the poor lubricity of diesel fuel in the distributor type injection pumps of diesel engines that use the diesel for lubrication of their moving parts. To investigate the reason for poor lubricity of low sulfur diesel fuels, the wear scar diameters by HFRR (High Frequency Reciprocating Rig) were measured on the diesel fuels from Korean markets and the results were compared with their physical and chemical properties. Also, the lubricity change and the improvement effects on lubricity additives for the ultra low sulfur diesel fuel, were made experimentally, that will be regulated to a maximum of 0.005 wt% from about 2005 were evaluated. As a result, a good correlation was found between the wear scar diameter and the polyaromatic compound which includes heterocyclic compound in the diesel fuel. It was also found that the content of polyaromatic compound including heterocyclic compound was affected by the amount of desulfurization treatment fraction. And the lubricity additives with ester base were more effective than that with acid base on the ultra low sulfur diesel fuel. Therefore, it is suggested that the factors affecting the lubricity stated above should be taken into account to improve the lubricity property of the diesel fuel in the refining process.

Theoretical Analyses of Autothermal Reforming Methanol for Use in Fuel Cell

  • Wang Hak-Min;Choi Kap-Seung;Kang Il-Hwan;Kim Hyung-Man;Erickson Paul A.
    • Journal of Mechanical Science and Technology
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    • v.20 no.6
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    • pp.864-873
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    • 2006
  • As fuel cells approach commercialization, hydrogen production becomes a critical step in the overall energy conversion pathway. Reforming is a process that produces a hydrogen-rich gas from hydrocarbon fuels. Hydrogen production via autothermal reforming (ATR) is particularly attractive for applications that demand a quick start-up and response time in a compact size. However, further research is required to optimize the performance of autothermal reformers and accurate models of reactor performance must be developed and validated. The design includes the requirement of accommodating a wide range of experimental set ups. Factors considered in the design of the reformer are capability to use multiple fuels, ability to vary stoichiometry, precise temperature and pressure control, implementation of enhancement methods, capability to implement variable catalyst positions and catalyst arrangement, ability to monitor and change reactant mixing, and proper implementation of data acquisition. A model of the system was first developed in order to calculate flowrates, heating, space velocity, and other important parameters needed to select the hardware that comprises the reformer. Predicted performance will be compared to actual data once the reformer construction is completed. This comparison will quantify the accuracy of the model and should point to areas where further model development is required. The end result will be a research tool that allows engineers to optimize hydrogen production via autothermal reformation.

Study on the Deactivation Trends of Liquid Fuel According to the Types of Endothermic Catalyst in Flow Reactor (흐름형 반응기 내에서 액체연료의 흡열반응촉매 종류에 따른 비활성화 정도에 대한 연구)

  • Lee, Tae Ho;Jeon, Sunbin;Kim, Sung Hyun;Jeong, Byung Hun;Han, Jeong Sik
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.5
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    • pp.81-87
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    • 2018
  • In hypersonic aircraft, increase of aerodynamic and engine heat lead thermal load in airframe. It could lead structural change of aircraft's component and malfunctioning. Endothermic fuels are liquid hydrocarbon fuels which absorb the heat load by undergoing endothermic reactions. In this study, we investigated the relationship between product, coke formation and catalytic properites of endothermic catalysts by using exo-tetrahydrodicyclopentadiene as a fuel in a fixed bed flow reactor similar to the actual reaction conditions.

Characteristics of Chemical Reaction and Ignition Delay in Hydrogen/Air/Diluent Mixtures (수소/공기/희석제 혼합기의 점화지연과 화학반응 특성연구)

  • Lee, Dong Youl;Lee, Eui Ju
    • Journal of the Korean Society of Safety
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    • v.36 no.3
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    • pp.1-6
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    • 2021
  • Hydrogen is considered a cleaner energy source than fossil fuels. As a result, the use of hydrogen in daily life and economic industries is expected to increase. However, the use of hydrogen energy is currently limited because of safety issues. The rate of combustion of the hydrogen mixture is about seven times higher than that of hydrocarbon fuels. The hydrogen mixture is highly flammable and has a low minimum ignition energy. Therefore, it presents considerable risks for fire and explosions in all areas of hydrogen manufacturing, transportation, storage, and use. In this study, the auto-ignition characteristics of hydrogen were investigated numerically for diluted hydrogen mixtures. Auto-ignition temperature, a critical property predicting the fire and explosion risk in hydrogen combustion, was determined in well-stirred reactors. When N2 and CO2 were used to dilute the hydrogen/air mixture, the ignition delay time increased with increasing dilution ratios in both cases. The CO2-diluted mixtures exhibited a longer ignition delay than the N2-diluted mixtures. We also confirmed that lower initial ignition temperatures increased the ignition delay times at 950 K and above. Overall, the auto-ignition characteristics, such as the concentrations of participating species and ignition delay times, were primarily affected by the initial temperature of the mixture.

Combustion and thermal decomposition characteristics of brown coal and biomass

  • Kim, Hee Joon;Kasadani, Yuichi;Li, Liuyun;Shimizu, Tadaaki;Kim, Lae-Hyun
    • Journal of Energy Engineering
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    • v.21 no.4
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    • pp.373-377
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    • 2012
  • Among the fossil fuels, the brown coal is a great deal of resources. However, it is hardly used due to the high moisture content and low calorific value. It has both the week points such as spontaneous combustion and high volatile content and the strong points such as the low-sulfur and low ash content. If we overcome these week points, the using amount of brown coal would be increased. Also, it is well known that biomass is one of the important primary renewable energy sources because of carbon neutral energy. Furthermore, the utilization of biomass has been more and more concerned with the depletion of fossil fuel sources as well as the global warming issues. Combustion and thermal decomposition of biomass is one of the more promising techniques among all alternatives proposed for the production of energy from biomass. In this study, combustion of brown coals and mushroom waste was done. Mass change of samples and emission of hydrocarbon components were measured. As the results, we obtained combustion rate constant. Also activation energy was calculated in char combustion step. Hydrocarbon components were more generated in low oxygen concentration than high. Emission amount of hydrocarbon components in mushroom waste was significantly increased comparing to brown coal.

Synthetic Strategies for High Performance Hydrocarbon Polymer Electrolyte Membranes (PEMs) for Fuel Cells (고성능 탄화수소계 고분자 전해질막의 합성 전략)

  • Lee, So Young;Kim, Hyoung-Juhn;Nam, Sang Yong;Park, Chi Hoon
    • Membrane Journal
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    • v.26 no.1
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    • pp.1-13
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    • 2016
  • Fuel cells are regarded as a representative energy source expected to replace fossil fuels particularly used in internal combustion engines. One of the most important components is polymer electrolyte membranes (PEMs) acting as a proton conducting barrier to prevent fuel gas crossover. Since water channels act as proton pathways through PEMs, many researchers have been focused on the 'good phase-separation of hydrophilic moiety' which ensures high water retention under low humidity enough to keep the water channel for good proton conduction. Here, we summarized the strategies which have been adopted to synthesize sulfonated PEMs having high proton conductivities even under low humidified conditions, and hope this review will be helpful to design high performance hydrocarbon PEMs.

An Experimental Study on Analyses and Exhaust Emission Characteristics with EGBE Addition in D.I. Diesel Engine (직접분사식 디젤기관에서 EGBE 첨가에 의한 배기가스 배출특성과 분석에 관한 실험적 연구)

  • O, Yeong-Taek;Choe, Seung-Hun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.3
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    • pp.498-506
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    • 2002
  • Improvements of fuel properties have become essential for exhaust emission reduction as well as for optimization of directly-related design factors and exhaust gas aftertreatment. In this study, the potential possibility of oxygenated fuel such as ethylene glycol mono-n-butyl ether(EGBE) was investigated for the sake of smoke reduction from diesel engine. Because EGBE include oxygen content approximately 27%, it is a kind of effective oxygenated fuel that the smoke emission of EGBE is reduced remarkably in comparison with commercial diesel fuel, that is, it can supply oxygen component sufficient at high load and speed in diesel engine. And, it was tried to analyze the quantities of the low and high boiling point hydrocarbon among the exhaust emissions in diesel engine. It have been investigated by the quantitative analysis of the hydrocarbon $C_1$~ $C_{6}$ using the gas chromatography. This study was carried out by comparing the chromatogram with diesel fuel and diesel fuel blended EGBE 20vo1-%. The results of this study show that the hydrocarbon $C_1$~C$_{6}$ among the exhaust emission of the mixed fuels are exhausted lower than those of the diesel fuel at the all load and speed. In particular, high boiling point hydrocarbons such as $C_{5}$ and $C_{6}$ were reduced remarkably at high speed and load.d.

A Study on Heat Release Fluctuation Using Various Hydrocarbon Fuels (다양한 탄화수소 연료를 이용한 열방출 섭동 연구)

  • Hwang, Donghyun;Ahn, Kyubok
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.6
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    • pp.1-10
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    • 2016
  • For the active control of a combustion instability, a change should be made in pressure fluctuation or heat release fluctuation using an acoustic driver or a secondary fuel injection. Also, to determine the location and timing of a secondary fuel injection, one needs to know the distribution of heat release fluctuation under combustion instability. In the present research, the distribution of heat release fluctuation has been experimentally measured by changing hydrocarbon fuel, inlet velocity, equivalence ratio, and acoustic forcing condition. It was confirmed that heat release fluctuation with regards to vortex shedding was significantly affected by the $Damk{\ddot{o}}hler$ number. Under the cases of the $Damk{\ddot{o}}hler$ number above approximately 4 - 5, hot spot region was generated in the leading edge of vortex and cold spot region was in the trailing edge. On the contrary, the cases of the $Damk{\ddot{o}}hler$ number below 3 showed the opposite trend.

A Study on Emission Reductions of Diesel Engine Using Plasmatron Fuel Converter (플라즈마트론을 이용한 디젤 엔진의 매연저감에 관한 연구)

  • Ki, Ho-Beom;Kim, Bong-Soo;Kwak, Yong-Hwan;Kim, Woo-Hyung;Lim, Won-Kyung;Chae, Jae-Ou
    • 한국연소학회:학술대회논문집
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    • 2006.10a
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    • pp.104-109
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    • 2006
  • Improvements in internal combustion engine and aftertreatment technologies are needed to meet future environmental quality goals. Plasmatron fuel converters provide a rapid response, compact means to transform a wide range of hydrocarbon fuels (including gasoline, natural gas and diesel fuel) into hydrogen-rich gas. Hydrogen-rich gas can be used as an additive to provide NOx reductions of more than 80% in diesel engine vehicles by enabling very lean operation or heavy exhaust engine recirculation. For diesel engines, use of compact plasmatron reformers to produce hydrogen-rich gas for the regeneration of NOx absorber/absorbers and particulate traps for diesel engine exhaust after-treatment could provide significant advantages. Recent tests of conversion of diesel fuel to hydrogen-rich gas using a low current plasmatron fuel converter with non-equilibrium plasma features are described.

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