The Effect of Potassium Oxalate on Hydration of Cement with the Ternary System of $C_2$S-C$_4$A$_3$-CS

C$_2$S-C$_4$A$_3$-CS 3성분계 시멘트의 수화에 미치는 Potassium Oxalate 첨가의 영향

  • 강승규 (한라시멘트 기술연구소) ;
  • 최상홀 (한양대학교 공과대학 무기재료공학과)
  • Published : 1998.12.01

Abstract

$\beta$-C2S and C4A3 were synthesized separately and potassium oxalate was added to each system. The ad-ditive caused calcium ions in solution to decrease at early time in hydration and promoted hydration reac-tion. And then clinker which is mainly composed of $\beta$-C2S and C4A3 was synthesized at 130$0^{\circ}C$ After ad-ding potassium oxalate to it behavior of hydration was observed. It showed that the additive promoted et-tringtie formation at early time and C-S-H formation as time went on.

Keywords

References

  1. World Cement Thechnology v.9 no.4 Investigation on Energy Saving Cement P. K. Mehta
  2. 9th Inter. Cong. Chem. Cement v.Ⅶ Present Problem in Cement Manufacturing H. Uchikawa
  3. 7th Inter. Cong. Chem. Cem. v.2 Cement Along the Join C₄A₂$\={S}$-C₂S K. Ikeda
  4. 7th Inter. Cong. Chem. Cem. v.3 High Strength cement in the CaO-Al₂O₃-SiO₂-SO₃System and Its Application G. Sudoh;T. Ohata
  5. 7th Inter. Cong. Chem. Cem. v.4 Sulfoaluminate Cement Series Deng Jun-An;Ge Wen-Min
  6. JCA Proceeding of Cement and Concrete v.47 Fundamental Studies of Concrete with Belite Type Portland Cement S. Nagaoka;T. Kuroda;M. Mizukoshi
  7. Cem and Conc. Res. v.26 no.8 High Belite Cement-Present Status and Future Technological Options A. K. Chatterjee
  8. Cement and Concrete no.548 Belite Cement K. Yoshida;T. Takahashi
  9. J. Mat. Sci. v.14 The Chemistry of Dicalcium Silicate Material N. Surendra;P. Ghosh;Rao Bhaskara
  10. 9th Inter. Cong. Chem. Cem. v.1 Mineralizers, Modifiers and Activators in the Clinker Process G. K. Molr;F. P. Glassem
  11. 9th Inter. Cong. Chem. Cem. v.1 The Crystal Structure of C₄A₃$\={S}$ Zhang Plexing;Chen Yimin;Shi Liping
  12. J. Kor. Ceram. Soc. v.27 no.2 Synthesis and Hydration of Modfied Belite Cement Clinker C. B. Kim;K. S. Han;S. H. Choi
  13. Quantitative X-ray Spectrometry Ron Jekins;R. W. Gould;Dale Gedcke
  14. Elecments of X-ray Diffration Quantitative Analysis(2nd Ed) B. D. Cullity
  15. Cem. and Conc. Res. v.13 Theorics of Expansion in Sulfoaluminate-Type Expansive Cement M. D. Cohen
  16. Cem. and Conc. Res. v.22 Mechanism of Ettringite and Momosulphate Formation J. Havlica;S. Sahu
  17. Cem. and Conc. Res. v.2 The Paste Hydration of 4CaO.3Al₂O₃ SO₃in Presence of Calcium Sulphate, Tricalcium Silicate and Dicalcium Silicate Mario Collepardi;Renato Turriziani
  18. Cem. and Conc. Res. v.21 Very Early Hydration of Dicalcium Silicate-Polymorphs R. Trettin;G. Oliew