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The Effect of La2O3 Loading on the Performance of Ni-La2O3-Ce0.8Zr0.2O2 Catalysts for Steam Reforming of Methane (수증기 개질 반응에서 Ni-La2O3-Ce0.8Zr0.2O2 촉매의 La2O3 함량이 촉매의 성능에 미치는 영향)

  • YOO, SEONG-YEUN;KIM, HAK-MIN;KIM, BEOM-JUN;JANG, WON-JUN;ROH, HYUN-SEOG
    • Journal of Hydrogen and New Energy
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    • v.29 no.5
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    • pp.419-426
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    • 2018
  • $Ni-La_2O_3-Ce_{0.8}Zr_{0.2}O_2$ catalysts with various $La_2O_3$ loading were investigated for hydrogen production from steam reforming of methane (SRM). The $La_2O_3$ loading influenced the physicochemical properties of $Ni-La_2O_3-Ce_{0.8}Zr_{0.2}O_2$ catalysts such as BET surface area, Ni dispersion, Ni size and reducibility. Among the prepared catalysts, $Ni-70La_2O_3-Ce_{0.8}Zr_{0.2}O_2$ catalyst showed the highest activity and stability at a very high gas hourly space velocity (GHSV) of $932,556h^{-1}$. This is mainly due to high Ni dispersion, small Ni size and high reducibility.

A Study on Maritime Traffic Characteristics according to Water Time(Multte) (물때에 따른 해상교통특성에 관한 연구)

  • Yoo, Sang-Lok;Jeong, Cho-Young;Jeong, Jae-Yong
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.21 no.5
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    • pp.501-506
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    • 2015
  • This study seeks to analyze ships traffic characteristics according to water time in order to provide the necessary data for efficient traffic management development. To analyze maritime traffic volume according to water time, 1 year amount of solar calendar data were converted into lunar calendar, and then applied the traditional water time system of West Sea by using AIS(Automatic Identification System) observation data gathered in Mokpo port for a year of 2013. As a result, it was found herein that the number of outbound ships was larger on the $2^{nd}-3^{nd}$ water times than the $7^{th}$ water times by 23-24 %. And the number of inbound ships was higher on the $12^{th}-13^{th}$ water times than the $9^{th}$ water time by 29-33 %. The hourly variation index of inbound and outbound ships according to time, in particular, was found to change in the form of sine function model. This study is expected to serve as a necessary basic material for development of maritime traffic management according to water time.

A Study on Seasonal Variation in Marine Traffic Congestion on Major Port and Coastal Routes (주요 항만 및 연안항로의 계절별 해상교통혼잡도 변화에 관한 연구)

  • Kang, Won-Sik;Song, Tae-Han;Kim, Young-Du;Park, Young-Soo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.23 no.1
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    • pp.1-8
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    • 2017
  • In this study, a congestion assessment was conducted to verify seasonal differences in congestion for major coastal traffic routes and fairways in major ports with GICOMS Data for 7 days without issuing a special weather report. As a result, a maximum of 11 % and 82 % are shown, with an average of 3.5 % and a 30 % seasonal difference for hourly average congestion and peak time congestion. Therefore, seasonal differences for the target area should be taken into consideration to perform further congestion assessments, particularly for maritime traffic safety assessments, and keen attention should be given to setting up safety measures against congestion.

A Study on the Wind Data Analysis and Wind Speed Forecasting in Jeju Area (제주지역 바람자료 분석 및 풍속 예측에 관한 연구)

  • Park, Yun-Ho;Kim, Kyung-Bo;Her, Soo-Young;Lee, Young-Mi;Huh, Jong-Chul
    • Journal of the Korean Solar Energy Society
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    • v.30 no.6
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    • pp.66-72
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    • 2010
  • In this study, we analyzed the characteristics of wind speed and wind direction at different locations in Jeju area using past 10 years observed data and used them in our wind power forecasting model. Generally the strongest hourly wind speeds were observed during daytime(13KST~15KST) whilst the strongest monthly wind speeds were measured during January and February. The analysis with regards to the available wind speeds for power generation gave percentages of 83%, 67%, 65% and 59% of wind speeds over 4m/s for the locations Gosan, Sungsan, Jeju site and Seogwipo site, respectively. Consequently the most favorable periods for power generation in Jeju area are in the winter season and generally during daytime. The predicted wind speed from the forecast model was in average lower(0.7m/s) than the observed wind speed and the correlation coefficient was decreasing with longer prediction times(0.84 for 1h, 0.77 for 12h, 0.72 for 24h and 0.67 for 48h). For the 12hour prediction horizon prediction errors were about 22~23%, increased gradually up to 25~29% for 48 hours predictions.

Assessment of Daily Steps, Activity Coefficient and Daily Energy Expenditures of Dieticians in Youngdong-area (영동지역 영양사의 1일 보행수, 활동계수 및 에너지 소비량 평가)

  • Lee, Jeong-Suk;Lee, Ga-Hui;Kim, Eun-Gyeong
    • Journal of the Korean Dietetic Association
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    • v.12 no.3
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    • pp.277-288
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    • 2006
  • The purpose of this study was to assess the energy expenditure and investigate the relationship between related variables of 57 dieticians in Youngdong-area. The average daily number of steps was found to be 9358.0$\pm$2714.3 steps/day on weekdays and 7862.9$\pm$2504.9 steps/day during weekends. Hourly step rates on weekdays and weekends came to 570.6$\pm$249.8 steps/hr and 564.0$\pm$224.8 steps/hr, respectively. Activity coefficient of subjects was higher on weekdays (1.56) than weekends (1.51, p<0.05). Resting energy expenditure estimated by the Harris-Benedict formula, WHO/NAO/FAO formula as well as formulas based on body surface area and DRIs (Dietary Reference Intake for Koreans) were calculated to be 1333.7$\pm$89.5kcal/day, 1351.0$\pm$123.3kcal/day, 1388.5$\pm$100.3kcal/day and 1295.9$\pm$90.8kcal/day, respectively. Using these resting energy expenditures and the activity coefficients, daily energy expenditures were calculated to be from 2039.7kcal/day to 2183.5kcal/day on weekdays and from 2016.1kcal/day to 2159.2kcal/day on weekends. Meanwhile energy intakes of subjects on weekdays and weekends were 1594.7$\pm$698.3kcal and 2152.9$\pm$768.0kcal, respectively. The activity coefficient (1.49) of dieticians who managed less than 500 meals per day was significantly lower than that of dieticians who served more than 500 meals per day. Dieticians of schools located in rural areas had higher activity coefficient (1.59) than those of schools located in urban or island settings. These results suggest that work analysis and development of management strategies are necessary to improve dieticians' productivity.

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Effect of artificial shrinkage on clinical outcome in fresh blastocyst transfer cycles

  • Hur, Yong-Soo;Park, Jeong-Hyun;Ryu, Eun-Kyung;Yoon, Hae-Jin;Yoon, San-Hyun;Hur, Chang-Young;Lee, Won-Don;Lim, Jin-Ho
    • Clinical and Experimental Reproductive Medicine
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    • v.38 no.2
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    • pp.87-92
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    • 2011
  • Objective: This study aimed to determine the safety and clinical effect of artificial shrinkage (AS) in terms of assisted hatching of fresh blastocysts. Also, we evaluated the correlation between patient age and the effect of AS on clinical outcome. Methods: Two AS methods, using a 29-gauge needle and laser pulse, were compared. Seventy-three blastocysts were shrunk using a 29-gauge needle and the same number of other blastocysts were shrunk by a laser pulse. We evaluated the shrunken blastocysts hourly and considered them viable if they re-expanded >70%. Blastocyst transfer cycles (n=134) were divided into two groups: a control group consisted of the cycles whose intact embryos were transferred (n=100), while the AS group consisted of the cycles whose embryos were replaced following AS (n=34). The implantation and pregnancy rates of the control group and AS group were compared ($p$ <0.05). Results: The re-expansion rates of the 29-gauge needle and laser pulse AS groups were similar (56 [76.7%] vs. 62 [84.9%], respectively). All of the remaining shrunken blastocysts were re-expanded within 2 hours. There was no degeneration of shrunken blastocysts. The total and clinical pregnancy rate of the AS group (23 [67.6%]; 20 [58.8%], respectively) was significantly higher than that of the control group (47 [47.0%]; 39 [39.0%], respectively). In the older patient group, there was no difference in the clinical outcomes between the AS and control groups. Conclusion: These results suggest that AS of blastocoele cavity, followed by the transfer, would be a useful approach to improve the clinical outcome in cycles in which fresh blastocyst stage embryos are transferred.

Analysis on the estimation errors of the lowest and highest astronomical tides for the southwestern 2.5 GW offshore wind farm, Korea

  • Ko, Dong Hui;Jeong, Shin Taek;Cho, Hong-Yeon;Kang, Keum-Seok
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.10 no.1
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    • pp.85-94
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    • 2018
  • For the design of wind-power facilities, the highest and lowest astronomical tides (HAT and LAT, respectively) are needed for the tidal-water levels regarding international designs; however, the approximate highest high water and approximate lowest low water AHHW and ALLW, respectively, have been used in Korea. The HAT and LAT in the wind-farm test-bed sea should be estimated to satisfy the international standard. In this study, the HAT and LAT are therefore estimated using the hourly tidal-elevation data of the Eocheongdo, Anmado, Younggwang, Gunsan, Janghang, and Seocheon tidal-gauging stations that are located in the adjacent coastal sea. The nodal variation patterns of the major lunar components, such as $M_2$, $O_1$, and $K_1$ are analyzed to check the expected long-term lunar cycle, i.e., 18.61 year's nodal-variation patterns. The temporal amplitude variations of the $M_2$, $O_1$, and $K_1$ clearly show the 18.61-years periodic patterns in the case of the no-nodal correction condition. In addition, the suggested HAT and LAT elevations, estimated as the upper and lower confidence limits of the yearly HAT and LAT elevations, are 50 cm greater than the AHHW and 40 cm lower than the ALLW, respectively.

Non-linear Regression Model Between Solar Irradiation and PV Power Generation by Using Gompertz Curve (Gompertz 곡선을 이용한 비선형 일사량-태양광 발전량 회귀 모델)

  • Kim, Boyoung;Alba, Vilanova Cortezon;Kim, Chang Ki;Kang, Yong-Heack;Yun, Chang-Yeol;Kim, Hyung-Goo
    • Journal of the Korean Solar Energy Society
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    • v.39 no.6
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    • pp.113-125
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    • 2019
  • With the opening of the small power brokerage business market in December 2018, the small power trading market has started in Korea. Operators must submit the day-ahead estimates of power output and receive incentives based on its accuracy. Therefore, the accuracy of power generation forecasts is directly affects profits of the operators. The forecasting process for power generation can be divided into two procedure. The first is to forecast solar irradiation and the second is to transform forecasted solar irradiation into power generation. There are two methods for transformation. One is to simulate with physical model, and another is to use regression model. In this study, we found the best-fit regression model by analyzing hourly data of PV output and solar irradiation data during three years for 242 PV plants in Korea. The best model was not a linear model, but a sigmoidal model and specifically a Gompertz model. The combined linear regression and Gompertz curve was proposed because a the curve has non-zero y-intercept. As the result, R2 and RMSE between observed data and the curve was significantly reduced.

An Ordinary Management System for Updating Construction Equipment Prices in the Poom-Saem Based on the Standard Market Price1 (시가표준액표를 활용한 건설공사표준품셈 건설기계가격 상시관리 시스템 개발)

  • Ahn, Bang-Ryul;Tae, Yong-Ho;Kim, Dae;Huh, Young-Ki
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.4
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    • pp.397-404
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    • 2015
  • Construction equipment cost is critical to estimate the total construction costs, particularly in large and complicated projects. Public construction projects are typically estimated using the Poom-Saem which includes hourly rates for workers and equipments. Despite its importance, the construction equipment cost may not properly reflect the current market value because it is being updated every six years at most. To keep the data for construction equipment cost estimation up to date, it is highly recommended to use the standard market price that is reported each year by the Ministry of Security and Public Administration (MOSPA). However, there is still a wide gap to directly adopt the standard market price for updating the construction equipment prices. Therefore, this paper suggests an effective way to develop an ordinary management systems for updating construction equipment prices in the Poom-saem based on the standard market price.

Sequence Mining based Manufacturing Process using Decision Model in Cognitive Factory (스마트 공장에서 의사결정 모델을 이용한 순차 마이닝 기반 제조공정)

  • Kim, Joo-Chang;Jung, Hoill;Yoo, Hyun;Chung, Kyungyong
    • Journal of the Korea Convergence Society
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    • v.9 no.3
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    • pp.53-59
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    • 2018
  • In this paper, we propose a sequence mining based manufacturing process using a decision model in cognitive factory. The proposed model is a method to increase the production efficiency by applying the sequence mining decision model in a small scale production process. The data appearing in the production process is composed of the input variables. And the output variable is composed the production rate and the defect rate per hour. We use the GSP algorithm and the REPTree algorithm to generate rules and models using the variables with high significance level through t-test. As a result, the defect rate are improved by 0.38% and the average hourly production rate was increased by 1.89. This has a meaning results for improving the production efficiency through data mining analysis in the small scale production of the cognitive factory.