• Conservation Science in Museum
• /
• v.21
• /
• pp.29-40
• /
• 2019

An experimental study was conducted to test the applicability of natural hydraulic lime (NHL) as a reinforcing agent for the supporting layers of mural paintings in ancient tombs.Drawing upon preceding studies on mural paintings inancient tombs, samples of reinforcing agents for various conditions were prepared using NHL products, and pseudo-samples of the supporting layers of mural paintings were also produced. The samples were cured for 7, 28, and 84 days in a high-humidity condition similar to that of the mural-tomb environment. Physical properties such as dimensional stability and compressive strength were measured for each curing period.The results indicated that the NHL samples had a rapid curing speed and a low contraction ratio and are therefore suitable as reinforcing agents, whereas they showed a poor match in terms of strength compared to the supporting layer,and also low whiteness. The dimensional stability and compressive strength testsrevealedthat an NHL product mixed with a pseudo-sample of a supporting layer provided desirable conditions for reinforcing agent. The findings suggested that different conditions for curing time and strength should be considered for each supporting layer prior to applying NHL as a reinforcing agent for damaged mural paintings in ancient tombs.

• Composites Research
• /
• v.20 no.5
• /
• pp.64-69
• /
• 2007

Matrix dominant properties of composites are largely degraded under harmful environments such as temperature and humidity. Therefore we should consider the harmful environmental factors in the design of an UAV integral fuel tank subjected to high temperature and high humidity. The harmful environment experiment was performed for carbon/epoxy composites made of a unidirectional prepreg USN175B, and a plain woven fabric prepreg WSN3. The immersion experiment was performed under $90^{\circ}C$. The specimens were tested when the weight gam of specimen was saturated. The specimens were tested under $74^{\circ}C$ to obtain tensile and inplane shear properties. The results showed that the matrix dominant properties were extremely degraded by hygrothermal environment. To consider the variability of load, the anti-optimization method was applied. By using this method, the worst load case was found by comparing the load convex model and stability boundary. The stability boundary was obtained by analysis of the integral wing fuel tank of UAV using degraded properties. To do this, it was known that the worst load case of the integral wing fuel tank was the hovering mode load case.

• Journal of Pharmaceutical Investigation
• /
• v.27 no.4
• /
• pp.253-263
• /
• 1997

To investigate the interaction of omeprazole (OMP) and meglumine (MEG), a complex was prepared by freeze-drying method in ammoniacal aqueous medium at room temperature and subjected to IR, DSC, and 1H NMR analysis. In addition, the stability of the complex was tested by accelerated stability analysis, and the dissolution rate of both powder and enteric coated was determined pellet by paddle method. The results are as follows; i) IR, DSC, and $^{1}H$ NMR studies indicate the formation of inclusion complex between OMP and MEG probably by electrostatic forces as $[OMP]\;[MEGH]^+$ form in a stoichiometric ratio (1:1) of OMP : MEG. ii) The dissolution rate of enteric coated OMP-MEG complex pellet in simulated enteric fluid was 90.6% in 10 minutes, which may satisfy the requirement for the regulation of dissolution. iii) OMP-MEG complex were decomposed according to pseudo 1st order kinetics: while the decomposition of OMP showed a rate constant $(k_{25^{\circ}C})$ of $5.13{\times}10^{-4}{\cdot}\;day^{-1}$, a half-life$(t_{1/2})$ of 1,350 days, a shelf-life$(T_{90%})$ 205 days and an activation energy of 23.53 kcal/mole. OMP-MEG complex inhibited a rate $(k_{25})$ of $2.92{\times}10^{-4}{\cdot}\;day^{-1}$, a half-life$(t_{1/2})$ of 2,373 days, a shelf-life $(T_{90%})$ of 306 days and an activation energy of 20.18 kcal/mole. iv) OMP was stabilized markedly by the formation of OMP-MEG complex between OMP and MEG, and the humidity increased the stability of OMP-MEG complex by decreasing the decomposition rate$(k_{50^{\circ}C})$ from $1.27{\times}10^{-2}{\cdot}\;day^{-1}$ at 31% R.H. to $2.54{\times}10^{-2}{\cdot}\;day^{-1}$ at 90% R.H.

• Animal Bioscience
• /
• v.34 no.4
• /
• pp.701-713
• /
• 2021

Objective: The present work was undertaken to evaluate the effects of storage time, choline chloride, and high concentrations of Cu and Zn on the kinetic behavior of vitamin degradation during storage in two vitamin premixes and four vitamin-trace mineral (VTM) premixes. Methods: Two vitamin premixes (with or without 160,000 mg/kg of choline) were stored at 25℃ and 60% humidity. Besides, four VTM premixes were used to evaluate the effects of choline (0 vs 40,000 mg/kg) and trace minerals (low CuSO4+ZnO vs high CuSO4+ZnO) on vitamin stability in VTM premixes stored in room, and the VTM premixes were stored in room temperature at 22℃. Subsamples from each vitamin and VTM premix were collected at 0, 1, 2, 3, 6, and 12 months. The retention of vitamin A (VA), vitamin D3 (VD3), vitamin E (VE), vitamin K3 (VK3), vitamin B1 (VB1), vitamin B2 (VB2), vitamin B3 (VB3), vitamin B5 (VB5), and vitamin B6 (VB6) in vitamin premixes and VTM premixes during storage was determined. The stability of vitamins in vitamin premixes and VTM premixes was determined and reported as the residual vitamin activity (% of initial) at each sampling point. Results: The effect of choline on VK3 retention was significant in vitamin premixes (p<0.05). The negative effect of storage time was significant for the retentions of VD3, VK3, VB1, VB2, VB5, and VB6 in vitamin premix (p<0.05). For VTM premixes, negative effect of storage time was significant (p<0.05) for the losses of vitamin in VTM premixes. Choline and high concentrations of Cu and Zn significantly increased VA, VK3, VB1, and VB2 loss during storage (p<0.05). The supplementation of high concentrations of Cu and Zn significantly decreased the concentrations of VD3 and VB6 (p<0.05) in VTM premixes at extended storage time. Conclusion: The maximum vitamin stability was detected in vitamin and VTM premixes containing no choline or excess Cu and Zn. The results indicated that extended storage time increased degradation of vitamin in vitamin or VTM premixes. These results may provide useful information for vitamin and VTM premixes to improve the knowledge of vitamin in terms of its stability.

• Journal of Korean Society for Atmospheric Environment
• /
• v.21 no.2
• /
• pp.191-204
• /
• 2005

Building and furnishing materials and consumer product are important sources of volatile organic compounds(VOCs) and other aldehydes in the indoor environment. Some available evidence indicates that VOCs can cause adverse health effects to the building occupants and contribute to some of the symptoms of what we call, 'Sick House Syndrome' in Korea. The aims of this study were to evaluate the efficiency of emission system and to investigate comparison of the emission characteristics of different building materials such as wall-papers, paints, and adhesives. The emission of VOCs from building materials were determined in the small chambers defining the temperature, relative humidity, and ventilation rate in this study. VOCs were sampled for 20 minutes using Tenax-TA tubes and analysed by GC-MS with thermal desorption. The stability of conditions for temperature and relative humidity in this small chamber system showed that the fluctuation of temperature was between 25.4$\pm$0.3$^{\circ}C$ and that of relative humidity was 50.2$\pm$0.6$\%$ under the airflow rate of 167 mL/min. The emission tests from building materials resulted in TVOC emission rates of 0.011 $\~$ 3.108 mg/m$^{2}$h after 7 days. The general wall-papers emitted toluene abundantly and the natural wall-papers mainly emitted n-butanol and a minor amount of alkanes compound such as n -tetradecane. The remainder consisted of toluene, m,p -xylene, and styrene. The paints mainly emitted toluene and the adhesives mainly emitted chloroform as well as toluene. As a result, this study is expected to suggest meaningful data for future studies in exposure control through selecting healthy building materials and for the establishment of guidelines for various building materials in Korea.

• Korean Journal of Food Science and Technology
• /
• v.17 no.2
• /
• pp.114-120
• /
• 1985

This study was carried out to investigate the storage stability of Yackwa (a Korean fried cake made from wheat flour, honey and 20% oil), with the variation in frying oils (soybean oil of fresh or heat-treated corn oil and rapeseed oil) and storage conditions (temperature, humidity and in dark or under fluorescent light) for 20 weeks period. In $5^{\circ}C$ storage, acid and peroxide values increased slowly, showing the peroxide value of 20 meq/kg after 13 weeks. In $40^{\circ}C$ storage, acid and peroxide values increased remarkably. The product became harder at storage humidity of 25% and softer by moistening at storage humidity of 80%. Acid and peroxide values of Yackwa from corn, rapeseed and soybean oils increased with storage period, to a different extent. The values of fluorescent groups, especially rapeseed oil group, were higher than those of control groups and the heat-treated oil groups were higher than those of fresh oil groups. Sensory scores for rancid flavor were gradually increased with the storage period in all groups. There was no significant difference with the kinds of frying oils, storage conditions and heat treatment. Correlation of sensory scores with acid values was positive throughout whole storage period, with low ${\gamma}-values$. Its correlation with peroxide values was positive up to 6th week but negative at 9th week of storage.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
• /
• v.37 no.1
• /
• pp.1-7
• /
• 2019

In this study, we estimated the tropospheric delay of GNSS (Global Navigation Satellite System) signals during passing through the atmosphere in relation to weather and seasonal factors. For this purpose, we chose four CORS (Continuously Operating Reference Station) stations from inland (CCHJ and PYCH) and on the coast (GEOM and CHJU). A total of 48 days for each station (one set of data for each week) were downloaded from the NGII (National Geographic Information Institute) and processed it using the scientific GNSS software. The average tropospheric delays in winter are less than 2,400 mm, which is about 200 mm less than those in summer. The estimated tropospheric delay shows a similar pattern from all stations except the absolute bias in magnitude, while a large delay was observed for the station located on the coast. In addition, the delay during the day was relatively stable in winter, and the average tropospheric delay was strongly related to the orthometric height. The inland stations have tropospheric delays by the precipitation rather than humidity due to dry weather and difference in temperature. On the contrary, it was primarily caused by the humidity on the sea. The correlation between temperature and water vapor pressure is 0.9 or larger for all stations, and the tropospheric delay showed a high linear relationship with temperature. It is necessary to analyze the GNSS data with higher temporal resolution (e.g. all RINEX data of the year) to improve the stability and reliability of the correlation results.

• Bulletin of the Korean Chemical Society
• /
• v.34 no.6
• /
• pp.1763-1770
• /
• 2013

A series of the block copolymers were successfully synthesized from post-sulfonated hydrophilic and hydrophobic macromers via three-step copolymerization. The degrees of sulfonation (DS) of the copolymers (10%, 30%, or 50%) were controlled by changing the molar ratio of the hydrophilic and hydrophobic parts. The resulting block copolymers were characterized by $^1H$ NMR and other technologies. The membranes were successfully cast using dimethyl sulfoxide (DMSO) solution at $100^{\circ}C$. The copolymers were characterized to confirm chemical structure by $^1H$ NMR and FT-IR. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) demonstrated that all sulfonated block copolymers exhibited good thermal stability with an initial weight loss at temperatures above $240^{\circ}C$. The membranes showed acceptable ion exchange capacity (IEC) and water uptake values in accordance with DS. The maximum proton conductivity was 184 mS $cm^{-1}$ in block copolymer-50 at $60^{\circ}C$ and 100% relative humidity, while the conductivity of Nifion-115 was 160 mS $cm^{-1}$ under the same measurement conditions. AFM images of the block copolymer membranes showed well separated the hydrophilic and hydrophobic domains. From the observed results it is that the prepared block membranes can be considered as suitable polymer electrolyte membranes for the application of polymer electrolyte membrane fuel cells (PEMFC).

• Journal of Korean Society for Atmospheric Environment
• /
• v.15 no.4
• /
• pp.417-428
• /
• 1999

The measurement of VOSCs(volatile organic sulfur compounds) in the air is nowadays a very important environmental research field. It is, however, very difficult because the concentration of the VOSC in ambient air is usually very low and the high reactivity makes it difficult to keep in container without loss of recovery. In this study, sampling method with cryogenic preconcentration is evaluated for analysis of atmospheric VOSC such as $CH_3SH,\;CH_3CH_2SH,\;CH_3SCH_3,\;CS_2,\;CH_3SSCH_3,\;CH_3SCH_2SCHA_3,\;and\;C_2H_5SSC_2H_5$ analyzed by GC-MS or GC-FID. Repeatabilities of measurement accompanied with preconcentration for 3-successive runs were in the range of 0.2~1.0% as a relative standard deviation. Stabilities up to 13 days were measured in 6 L canister and 10 L tedlar bag filled with VOSCs in ppb level. Higher stability was observed in tedlar bag as compared to canister with glass coated inner walls, and thiol compounds show dramatic losses in canister within 2~3 days. It is found that recovery over 70% was obtained in a week for all tested VOSCs when the compounds from ambient air matrix were stored in tedlar bag. It is also found that the stabilities of VOSCs are depending on humidity and coexisting compounds in matrix gas due to sample adsorption onto inner surface and reactivity. The results indicate the possibility and limitations of VOSC analysis in ambient air using container sampling method with cryogenic preconcentration.

• Fashion & Textile Research Journal
• /
• v.16 no.1
• /
• pp.145-152
• /
• 2014

The usage of textile-based sensors has increased due to their many advantages (compared to IT sensors) when applied to body assessment and comfort. Textile-based sensors have different detecting factors such as pressure, voltage, current and capacitance to investigate the characteristics. In this study, textile-based sensor fabrics with sheath-core type conductive yarns were produced and the relationship between capacitance changes and applied load was investigated. The physical and electric properties of textile-based sensor fabrics were also investigated under various laminating conditions. A textile based pressure sensor that uses a sheath-core conductive yarn to ensure the stability of the pressure sensor in the textile-based sensor (the physical structure of the reaction characteristic of the capacitance) is important for the stability of the initial value of the initial capacitance value outside the characteristic of the textile structural environment. In addition, a textile based sensor is displaced relative to the initial value of the capacitance change according to pressure changes in the capacitance value of the sensor due to the fineness of the high risk of noise generation. Changing the physical structure of the fabric through the sensor characteristic of the pressure sensor via the noise generating element of laminating (temperature, humidity, and static electricity) to cut off the voltage output element to improve the data reliability could be secured.