• Title/Summary/Keyword: Hybrid membrane

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Roles of polypropylene beads and pH in hybrid water treatment of carbon fiber membrane and PP beads with water back-flushing

  • Song, Sungwon;Park, Yungsik;Park, Jin Yong
    • Membrane and Water Treatment
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    • v.10 no.2
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    • pp.155-163
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    • 2019
  • The roles of polypropylene (PP) beads and pH on membrane fouling and treatment efficiency were investigated in a hybrid advanced water treatment process of tubular carbon fiber membranes (ultrafiltration (UF) or microfiltration (MF)) and PP beads. The synthetic feed including humic acid and kaolin flowed inside the membrane, and the permeated contacted the PP beads fluidized in the space between the membrane and the module with UV irradiation and periodic water back-flushing. In the hybrid process of UF ($0.05{\mu}m$) and PP beads, final resistance of membrane fouling ($R_f$) after 180 min increased as PP beads increased. The turbidity treatment efficiency was the maximum at 30 g/L; however, that of dissolved organic matters (DOM) showed the highest at PP beads 50 g/L. The $R_f$ strengthened as pH of feed increased. It means that the membrane fouling could be inhibited at low alkali condition. The treatment efficiency of turbidity was almost constant independent of pH; however, that of DOM showed the maximum at pH 5. For MF ($0.1{\mu}m$), the final $R_f$ was the minimum at PP beads 40 g/L. The treatment efficiencies of turbidity and DOM were the maximum at PP beads 10 g/L.

Effect of Organic Materials in Water Treatment by Hybrid Module of Multi-channel Ceramic Microfiltration and Activated Carbon Adsorption

  • Park, Jin-Yong;Lee, Sang-Min
    • Korean Membrane Journal
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    • v.11 no.1
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    • pp.21-28
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    • 2009
  • We investigated the effect of organic materials on membrane fouling in advanced drinking water treatment by a hybrid module packed with granular activated carbon (GAC) outside multi-channel ceramic microfiltration membrane. Synthetic water was prepared with humic acid and kaolin to simulate natural water resouces consisting of natural organic matter and inorganic particles. Kaolin concentration was fixed at 30 mg/L and humic acid was changed as 2~10 mg/L to inspect the effect of organic matters. Periodic back-flushing using permeate water was performed for 10 sec per filtration of 10 min. As a result, both resistance of membrane fouling (Rf) and permeate flux (J) were influenced highly by concentration of humic acid. It proved that NOM like humic acid could be an important factor on membrane fouling in drinking water treatment. Turbidity and UV254 absorbance were removed up to above 97.4% and 59.2% respectively.

Spring-back prediction for sheet metal forming process using hybrid membrane/shell method (하이브리드 박막/쉘 방법을 이용한 박판성형공정의 스프링백 해석)

  • F. Pourboghrat
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1999.03b
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    • pp.62-65
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    • 1999
  • To reduce the cost of finite element analyses for sheet forming a 3D hybrid membrance/sheel method has been developed to study the springback of anisotropic sheet metals. in the hybrid method the bending strains and stresses were analytically calculated as post-processing using incremental shapes of the sheet obtained previously from the membrane finite element analysis. To calculate springback a shell finite element model was used to unload the final shape of the sheet obtained from the membran code and the stresses and strains that were calculated analytically. For verification the hybrid method was applied to predict the springback of a 2036-T4 aluminum square blank formed into a cylindrical cup. the springback predictions obtained with the hybrid method was in good agreement with results obtained using a full shell model to simulateboth loading an unloading and the experimentally measured data. The CPU time saving with the hybrid method over the full shell model was 75% for the punch stretching problem.

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Preparation of Polyethersulfone Ultrafiltration Membranes Containing $ZrO_2$ Nanoparticles by Combining Phase-inversion Method/Sol-gel Technique (상변환/졸-겔법에 의한 $ZrO_2$ 나노입자 함유 Polyethersulfone 한외여과 막의 제조)

  • Youm, Kyung-Ho;Lee, Yun-Jae
    • Membrane Journal
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    • v.16 no.4
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    • pp.303-312
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    • 2006
  • The asymmetric hybrid membranes of polyethersulfone (PES) and $ZrO_2$ nanoparticles were prepared via new one-step procedure combining simultaneously the phase-inversion method and the sol-gel technique. The optimum contents of $Zr(PrO)_4\;and\;HNO_3$ catalyst were determined by the adsorption experiments of phosphate anion onto the resulting hybrid membranes. The maximum adsorption of phosphate anion is obtained at the conditions of 0.15 mL $Zr(PrO)_4$ addition per 1 mL PES and 30 mL $HNO_3$ addition per 1 mL $Zr(PrO)_4$. Variation of morphology, performance and incorporated $ZrO_2$ amount of the resulting hybrid membranes were discussed and determined using SEM, pure water flux, TGA, ICP, XRD and contact angle measurements. Increasing $Zr(PrO)_4$ addition into casting solution, pure water flux is increased and $ZrO_2$ amount in the hybrid membrane is maximized at the conditions 0.15 mL $Zr(PrO)_4$ addition per 1 mL PES. The prephosphatation of PES-$ZrO_2$ hybrid membrane was studied to modify the surface characteristics of membrane. Ultrafiltration of bovine serum albumin (BSA) solution was performed in a dead-end cell using both a bare (non-phosphated) and a phosphated hybrid membrane. It is revealed that both the permeate flux and BSA rejection were increased as about 40% by prephosphatation of hybrid membrane. These results may be explained on the basis of the increase of membrane hydrophilicity, which was determined from contact angle measurements.

A Study on the Unit System of Hybrid System Using the Membrane and Tensegrity (막과 텐세그러티를 이용한 하이브리드 구조물의 단위 구조 제안)

  • Sur, Sam-Yeol;Ko, Kwang-Ung
    • Journal of Korean Association for Spatial Structures
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    • v.5 no.2 s.16
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    • pp.81-87
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    • 2005
  • The Space structures may have large freedom in scale and form. And especially Hybrid structures are received much attention from the view points of their light weight and aesthetics. Hybrid systems are stable structures which are reticulated spatial structures composed of compressive straight members, struts and cables and Membranes. In this paper, The Hybrid Unit System are suggested using the Membrane and Cable elements based on the Tensegrity Unit system. Also, The Hybrid System of double-layered single curvature is presented. We analyze the force density method allowing form-finding for Tensegrity systems. And We analyze the shape analysis by the LARSH which is the program for nonlinear analysis.

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Effects of EPS on membrane fouling in a hybrid membrane bioreactor for municipal wastewater treatment

  • Zhang, Aining;Liu, Zhe;Chen, Yiping;Kuschk, Peter;Liu, Yongjun
    • Membrane and Water Treatment
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    • v.5 no.1
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    • pp.1-14
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    • 2014
  • A pilot-scale hybrid membrane bioreactor (HMBR) for real municipal wastewater treatment was developed by adding biofilm carriers into a conventional membrane bioreactor, distribution and dynamic changes of the extracellular polymeric substances (EPS) and their roles in membrane fouling were investigated. The results showed that the concentrations of loosely bond EPS (LB-EPS) and tightly bond EPS (TB-EPS) in activated sludge, carrier biofilm and sludge cake layer have been increased significantly with the running time of HMBR, during operation of the HMBR, EPS demonstrated positive correlations with membrane fouling. Compared to TB-EPS, LB-EPS showed more significant correlations with sludge physical properties and specific resistance to filtration (SRF) in HMBR, and thus demonstrated that LP-EPS have a stronger potential of fouling than TB-EPS. It was also found that a lower organic loading in HMBR could result a significant increase in EPS concentration, which would in turn influence membrane fouling in HMBR. This critical investigation would contribute towards a better understanding of the behavior, composition and fouling potential of EPS in HMBR operation.

Gas permeation property of organic-inorganic hybrid membrane made by ion-beam irradiation

  • Kawakami, Hiroyoshi
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.90-93
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    • 2004
  • In this study, we have reported an organic-inorganic hybrid membrane, which exhibits an asymmetric structure consisted of a carbonized skin layer and a polyimide porous substructure, to synthesize a novel gas separation membrane combining high gas permeability and selectivity. Both the gas permeability and selectivity of the carbonized layer significantly enhanced when compared with those determined in the control polyimide.

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Synthesis and Characterization of Sulfonated Poly(phthalazinone ether sulfone)(sPPES)/Silica Membrane for Proton Exchange Membrane Materials

  • Kim, Dae Sik;Park, Ho Bum;Nam, Sang Young;Rhim, Ji Won;Lee, Young Moo
    • Korean Membrane Journal
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    • v.6 no.1
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    • pp.44-54
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    • 2004
  • Organic-inorganic composite membranes based on sulfonated poly(phthalazinone ether sulfone) (sPPES)/silica hybrid were prepared using the sol-gel process under acidic conditions. The sulfonation of PPES with concentrated sulfuric acid as sulfonation agent was carried out to prepare proton exchange membrane material. The behaviors of the proton conductivity and methanol permeability are depended on the sulfonation time (5-100 hr). The hybrid membranes composed of highly sulfonated PPES (IEC value: 1.42 meq./g) and silica were fabricated from different silica content (5-20 wt%) in order to achieve desirable proton conductivity and methanol permeability demanded for fuel cell applications. The silica particles within membranes were used for the purpose of blocking excessive methanol cross-over and for forming the path way to transport of the proton due to absorbing water molecules with ≡SiOH on silica. The presence of silica particles in the organic polymer matrix results in hybrid membranes with reduced methanol permeability and improved proton conductivity.