• 한국세라믹학회지
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• 제24권2호
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• pp.133-138
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• 1987

The behavior of CaO and SiO2 in the reaction produced which produced in the early hydration of C3S was studied by XRD and thermal analyzer. Polymerization of hydrated siltcates was also studied by TMS method. TMS derivatives were separated by gaschromatography. Cao/SiO2 molar ratios of the produced CSH gel under the air atmosphere were higher than that in the CO2. Dimerization rate of hydrated silicates was very fast in the early hydration stage. Trimer began to appear later than dimer and its increasing rate was very low. The amount of dimer and trimer formed under the CO2 atmosphere was less than that in the air.

• 한국지반공학회논문집
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• 제19권6호
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• pp.127-149
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• 2003

본 교량은 교축방향에 대해 사각 60도인 90m 3경간 연속 완전 일체식 교대교량이다. 이 교량의 상부슬래브 콘크리트 타설후, 7일간의 콘크리트 양생에 따른 H말뚝의 수평거동을 알아보기 위하여, H말뚝 축방향으로 매설형 경사계와 변형률계를 설치하여 계측을 실시하였다. 이때 계측 결과를 수화열 및 건조수축 전용프로그램인 HACOM의 해석결과와 H말뚝의 횡방향 비선형 p-y 모델해석 거동에 비교하였다. 그 결과에 의하면, 실측한 H말뚝의 수평변위는 상부슬래브 콘크리트가 양생함에 따라 발생하는 수화열과 건조수축에 영향을 받았고, 그 크기는 각각 2.2mm, 1.4mm이었다. 말뚝 축방항 수평변위의 변곡점은 교대 기초저면에서 1.3m 위치에서 발생하였다. 이는 이 교량의 교대말뚝은 말뚝머리 고정조건으로 거동하는 것이 아니라 이와 매우 유사한 거동을 보였다. 그리고 실측한 말뚝의 휨응력 거동은 말뚝머리 회전구속과 같은 거동을 보이지 않고, 연직방향의 하중전이와 같은 거동을 나타내었다. 또한 교대말뚝의 비선형 p-y 모델해석으로 구한 최대휨응력 증분량의 크기는 약 300(kgf/$\textrm{km}^2$)이었고, 교대말뚝의 계측기 부착위치와는 무관하게 실측한 값보다 약 2배 크게 발생하였다. 그리고 말뚝의 비선형 p-y 모델해석에서 말뚝의 수평하중, 최대수평 변위, 최대휨응력, 최대휨모멘트는 콘크리트 양생시간에 따라 모두 선형적인 거동을 보였다.

• 한국세라믹학회지
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• 제39권6호
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• pp.528-534
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• 2002

CaO ceramics were prepared by conventional sintering process and their hydration behaviors were evaluated by measuring weight increment on saturated water vapor pressure at ambient temperature. CaCO$_3$ and limestone were used as CaO source materials and $Al_2$O$_3$, MgO and SiO$_2$ were added as sintering agents. $Al_2$O$_3$ was a liquid phase sintering agent to increase densification and grain growth rates, whereas MgO and SiO$_2$, densification and grain growth inhibitors. Regardless of composition, all of the prepared CaO ceramics showed the improved hydration resistance as bulk density increased. Especially, when bulk density was more than 3.0 g/㎤, there was no weight increment after 120 h of hydration. Therefore, to decrease contact area between CaO and water vapor by increasing bulk density with the $Al_2$O$_3$ sintering additive was effective for the improvement of CaO hydration resistance.

• 자원리싸이클링
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• 제24권1호
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• pp.12-20
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• 2015

본 연구에서는 고로 수쇄 슬래그 및 석고를 혼합한 3성분계 천연 수경성 석회 페이스트에서 석고종류 및 혼합량에 따른 수화특성 변화를 확인하고자 하였다. 고로 수쇄 슬래그 20 %를 혼합한 천연 수경성 석회에 무수석고, 반수석고, 이수석고를 각각 3 %, 10%를 혼합하여 석고의 용해도 및 반응성에 따라 수화초기 생성되는 수화물의 종류와 생성량을 분석하였으며, 이에 따른 물리적 특성 변화거동에 대하여 조사하였다. 페이스트를 활용한 수화특성 결과 모든 샘플에서 수화초기 ettringite, C-S-H와 같은 수화물이 생성되었으며, 재령이 길어짐에 따라 수화물의 생성량이 증가하였다. 압축강도 측정결과, 석고 혼합량이 3 %일 때 더 높은 강도를 보였으며 재령 28일에서 무수석고 및 반수석고가 이수석고를 혼입할 경우 보다 높은 특성을 나타내었다.

• Computers and Concrete
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• 제8권6호
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• pp.647-675
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• 2011

Our ability to predict hydration behavior is becoming increasingly relevant to the concrete community as modelers begin to link material performance to the dynamics of material properties and chemistry. At early ages, the properties of concrete are changing rapidly due to chemical transformations that affect mechanical, thermal and transport responses of the composite. At later ages, the resulting, nano-, micro-, meso- and macroscopic structure generated by hydration will control the life-cycle performance of the material in the field. Ultimately, creep, shrinkage, chemical and physical durability, and all manner of mechanical response are linked to hydration. As a way to enable the modeling community to better understand hydration, a review of hydration models is presented offering insights into their mathematical origins and relationships one-to-the-other. The quest for a universal model begins in the 1920's and continues to the present, and is marked by a number of critical milestones. Unfortunately, the origins and physical interpretation of many of the most commonly used models have been lost in their overuse and the trail of citations that vaguely lead to the original manuscripts. To help restore some organization, models were sorted into four categories based primarily on their mathematical and theoretical basis: (1) mass continuity-based, (2) nucleation-based, (3) particle ensembles, and (4) complex multi-physical and simulation environments. This review provides a concise catalogue of models and in most cases enough detail to derive their mathematical form. Furthermore, classes of models are unified by linking them to their theoretical origins, thereby making their derivations and physical interpretations more transparent. Models are also used to fit experimental data so that their characteristics and ability to predict hydration calorimetry curves can be compared. A sort of evolutionary tree showing the progression of models is given along with some insights into the nature of future work yet needed to develop the next generation of cement hydration models.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 봄 학술발표회 논문집(I)
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• pp.281-286
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• 1999

Nonlinear temperature distribution induced by the hydration heat generates thermal stress in mass concrete. At early ages, such thermal stress may induce thermal cracks in the structure which can affect on the durability and safety of the structure. Up to now, a lot of works have focused on the prediction of temperature distribution and thermal stress in the structure. In most of such works, however, the inside of structure was considered as adiabatic state to predict temperature distribution and the thermal stress. And due to the lacks of appropriate analysis models after crack, there was little research on the crack occurrence. This paper deals with the prediction of the temperature distribution in the structure using the rate of hydration heat generation and also estimates the behavior of structure before and after cracking due to hydration heat using crack band model.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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• pp.301-304
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• 2003

Nowadays, hydration heat analysis using FEM is common in thermal crack control of concrete structure. Many kinds of general FEM programs for hydration heat analysis are used in practice. But there are some problems in this using. In this study hydration heat analysis of wall according to placement length are performed. In this results we could get two conclusions. First, general structures like wall having general geometry and construction condition have similar behavior. So it is not necessary to analysis thermal crack in every case. Second, the results of 2D analysis is possible to be applied instead of those of 3D analysis because the results of 2D analysis is similar to 3D analysis in long wall having about 15~18m or over length at 3m height.

• 한국세라믹학회지
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• 제35권12호
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• pp.1241-1248
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• 1998

$\beta$-C2S and C4A3 were synthesized separately and potassium oxalate was added to each system. The ad-ditive caused calcium ions in solution to decrease at early time in hydration and promoted hydration reac-tion. And then clinker which is mainly composed of $\beta$-C2S and C4A3 was synthesized at 130$0^{\circ}C$ After ad-ding potassium oxalate to it behavior of hydration was observed. It showed that the additive promoted et-tringtie formation at early time and C-S-H formation as time went on.

• 한국세라믹학회지
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• 제32권5호
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• pp.527-534
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• 1995

In this research, the emphasis was focused on the rearrangement and densification behavior of CaO particles when the aluminum was added to improve the hydration resistance. For the case of 0.5vol% Al added specimen, the rearrangement of CaO particles due to liquid aluminum was terminated near 140$0^{\circ}C$ where the theoretically calculated fractional volume of solid reached 0.74 under Ar atmosphere. The density of the specimen sintered at 155$0^{\circ}C$ for 5hrs reached 96% of relative theoretical density when the ambient was switched to O2 at intermediate and final stages of the sintering. The weight gain due to the hydration after 60 days under 72% of relative humidity at 26$^{\circ}C$ was less than 1%.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 2006년도 정기 학술대회 논문집
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• pp.898-905
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• 2006

In the present paper, for a quantitative assessment of early-age cracking in an RC wall, an improved analytical model is proposed. First of all, a three-dimensional finite element model for the analysis of stresses due to hydration heat and differential drying shrinkage is introduced. A discrete steel element derived using the equivalent nodal force concept is used to simulate reinforcing steels, embedded in a concrete matrix. In advance, to quantitatively calculate the cracking potential, an analytical model that can estimate the post-cracking behavior in an RC tension member is proposed Subsequent comparisons. of analytical results with test results verify that the combined use of both the finite element model for the stress analysis as well as the analytical model for the estimation of the post-cracking behavior in an RC tension member make it possible to accurately predict the cracking ,behavior of RC walls.