• The Transactions of The Korean Institute of Electrical Engineers
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• v.66 no.2
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• pp.357-362
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• 2017

Among the lithium metal oxides for asymmetric hybrid supercapacitor, $Li_4Ti_5O_{12}(LTO)$ is an emerging electrode material as zero-stain material in volume change during the with the charging and discharging processes. The pulverized LTO powder was observed to show the enhanced capacity from 120 mAh/g to 156 mAh/g at C-rate (10, 100 C). Hybrid supercapacitor module(48V, 416F) was fabricated using an asymmetric hybrid capacitor with a capacitance of 7500F. As a result of the measurement of C-rate characteristics, the module shows that the discharge time is drastically reduced at more than 50C, and the ESR and voltage drop characteristics are increased. The energy density and power density were reduced under high C-rate conditions. When designing asymmetric hybrid supercapacitor module, the C-rate and ESR should be considered As a result of measuring the 5 kw UPS, it was discharged at the current of 116A~170A during the discharge in the voltage range of 48V~30V, and the compensation time at discharge was measured to be about 33.2s. Experimental results show that it can be applied to applications related to stabilization of power quality by applying hybrid supercapacitor module.

• Journal of Electrical Engineering and Technology
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• v.13 no.1
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• pp.413-417
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• 2018

The $Li_4Ti_5O_{12}$ of anode material for the hybrid capacitor was coated using $CePO_4$, $M_3(PO_4)_2$ (M=Mg, Zn). The capacitance of phosphate coated $Li_4Ti_5O_{12}$ was found to be lower than that of $Li_4Ti_5O_{12}$, whereas the equivalent series resistance was higher than that of $Li_4Ti_5O_{12}$. With an increase in cycle number, the base of cylindrical cell exhibited swelling due to gas generated from the reaction between $Li_4Ti_5O_{12}$ and electrolyte. The swelling cycle number of phosphate coated $Li_4Ti_5O_{12}$ was higher than that of $Li_4Ti_5O_{12}$ due to improvement in electrochemical stability. Based on the results, it is proposed that phosphate coating can be employed as a barrier layer to control the gassing reaction by isolating the $Li_4Ti_5O_{12}$ particle from electrolyte solution.

• Journal of Electrochemical Science and Technology
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• v.4 no.1
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• pp.19-26
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• 2013

Graphene/Ni-Al layered double hydroxide (LDH) hybrid materials were synthesized by a hydrothermal reaction. Hexagonal Ni-Al LDH particles nucleated and grew on graphene sheets, thus preventing restacking of the graphene sheets and aggregation of the Ni-Al LDH nanoparticles upon drying. Electrode made from the graphene/Ni-Al LDH hybrid materials showed a substantial improvement in electrochemical capacitance relative to those made with pure Ni-Al LDH nanoparticles. In addition, the graphene/Ni-Al LDH hybrid composite materials showed remarkable stability after 4000 cycles with over 100% capacitance retention. These materials are thus very promising for use in electrochemical capacitor electrodes.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.20 no.9
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• pp.1763-1770
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• 2016

This paper proposed hybrid converter to operate over a wide output load power. The switched-capacitor converter has a high efficiency at low load power and a low efficiency at high load power. On the contrary, the buck converter has a high efficiency at high load power and a low efficiency at low load power. The proposed hybrid converter has combination of the switched-capacitor converter and the buck converter. The switched-capacitor operates at low load power and buck converter operates at high load power, so that the hybrid converter is improved power efficiency at wide output load power. The hybrid converter was implemented with a $0.18{\mu}m$ CMOS process. The hybrid converter has a range of the load power between $50{\mu}W$and 100mW. The maximum power efficiencies are 93% and 77% at the buck converter and the switched-capacitor converter, respectively.

• Korean Chemical Engineering Research
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• v.51 no.3
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• pp.308-312
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• 2013

Active carbons with high specific surface area and micro pore structure were prepared from the coconut shell char using the chemical activation method of NaOH. The preparation process has been optimized through the analysis of experimental variables such as activating chemical agents to char ratio and the flow rate of gas during carbonization. The active carbons with the surface area (2,481 $m^2/g$) and mean pore size (2.32 nm) were obtained by chemical activation with NaOH. The electrochemical performances of hybrid capacitor were investigated using $LiMn_2O_4$, $LiCoO_2$ as the positive electrode and prepared active carbon as the negative electrode. The electrochemical behaviors of hybrid capacitor using organic electrolytes ($LiPF_6$, $TEABF_4$) were characterized by constant current charge/discharge, cyclic voltammetry, cycle and leakage tests. The hybrid capacitor using $LiMn_2O_4$/AC electrodes had better capacitance than other hybrid systems and was able to deliver a specific energy as high as 131 Wh/kg at a specific power of 1,448 W/kg.

• Journal of Electrical Engineering and Technology
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• v.6 no.6
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• pp.786-792
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• 2011

The present paper presents an optimal capacitor placement (OCP) algorithm for voltagestability enhancement. The OCP issue is represented using a mixed-integer problem and a highly nonlinear problem. The hybrid particle swarm optimization (HPSO) algorithm is proposed to solve the OCP problem. The HPSO algorithm combines the optimal power flow (OPF) with the primal-dual interior-point method (PDIPM) and ordinary PSO. It takes advantage of the global search ability of PSO and the very fast simulation running time of the OPF algorithm with PDIPM. In addition, OPF gives intelligence to PSO through the information provided by the dual variable of the OPF. Numerical results illustrate that the HPSO algorithm can improve the accuracy and reduce the simulation running time. Test results evaluated with the three-bus, New England 39-bus, and Korea Electric Power Corporation systems show the applicability of the proposed algorithm.

• Proceedings of the KIPE Conference
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• 2018.07a
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• pp.105-107
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• 2018

This paper presents a new hybrid multilevel converter topology, which consists of a combination of the series connected switched capacitor units with boost ability, and an H-bridge with T-type bidirectional switches. The proposed converter boosts the input voltage without any bulky inductors, and has the small number of components, which can make the size and cost of a power converter greatly reduced. The output filter size and harmonics are also reduced by the high quality multilevel output. In addition, there is no need for complicated methods to balance the capacitor voltage. Simulation and experimental results with a nine-level converter system are presented to validate the proposed topology and modulation method.

• Journal of the Korean Electrochemical Society
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• v.6 no.2
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• pp.153-157
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• 2003

A hybrid electrochemical capacitor having both characteristics of electric double layer capacitance and pseudo-capacitance was studied throughout cell tests. Asymmetric electrodes with $Ni(OH)_2/activated$ carbon based positive electrode and activated carbon based negative electrode were used in preparing test cells of $5\times5cm^2$. Cyclic voltammetry measurements and impedance measurements were conducted to understand electrochemical behavior of each electrode. To find an optimal mass ratio of negative to positive electrode, charge-discharge cycle tests were also performed.

• Journal of Power Electronics
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• v.17 no.1
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• pp.96-105
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• 2017

In this paper, a hybrid modular multilevel converter (MMC) topology with an improved nearest level modulation method is proposed for medium-voltage high-power applications. The arm of the proposed topology contains N series connected half-bridge submodules (HBSMs), one full-bridge submodule (FBSM) and an inductor. By exploiting the FBSM, half-level voltages are obtained in the arm voltages. Therefore, an output voltage with a 2N+1 level number can be generated. Moreover, the total level number of the inserted submodules (SMs) is a constant. Thus, there is no pulse voltage across the arm inductors, and the SM capacitor voltage is rated. With the proposed voltage balancing method, the capacitor voltage of the HBSM is twice the voltage of the FBSM, and each IGBT of the FBSM has a relatively low switching frequency and an equalized conduction loss. The capacitor voltage balancing methods of the two kinds of SMs are implemented independently. As a result, the switching frequency of the HBSM is not increased compared to the conventional MMC. In addition, according to a theoretical calculation of the total harmonic distortion of the electromotive force (EMF), the voltage quality with the presented method can be significantly enhanced when the SM number is relatively small. Simulation and experimental results obtained with a MMC-based inverter verify the validity of the developed method.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.06a
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• pp.18-18
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• 2009

본 논문은 X8R 온도 특성을 가지는 유전체 원료를 이용하여 고용량이면서 고압화가 가능한 적층 칩 캐패시터를 제작하였다. 대형 고압용 적층 칩 캐패시터를 위한 내부 전극 설계 및 외부 전극 형성 방법에 대한 연구도 함께 진행하였다. 적층 칩 캐패시터를 하이브리드 자동차 및 산업용 인버터의 DC-Link으로 사용하기 적합한 모듈을 제작하였으며 모듈 설계시 고유전율의 에폭시-세라믹 필름을 하였다. 본 모듈을 평가한 결과 기존 캐패시터 모듈에 비하여 2/3 크기의 소형화를 얻을 수 있었으며 ripple 전류 및 발열 특성이 매우 우수함을 확인하였다.