• Current Photovoltaic Research
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• 제10권2호
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• pp.49-55
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• 2022

With rapid growth in light-harvesting efficiency from 3.8 to 25.8%, organic-inorganic hybrid perovskite solar cells (PSCs) have attracted great attention as promising photovoltaic devices. However, despite of their outstanding performance, the commercialization of PSCs has been suffered from severe stability issues, especially for UV and humidity: (i) UV irradiation towards PSCs is able to lead UV-induced decomposition of perovskite films or catalytic reactions of charge-transporting layers, and (ii) exposure to surrounding humidity causes irreversible hydration of perovskite layers by the penetration of water molecules, resulting considerable decrease in their power-conversion efficiency (PCE). This review investigates current status of strategies to enhance UV and humidity stability of PSCs in terms of UV-management and moisture protection, respectively. Furthermore, the multifunctional approach to increase long-term stability as well as performance is discussed as advanced research directions for the commercialization of PSCs.

• YAKHAK HOEJI
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• 제28권6호
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• pp.299-303
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• 1984

In order to eluciate the effect of humidity and organic solvent on the decomposition of carbamide peroxide, the kinetic study was carried out. The carbamide peroxide was prepared from urea and 30%-hydrogen peroxide. The accelerated stability analysis for carbamide peroxide crystal in various relative humidity, and for 10%-carbamide peroxide solution of organic solvents were investigated. Both humidity and temperature were important factors influencing the decomposition rate of carbamide peroxide crystal. The higher the humidity and temperature, the greater was the reaction rate. The breakdown rate of crystal was observed as an apparent zero-order, and was faster than the rate of decomposition in dilute propylene glycol, glycerine or sorbitol solutioos which were measured as an apparent first-order reaction. The more dilute to 10% the organic solvents of 10%-carbamide peroxide, the slower was breakdown rate. It is, therefore, useful in the aspects of stability and economics to substitute solvent of carbamide peroxide topical solution (USP XXI) with 10%-propylene glycol or glycerine instead of anhydrous glycerine.

• Journal of Conservation Science
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• 제27권1호
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• pp.91-100
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• 2011

This study is to examine the PEG concentration, and drying humidity and drying periods of humidity-controlled drying(HCD) for conservation of waterlogged woods(Pinus densiflora S. et Z.), and dimension stability of HCD were compared with those of air-drying and vacuum freeze-drying(VFD). Dimension stability of vacuum freeze-drying was the most excellent, i.e., PEG crystal was uniformly distributed in woods. Increasing concentrations of PEG, dimension stability of HCD was increased and drying periods decreased. Dimension stability of HCD after the treatment with the high concentration(70%) of PEG soaking was similar to those of VFD after the treatment with the low concentration(40%) of PEG soaking. In conclusion, high concentration(about 70% in water) PEG solution was the most suitable as a pre-treatment for HCD of waterlogged woods. However, drying should be maintained with enough high humidity and longer period.

• Applied Chemistry for Engineering
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• 제10권3호
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• pp.461-466
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• 1999

The humidity sensor containing ammonium salt was prepared from the copolymer of 2-methacryloxyethyl dimethyl 2-hydroxyethyl ammonium bromide (MDHAB)/MMA/DAEMA = 6/3/1. The humid membrane was fabricated on the gold/alumina electrode by dipping. The impedances were $298k{\Omega},\;11k{\Omega}$, and $2.3k{\Omega}$ at 40%RH, 70%RH and 90%RH, respectively, at $5^{\circ}C$ and the humidity-sensitive characteristics were suitable for low temperature humidity sensor. The temperature-dependent coefficient between $5^{\circ}C$ and $20^{\circ}C$ was found to be $-0.80%RH/^{\circ}C$ and the hysteresis falled in the ${\pm}2%RH$ range. The response time was found to be 38 sec for the relative humidity ranging from 34%RH to 88%RH at $20^{\circ}C$. The reliabilities such as temperature cycle, humidity cycle, high temperature and humidity resistance, electrical load stability, stability of long-term storage and water durability were measured and evaluated for the application as a humidity sensor.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• 제7권1호
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• pp.21-31
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• 1997

Toluene, n-hexane, and methyl ethyl ketone(MEK) were exposed to the activated carbon fiber(ACF) and 3M(Model 3500) diffusive samplers under low and high humidity levels. In order to evaluate these two samplers, the sampling capacity, sampling rate, reverse diffusion, and storage stability were obtained. At low humidity level($8{\pm}3%RH$), the adsorption amount of all three organic vapors to the ACF diffusive sampler showed a positive linear relationship up to 8 hours. However, at high humidity level($90{\pm}5%RH$), n-hexane and MEK maintained a positive linear relationship up to 1.5 hrs, but decreased in their adsorption amounts afterwards. On the other hand, the adsorption amount of n-hexane, MEK, and toluene to 3M diffusive sampler showed almost a positive linear relationship up to 8 hours at both humidity levels. At low humidity level, there was almost no reverse diffusion for both 3M and ACF diffusive samplers. However, when the ACF diffusive sampler was used at high humidity level, there was about 52.63% of MEK sample loss and about 92.59% of n-hexane sample loss. The storage stabilities of the ACF and 3M diffusive samplers were both relative stable except for MEK. In the case of MEK, the difference between the analysis of the organic vapor right after the sampling and that of 3 weeks later at room temperature was 45% for the ACF diffusive sampler and 18% for the 3M diffusive sampler. Since the storage stability of the samples stored in a refrigerator was relatively stable, they need to be refrigerated until the analysis is done.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 한국전기전자재료학회 1996년도 추계학술대회 논문집
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• pp.421-424
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• 1996

Effects of humidity absorbing deterioration on AC dielectric breakdown characteristics of modified epoxy resin system with SN(succinonitrile) were investigated. As the forced humidity absorbing deterioration proceeded under high temperature and humidify, glass transition temperature increased. The dielectric breakdown strength increased and then decreased at deterioration cycles higher than 2. Not only, the increment of thermal stability but also, the physical detects such as Internal cracks and voids occurred during the humidity absorbing deterioration cycle were the main causes of the change in dielectric properties.

• Macromolecular Research
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• 제13권2호
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• pp.96-101
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• 2005

Thin-film humidity sensors were prepared using inorganic/organic hybrid polyelectrolytes, which were prepared from the sol-gel reaction of copolymers of [2-(methacryloyloxy)ethyl]dimethylpropylammonium bromide (MEPAB), n-butyl methacrylate (BMA), and 3-(trimethoxysilyl)propyl methacrylate (TSPM) with tetraethyl ortho-silicate (TEOS). The humidity-sensitive polyelectrolytes were composed of the copolymers having the following mole ratios of MEPAB, BMA, and TSPM: 60/30/10, 55/30/15, and 50/30/20. We found that the impedance varied with the content of MEPAB or TEOS; it ranged from $10^{7} to 10^{3}\Omega$ between 20 and $95\%$ relative humidity, which is the range required for a humidity sensor operating at ambient humidity. In addition we investigated a number of characteristics of these humidity sensors, such as their hysteresis, response time, temperature dependence, frequency dependence, water durability, and long-term stability.

• YAKHAK HOEJI
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• 제40권4호
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• pp.375-381
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• 1996

Five crystal modification of droperidol were prepared by recrystallization. They were characterized by UV spectrophotometer, DSC, and X-ray crystallography. Their dissolution pa tterns were also investigated. After storage of 2 months at 100% humidity, all polymorphic modifications were transformed.

• Applied Science and Convergence Technology
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• 제25권6호
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• pp.124-127
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• 2016

Humidity calibration for a temperature-stable quartz oscillator (TSQO) was investigated to exclude the influences of relative humidity on the TSQO output in order to use the corresponding devices outdoors. The TSQO output is a voltage that is inversely proportional to the electric impedance of the quartz oscillator, which depends on the viscosity and density of the measured gas. The TSQO output was humidity calibrated using its humidity dependence, which was obtained by varying the relative humidity (RH) from 0 to 100 RH% while other conditions were kept constant. The humidity dependencies of the TSQO output were fit by a linear function. Subtracting the change in the TSQO output induced by the change in humidity, calculated with the function from the experimentally measured TSQO output for a range of 0-100RH%, eliminated the influence of humidity on the TSQO output. The humidity calibration succeeded in reducing the fluctuations of the TSQO output from 0.4-3% to 0.1-0.3% of the average values for a range of 0-100RH%, at constant temperatures. The necessary stability of the TSQO output for application in hydrogen sensors was below one-third of the change observed for a hydrogen leakage of 1 vol.% hydrogen concentration, corresponding to 0.33% of the change in each background. Therefore, the results in this study indicate that the present humidity calibration effectively suppresses the influence of humidity, for the TSQO output for use as an outdoor hydrogen sensor.

• Journal of Sensor Science and Technology
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• 제12권6호
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• pp.241-248
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• 2003

An electrochemical humidity sensor was fabricated with poly(1,5-diaminonaphthalene) film coated on a gap of two splitted gold electrodes, which were made by vacuum deposition. Response currents according to humidity were measured by the potential sweep method and chronoamperometry. The stability of the polymer film was improved by double step chronoamperometry using the applied voltage of ${\pm}0.5$ Vdc. The response time determined by the pulse technique was about ${\sim}50$ msec and the relative standard deviation of current response was within ${\pm}5.0%$. The response current of the film was intrinsically humidity dependent. The film exhibited a non-linear but reproducible response in ordinary range of relative humidity. The linear equations were $I(nA)=0.28{\times}%RH-1.01$ between 10 to 70 %RH and $I(nA)=6.05{\times}%RH-403.21$ between 70 to 90 %RH.