• Title/Summary/Keyword: Hydration products

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Mechanical and Chemical Characteristics of Bottom Ash Aggregates Cold-bonded with Fly Ash (플라이애시로 표면개질한 바텀애시 경량골재의 물리 화학적특성)

  • Kim, Hyeong-Ki;Ha, Kyung-Ae;Jang, Jeong-Gook;Lee, Haeng-Ki
    • Journal of the Korean Ceramic Society
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    • v.51 no.2
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    • pp.57-63
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    • 2014
  • Bottom ash can be used as pelletizing seeds in unsintered artificial lightweight aggregates, so it can be called as 'cold-bonded aggregates'. In the present study, the mechanical and chemical characteristics of bottom ash aggregates cold-bonded with fly ash were investigated. The crushing strength and the water transfer characteristic of the aggregates, which may affect the strength gain of the concrete, were evaluated. Moreover, the degree of hydration and the hydration products of the aggregates were analyzed to verify the chemical stability of the aggregates. Compared to commercialized artificial lightweight aggregates manufactured by sintering process, cold-bonded fly/bottom ash aggregates had similar levels of water transfer characteristics, while having lower strengths. The calcium hydroxide in the aggregates was almost completely consumed after 28 days moist curing.

An Experimental Study of Precast concrete Alters Cement Types of High-Strength Concrete (시멘트종류를 변화시킨 프리캐스트 고강도 콘크리트의 실험적 연구 - 수화열 온도특성을 중심으로 -)

  • Park, Heung-Lee;Kim, Sung-Jin;Paik, Min-Su;Lee, Seung-Hoon;Park, Byung-Keun;Jung, Sang-Jin
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2009.05b
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    • pp.119-122
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    • 2009
  • As architectures have recently become high-risers and mega-structured, stable high strength products have been ensured. Accordingly, use of precast concrete accouplement has been increased in order to facilitate air compression and rationalize construction. Since not only external heating but a1so internal temperature rise caused by the accumulation of cement hydration heat in manufacturing process, precast concrete members with large cross-section used for high-rise mega-structure's columns and beams may exhibit different temperature history compared to the precast concrete members for wall and sub-floor with relatively small cross-sections. Therefore, this study aims to elucidate the characteristics of temperature history of mass concrete members cast with high-strength concrete fur precast concrete application. In this study, large cross-sectional precast concrete mock-up, unit cement quantity, and temperature histories in manufacturing precast concrete member under different curing condition were inclusively investigated.

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Resistance to Sea Water of Hardened Cement with Calcium Sulfoaluminate Type Expansive Additives(I) (칼슘 설포알루미네이트계 팽창재를 혼합한 시멘트 경화체의 내해수성(I))

  • 전준영;송종택
    • Journal of the Korean Ceramic Society
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    • v.40 no.3
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    • pp.234-240
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    • 2003
  • Hardened cement pastes of OPC which contains 10 wt% CSA type expansive additives were immersed in aqueous solution of 10 wt% MgS $O_4$.7$H_2O$ and then investigated by compressive strength, XRD. SEM and DSC etc.. According to the results including the hydration products and the microstructure of the hardened paste, the case of CSA type expansive additives[No. 6(C/(equation omitted) : 2.29, A/(equation omitted) : 0.16)] prepared from raw materials increased the resistance to $Mg^{2+}$, S $O_4$$^{2-}$ ion diffusion than that of OPC paste due to the densification by the formation of fine ettringite in the first stage and the hydrates according to $\beta$-C$_2$S hydration in the late period.

A Study on Pretreated Paper Sludge Ash for Cement Admixture (시멘트 혼합재로의 전처리 제지애쉬 적용가능성 연구)

  • Jung, Jae-Hyun;Seo, Seong-Kwan;Chu, Yong-Sik
    • Resources Recycling
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    • v.25 no.6
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    • pp.58-64
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    • 2016
  • Paper industry discharges many by-products and quantity of PSA (Paper sludge ash) has been increased. In this study, hydration water was added to PSA for use as cement admixture. PSA with added water was mixed with anhydrite and this mixture was used as cement substitute. Physical properties of PSA cement were changed by contents of PSA, but PSA cement containing PSA less than 10% had similar properties to those of OPC. Compressive strength of PSA cement mortar had a certain relationship with $Ca(OH)_2$ content. Compressive strength at 3 days increased, as $Ca(OH)_2$ content increased. However, the strength at 28 days increased, as $Ca(OH)_2$ content decreased.

Korean native wild herbal-based functional ingredient for skin health: Agatri® (Agastache rugosa extract) (피부 건강을 위한 국내 자생 천연 식물 원료: Agatri® (배초향 추출물))

  • Kim, Sang Woo
    • Food Science and Industry
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    • v.53 no.4
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    • pp.382-389
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    • 2020
  • "Eating cosmetic" market comes to prominence worldwide. Inner Beauty has established itself as the top trend nowadays and is leading the health functional food market. Another noticeable trend other than beauty-from-within is that products using "plant-based" natural botanical raw material are increasing. Based on these trends above, we have developed a plant extract named Agatri® for skin health using Agastache rugosa. By ingesting Agatri®, it is expected that the formation of skin wrinkles is suppressed, and skin elasticity is increased by suppressing the decrease in collagen content caused by ultraviolet rays. At the same time, it is possible to prevent skin aging by improving skin hydration and trans-epidermal water loss (TEWL). The studies show that it significantly increased production of hyaluronic acid and collagen, and decreased production of matrix metalloproteinases (MMPs). And Agatri® has been approved as an "Individually recognized functional ingredient for skin health by the Ministry of Food and Drug Safety, Korea in 2020. As a result, Agatri® is a good solution for those who are in need of skin protection from exposure to UV and aging.

Evaluation of Hydration Reactivity of Recycled Cement for the Utilization of Radioactive Waste Solidifying Materials (방사성 폐기물 고화재 활용을 위한 재생시멘트의 수화반응성 평가)

  • Choi, Yu-Jin;Kim, Ji-Hyun;Chung, Chul-Woo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.167-168
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    • 2022
  • Recently, starting with the permanent suspension of Gori 1 in Korea, the importance of the disposal of concrete structures in nuclear power plants has emerged, and environmental and safety are required to be proved accordingly. Safe radioactive waste disposal technology that immobilizes harmful radioactive elements, which are by-products of nuclear power, inside a solid matrix and recycling measures are needed to secure an efficient waste disposal space. This study was conducted to confirm whether recycled cement generated in the process of radioactive concrete treatment can be used as a solidifying material for radioactive waste treatment. In order to simulate the concrete exposed to radiation, aqueous solutions of Di-water, CsCl 1M, and CoCl2 1M were used as blending water at W/B 0.5. Tricalcium phosphate and Prussian blue were substituted with 5 wt.% based on the weight of recycled cement as a binder to improve solidification performance, and their hydration characteristic was analyzed.

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Study on the Skin Characteristic and Questionnaire according to Yin Deficiency Syndrome (한방 음허변증에 따른 피부특성 및 설문 분석 연구)

  • Min, Seorim;Myoung, Jooonoh;Kim, Byunghyun;Kim, Taehoon;Hwang, Seung Jin;Lim, Jun-Man;Jin, Mu Hyun
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.45 no.4
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    • pp.381-388
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    • 2019
  • Recently, the importance of individual skin characteristic is emphasized for customized beauty products. There are many studies on the concept of the syndrome differentiation, related to individual cosmetics in Korean Medicine. However, skin characteristic according to Yin deficiency syndrome (YDS), which is associated with aging, are yet to be clarified. The objective of this study was to evaluate the skin characteristic and questionnaire of female with YDS compare to with non-YDS. 218 healthy females between 40 and 59 years of age were assessed for the skin hydration, elasticity, brightness (L* value), redness (a* value), pore, pigmentation, wrinkle, and sebum by Corneometerr®, Cutometerr®, and Janus lll. Independent t-test showed lower hydration, lower elasticity, and higher redness in the YDS group compared to the non-YDS group (all p < 0.05). There was significant difference on the facial fever, insomnia, decreased amount of urine, and skin sensitive checklist. These results suggested that using the questionnaire associated with YDS and skin characteristic could separate skin types and apply to customized beauty products.

Carbonation Characteristics of Alkali Activated Blast-Furnace Slag Mortar (알칼리활성 고로슬래그 모르타르의 탄산화 특성)

  • Song, Keum-Il;Yang, Keun-Hyeok;Lee, Bang-Yeon;Song, Jin-Kyu
    • Journal of the Korea Concrete Institute
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    • v.24 no.3
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    • pp.315-322
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    • 2012
  • Alkali-activated slag (AAS) is the most obvious alternative materials that can replace OPC. But, AAS industrial usage as a structural material should be evaluated for its durability. Carbonation resistance is one of the most important factors in durability evaluation. Test results for 18 slag-based mortars activated by sodium silicate and 6 OPC mortars were obtained in this study to verify the carbonation property. Main variables considered in the study were flow, compressive strength before and after carbonation, and carbonation depth. Mineralogical and micro-structural analysis of OPC and AAS specimens prior to and after carbonation was conducted using XRD, TGA, FTIR FE-SEM. Test results showed that CHS was major hydration products of AAS and, unlike OPC, no other hydration products were found. After carbonation, CSH of hydration product in AAS turned into an amorphous silica gel, and alumina compounds was not detected. From the analysis of the results, it was estimated that the micro-structures of CSH in AAS easily collapsed during carbonation. Also, the results showed that this collapse of chemical chain of CSH lowered the compressive strength of concrete after carbonation. By increasing the dosage of activators, carbonation resistance and compressive strength were effectively improved.

The Strength Characteristics of CO2-reducing Cement Mortar using Porous Feldspar and Graphene Oxide (다공성 장석 및 산화그래핀을 적용한 탄소저감형 시멘트 모르타르 강도특성)

  • Lee, Jong-Young;Han, Jung-Geun
    • Journal of the Korean Geosynthetics Society
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    • v.20 no.4
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    • pp.1-7
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    • 2021
  • In response to the carbon emission reduction trends and the depletion of natural sand caused by the use of cement in construction works, graphene oxide and porous feldspar were applied as countermeasures in this study. By using (3-aminopropyl)trimethoxysilane-functionalized graphene oxide with enhanced bond characteristics, a concrete specimen was prepared with 5% less cement content than that in a standard mortar mix, and the compressive strengths of the specimens were examined. The compressive strengths of the specimen with (3-aminopropyl)trimethoxysilane-functionalized graphene oxide and porous feldspar and the specimen with standard mixing were 26MPa and 28MPa, respectively, showing only a small difference. In addition, both specimens met the compressive strength of cement mortar required for geotechnical structures. It is believed that a reasonable level of compressive strength was maintained in spite of the lower cement content because the high content of pozzolans, namely SiO2 and Al2O3, in the porous feldspar enhanced the reactions with Ca(OH)2 during hydration, the nano-sized graphene surface acted as a reactive surface for the hydration products to react actively, and the strong covalent bonding of the carboxyl functional group increased the bonding strength of the hydration products.

Diosmetin and Its Glycoside, Diosmin, Improve Atopic Dermatitis-Like Lesions in 2,4-Dinitrochlorobenzene-Induced Murine Models

  • Park, Sang-a;Bong, Sim-Kyu;Lee, Jin Woo;Park, No-June;Choi, Yongsoo;Kim, Sang Moo;Yang, Min Hye;Kim, Yong Kee;Kim, Su-Nam
    • Biomolecules & Therapeutics
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    • v.28 no.6
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    • pp.542-548
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    • 2020
  • Naturally derived diosmetin and its glycoside diosmin are known to be effective in treating inflammatory disease. This study was performed to determine whether diosmin and diosmetin have the effect of improving atopic dermatitis in a 2,4-dinitrochlorobenzen (DNCB)-induced atopic dermatitis (AD) model. DNCB was used to establish AD model in hairless mice. Skin moisture, serum immunoglobulin E (IgE), interleukin 4 (IL-4), and histological analysis were performed to measure the effectiveness of diosmin and diosmetine to improve AD. IL-4 levels were also measured in RBL-2H3 cells. Administration of diosmetin or diosmin orally inhibited the progress of DNCB-induced AD-like lesions in murine models by inhibiting transdermal water loss (TEWL) and increasing skin hydration. Diosmetin or diosmin treatment also reduced IgE and IL-4 levels in AD-induced hairless mouse serum samples. However, in the in vitro assay, only diosmetin, not diosmin, reduced the expression level of IL-4 mRNA in RBL-2H3 cells. Diosmin and diosmetine alleviated the altered epidermal thickness and immune cell infiltration in AD. Diosmin is considered effective in the cure of AD and skin inflammatory diseases by being converted into diosmetin in the body by pharmacokinetic metabolism. Thus, oral administration of diosmetin and diosmin might be a useful agent for the treatment of AD and cutaneous inflammatory diseases.