• Title/Summary/Keyword: Hydration water

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Drying Shrinkage of Ultra High Strength Steel-Fiber Reinforced Cementitious Composites (초고강도 강섬유 보강 시멘트 복합체의 자기수축 모델식에 관한 연구)

  • Kang, Su-Tae;Park, Jong-Sup;Joh, Chang-Bin;Park, Jung-Jun;Koh, Gyung-Taek;Kim, Byung-Suk
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.725-728
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    • 2008
  • Most of shrinkage is mainly caused by autogenous shrinkage in Ultra high strength steel-fiber reinforced cementitious composites(UHSFRC). water to binder ratio is very low, about 0.2. It occurs faster hydration and cause a large amount of autogenous shrinkage in early ages. the large autogenous shrinkage can cause harmful cracks in a structure and deteriorate the designed structural performance. therefore it is very important to predict the autogenous shrinkage accurately. The study about the autogenous shrinkage of UHSFRC was carried out in this paper. through comparing with JSCE recommendations for UHSFRC, it was found out that UHSFRC in this study showed higher autogenous shrinkage than that of JSCE. And Applicability of early proposed models by some researchers was also investigated. the analytical results let us know that Miyazawa's model showed the best agreement with the experimentally obtained autogenous shrinkage of UHSFRC.

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Engineering Characteristics of Coal Ash from Thermal Power Plants (화력발전소(火力發電所)에서 부산(副産)되는 석탄회(石炭灰)의 공학적(工學的) 특성(特性))

  • Chun, Byung Sik;Cho, Young Ku
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.8 no.2
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    • pp.59-66
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    • 1988
  • At the present time, annually about 2 million tons of coal ashes are generated from thermal power plants in Korea, however, they are dumped into ash ponds mixed with sea water very expensively. In this thesis, engineering characteristics of bituminous and anthracite ashes are studied to utilize them as construction materials. The coal ash is non-plactic material and its grain size falls in the range of silt, but it has better soil engineering characteristics than general soils of same grain size. For example, the permeability, shearing strength, CBR, and consolidation properties match to that of sandy soils, moreover, strengthening by hydration can be expected with the lapse of year because of CaO presence in the components. So, utilizing those coal ashes in a productive way as reclamation or banking materials is expected.

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Effects of Cloud Point of Non-ionic Surfactant on Deinking Efficiency of ONP at High Blending Ratio of OMG (비이온성 계면활성제의 운점이 OMG 배합비가 증가된 폐 신문지 탈묵효율에 미치는 영향)

  • Lee, Tai Ju;Seo, Jin Ho;Ryu, Jeong Yong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.6
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    • pp.164-169
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    • 2015
  • Nowadays blending ratio of OMG (old magazine) in recovered paper used for manufacturing newspaper have been increased. When large amount of OMG is consumed in newsprint mill, brightness can be improved by inorganic pigments of coating layer. On the other hand decrease in yield of deinking process will be encountered because the pigments can be removed as reject of froth flotation process. Therefore selection of the optimal deinking agent is an important. Non-ionic surfactant have been used widely in newsprint mill. Non-ionic surfactant has amphoteric characteristics. Hydrophilic group is ethylene and propylene oxide that can induce hydrogen bonding with water molecules. In this regard, cloud point is an important parameter in order to control efficiency of deinking process because hydration of the hydrophobic group can be varied according to temperature of a system. In this study, deinking properties of ONP at high blending ratio of OMG was analyzed according to cloud points of non-ionic surfactants. $L^*$, $a^*$, $b^*$, brightness and effective residual ink concentration did not affected by the change of cloud points. Especially, flotation reject decreased significantly according to increase in cloud point of the non-ionic surfactant. Consequently, when a nonionic surfactant having a cloud point higher than the temperature of the system is used, properties of the deinked pulp can be maintained and yield of deinking process can be improved.

Influence of Micro-Structural Characteristics of Concrete on Electrical Resistivity (콘크리트의 미세구조 특성이 전기저항에 미치는 영향)

  • Yoon, In-Seok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.6
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    • pp.122-129
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    • 2013
  • Since electrical resistivity of concrete can be measured in a more rapid and simple way than chloride diffusivity, it should be primarily regular quality control of the electrical resistivity of concrete which provides the basis for indirect of quality control of chloride diffusivity during concrete construction. If this is realized, the electrical resistivity of concrete can be a crucial parameter to establish maintenance strategy for marine concrete structures. The purpose of this study is to develop, design and test a surface electrical resistivity measurement protocol. Microstructural affecting factors such as capillary water, porosity, tourtousity, and so on, on the electrical resistivity of concrete were examined taking into account for mixing proportion properties, and hydration stage. This study can provide a non-destructive approach for durability design of marine concrete. From the relationship between electrical resistivity and chloride diffusivity, it is expected that the result is subsequently used as a calibration curve for an indirect control of the chloride diffusivity based on regular measurements of the electrical resistivity during concrete construction.

A Study on the Mechanical Properties of Polymer Repair-Mortars with CFBC Ash (순환유동층 보일러애시를 활용한 폴리머 보수 모르타르의 역학적 특성에 대한 연구)

  • Kang, Yong Hak;Lim, Gwi Hwan;Shin, Dong Cheol;Choi, Young Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.5
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    • pp.127-132
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    • 2018
  • The amount of generated Circulating Fluidized Bed Combustion ash (CFBC ash) is annually increasing, but most CFBC ash has been landfilled and discarded due to the limited utilization. The major chemical compositions of CFBC ash are $SiO_2$, CaO and $CaSO_4$, which could form hydration products by reacting with water as self-cementing property such as cement. The purpose of the this study is to derive the optimal mix proportions to improve polymer-modified mortar with the use of CFBC ash which has the self-cementing property. In order to develop polymer-modified mortar, three mix proportions were determined, and fundamental properties for the mixtures were obtained. As a result, the optimal mixture containing 10 percent of silica fume, 1.0 percent of polymer and 3.5 percent of expansive additives were proposed in this study.

Feasibility Study on the Use of CFBC Ash as Non-sintered Binder (순환유동층 보일러애시를 활용한 비소성 결합재로써의 활용 가능성 검토)

  • Kang, Yong Hak;Lim, Gwi Hwan;Kim, Sang Jun;Choi, Young Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.5
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    • pp.119-126
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    • 2018
  • Recently, the production of circulating fluidized bed combustion ash has been increased in thermal power plants. The addition of limestone for the desulfurizing effect of circulating fluidized bed boiler ash increases the content of CaO and $SO_3$ contained in ash, which is higher than the free fly ash in general fly ash. Unlike conventional fly ash, the circulating fluidized bed combustion ash has a high reactivity when it comes into contact with water due to its hydraulic properties and high free-CaO content. The aim of this study is to investigate the possibility of non-sintered binder by using self-cementing properties of circulating fluidized bed combustion ash. The mechanical and hydration characteristics were investigated according to the content of CFBC ash. In addition, the effects of gymsum type and content on the compressive strength and micro-structure of non-sintered binder pastes.

Aggravating and Mitigating Patient Factors Affecting Mild to Moderate Atopic Dermatitis (중등도 이하 아토피 피부염에 영향을 미치는 환자 요인)

  • Kang, Dong-Won;Kim, Yoon-Bum
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.33 no.4
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    • pp.1-15
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    • 2020
  • Objectives : To investigate aggravating and mitigating factors of atopic dermatitis and to utilize the outcome in treatment planning. Methods : The research has a cross-sectional study design. Patients' SCORing Atopic Dermatitis (SCORAD) Index, demographic, physical characteristics, social history, serologic index and skin related instrumental measurements were analyzed with correlation and regression analysis method. Results : 48 patients in total were enrolled in the study. Skin Surface Hydration (SSH) and sex were found to be statistically significant aggravating and mitigating factors. As SSH increased, Total SCORAD (tSCORAD) and Objective SCORAD (oSCORAD) increased as well. As SSH decreased, tSCORAD and oSCORAD decreased as well. Female patient had a higher probability of suffering from severer subjective symptoms than that of male. Age, body mass index (BMI), alcohol consumption and smoking, transepidermal water loss (TEWL), IgE, IL-4, IL-5, IL-6, IFN-γ were found not to be statistically significant. There was no correlation between Subjective SCORAD (sSCORAD) and oSCORAD neither with Eczema Area and Severity Index (EASI). Conclusions : Increasing cutaneous moisture should be included in the treatment plan of atopic dermatitis. More emphasis should be put on alleviating subjective discomforts of female patients than that of male. Establishing separate strategies of managing objective eczema status and subjective discomforts respectively should be considered.

Solidification/stabilization of simulated cadmium-contaminated wastes with magnesium potassium phosphate cement

  • Su, Ying;Yang, Jianming;Liu, Debin;Zhen, Shucong;Lin, Naixi;Zhou, Yongxin
    • Environmental Engineering Research
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    • v.21 no.1
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    • pp.15-21
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    • 2016
  • Magnesium potassium phosphate cement (MKPC) is an effective agent for solidification/stabilization (S/S) technology. To further explore the mechanism of the S/S by MKPC, two kinds of Cd including $Cd(NO_3)_2$ solution (L-Cd) and municipal solid waste incineration fly ash (MSWI FA) adsorbed Cd (S-Cd), were used to compare the effects of the form of heavy metal on S/S. The results showed that all the MKPC pastes had a high unconfined compressive strength (UCS) above 11 MPa. For L-Cd pastes, Cd leaching concentration increased with the increase of Cd content, and decreased with the increase of curing time. With the percentage of MSWI FA below 20%, S-Cd pastes exhibited similar Cd leaching concentrations as those of L-Cd pastes, while when the content of MSWI FA come up to 30%, the Cd leaching concentration increased significantly. To meet the standard GB5085.3-2007, the highest addition of S-Cd was 30% MSWI FA (6% Cd contained), with the Cd leaching concentration of 0.817 mg/L. The S/S of L-Cd is mainly due to chemical fixation, and the hydration compound of Cd was $NaCdPO_4$, while the S/S of S-Cd is due to physical encapsulation, which is dependent on the pore/crack size and porosity of the MKPC pastes.

Percutaneous Absorption Characteristics of Antidepressant Paroxetine (항우울제인 Paroxetine의 피부 투과 특성 연구)

  • Jung, Duck-Chae;Hwang, Sung-Kwy;Oh, Se-Young
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.2
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    • pp.170-177
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    • 2011
  • Transdermal drug delivery(TDS) offers many important advantages. For instance, it is easy and painless, it protects the active compound from gastric enzymes, and it avoids the hepatic first-pass effect. Also, it is simple to terminate the therapy if any adverse or undesired effect occurs. But skin is a natural barrier, and only a few drugs can penetrate the skin easily and in sufficient quantities to be effective. Therefore, in recent years, numerous studies have been conducted in the area of penetration enhancement. The most commonly used transdermal system is the skin patch using various types of technologies. Compared with other method of dosage, it is possible to use for a long term. It is also possible to stop the drug dosage are stopped if the drug dosage lead to side effect. Polysaccharide, such as xanthan gum and algin were selected as base materials of TDS. Also, these polymers were characterized in terms of enhancers and drug contents. Among these polysaccharide, the permeation rate of Paroxetine such as lipophilic drug was the fastest in xanthan gum matrix in vitro. We used glycerin, PEG400 and PEG800 as enhancers. Since dermis has more water content(hydration) than the stratum corneum, skin permeation rate at steady state was highly influenced when PEG400 was more effective for lipophilic drug. Proper selection of the polymeric materials which resemble and enhance properties of the delivering drug was found to be important in controlling the skin permeation rate.

Percutaneous absorption Characteristics of Anti hyperlipidemia Gel Ointment using Fibric acid (Fibric acid를 이용한 항고지혈증 겔 연고의 경피 흡수 특성)

  • Jung, Duck-Chae;Hwang, Sung-Kwy;Oh, Se-Young
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.4
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    • pp.407-414
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    • 2010
  • New biological treatments were being developed at a record place, but their potential could be compromised by a significant obstacle: the delivery of these drugs into a body. Pharmaceutical delivery is now nearly as important as product. New systems are being developed, and Drug Delivery Markets Series cover these new systems. Transdermal Delivery System(TDS) is often used as a method of drug dosage into the epidermic skin. An approach used to delivery drugs through the skin for therapeutic use as an alternative to oral, intravascular, subcutaneous and transmucosal routes. Various transdermal drug delivery technologies are described including the use of suitable formulations, carriers and penetration enhancers. The most commonly used transdermal system is the skin patch using various types of technologies. Compared with other methods of dosage, it is possible to use for a long term. It is also possible to stop the drug dosage are stopped if the drug dosage lead to side effect. Polysaccharides, such as karaya gum and glucomannan, were selected as base materials of TDS. Also, these polymers were characterized in terms of enhancers, drug contents. Among these polysaccharide, the permeation rate of karaya gum matrix was fastest in fibric acid(ciprofibrate) such as lipophilic drug in vitro. We used glycerin, PEG400 and PEG800 as enhancers. Since dermis has more water content(hydration) than the stratum corneum, skin permeation rate at steady state was highly influenced when PEG400 was more effective for lipophilic drug. Proper selection of the polymeric materials which resemble and enhance properties of the delivering drug was found to be important in controlling the skin permeation rate. Especially, this result suggests a possible use of polysaccharide gel ointment matrix as a transdermal delivery system of anti-hyperlipoproteinemic agent.