• Journal of Korea Foresty Energy
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• 제22권3호
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• pp.43-48
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• 2003

Black liquor staining for the development of natural color of bleached Hanji caused problems of discoloration and degradation. This study was carried out not only to complement these problems but also to develop natural dyeing method that was similar to the color of unbleached Hanji, through the dyeing of rice straw extractives. The dyeing properties of Hanji were influenced more by dyestuffs extraction method than extraction and dyeing time. Dyeing ability of hot water extractives was superior to cold-water extractives. Without the relation to the time of extraction and dyeing, the color of Hanji dyeing hot water extractives were similar to the control, and the color of Hanji dyed for 45 min with hot water extractives that extracted for 120 min, were almost same as the control. As natural dyestuffs, hot water extractives of rice straw showed that excellent dyeing ability for the development of various natural colors similar to unbleached Hanjis.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• 제43권1호
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• pp.83-91
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• 2011

Hemicelluloses are useful materials for papermaking and other biotechnological applications. To recover and further utilize the hemicelluloses, this study carried out the pre-extraction of the hemicelluloses from Korean mixed hardwoods chips using hot water and sodium hydroxide solution at various temperature and time conditions. Through the hot water pre-extraction, the wood components of 22% was extracted and the 35% of the hemicelluloses which were contained in the original wood chips were dissolved into the pre-extractives. The yield of the pre-extractives was more significantly influenced by the pre-extraction temperature than the time. The pre-extractives with the yield of 30% could be obtained by alkali pre-extraction and alkali concentration was the most important factor. It had lower hemicellulose content but high molecular weight, compared with the hot water pre-extractives.

• Journal of the Korean Wood Science and Technology
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• 제24권4호
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• pp.1-6
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• 1996

Extracts from bark have been studied with a view to producing water-proof wood adhesives. Lately many softwoods, such as radiata pine from New Zealand and larch from Siberia, Russia, have been imported and utilized, and their residual barks would be expecting as potential raw materials for something useful chemicals. The great effort toward utilization of bark extractives as a chemical feedstock has been made on a worldwide level. However few report has been done for the utilization of tree bark extractives in Korea. Hot-water extracts were prepared from barks of Japanese larch(Larix leptolepis). Siberian larch(Larix gmelinii) and Radiata pine(Pinus radiata). The effect of various factors, such as particle size, liquor ratio, extraction temperature, and reaction time, on the extractive yields was discussed. Particle sizes affected the hot-water extractives: the finer the particle size, the higher extractives and extract efficiency. Higher temperature and higher liquor ratio were more effective. Extractives from Japanese larch were relatively less than those from Siberian larch and Radiata pine barks. Formaldehyde precipitates was the highest in extractives of Radiata pine barks. It could be concluded that Siberian larch bark was the best raw material for tannin adhesives, because its extractive yield was higher than those of the other barks.

• Journal of the Korean Wood Science and Technology
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• 제21권2호
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• pp.67-72
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• 1993

Hot water extractives of sawdust/particle from domestic and foreign wood species, which were composed of pitch pine, Korean pine, larch, Italy poplar, acacia and oak as Korean wood species, Malaysian oil palm and German spruce were quantitatively analyzed with thin layer chromatography. Sugar components of saccharose, galactose, glucose, fructose and arabinose were contained in these wood species. It was assumed that arabinose and glucose are major inhibitory components against cement hardening in larch and oil palm, respectively, since both species contain a large amount of each sugar. In contrast, fructose might not influence so badly on a cement hardening, when considering that fructose was contained much in Italy poplar with a good cement hardening character. Galactose was a minor component.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• 제48권3호
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• pp.57-65
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• 2016

Indigo (Polygonum tinctorium L.) is a typical blue dye which had been used from ancient times. This study was going to shade the complicated traditional methods extracting indigo dye by the fermentation and producing as adsorbate on calcium hydroxide, which says so called as the 'Indigo lime'. Accordingly we were going to make indigo through the hydrolysis of the hot water extractives of indigo leaves simply. During hot-water extraction, ${\beta}$-glucosidase which required hydrolysis of the linkage between indigo and glucose was not activated. To achieve this goal, indican was acid-hydrolyzed to glucose and indigo. The acetic acid, citric acid, hydrochloric acid, and sulfuric acid were used for the hydrolysis of hot water extractives. The hydrolysis conditions of extractives performed in water bath at $80^{\circ}C$ for 120 minutes and in an autoclave for 120 minutes. In the acid hydrolysis of extracted indican by hot water, the indican yields of acetic acid and hydrochloric acid hydrolysis were higher than sulfuric acid in water bath. Also, the indican yield of hydrochloric acid hydrolysis was better than sulfuric acid in autoclave. The hot water extracted indican was confirmed by HPLC analysis and its structure was confirmed by UV-Vis and FT-IR spectroscopy, compared with isolated indigo and commercial synthesized indigo. This improved extraction and hydrolysis methods can be replace the traditional indigo making method.

• Journal of the Korean Wood Science and Technology
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• 제30권3호
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• pp.109-115
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• 2002

Mycelial growth of L. edodes by pretreatments of softwood was studied on a sawdust medium. The sawdust used was from the following softwood species : Larix leptolepis, Pinus densiflora and Pinus koraiensis. The pretreatment consisted of cold-water (48 h), hot-water (3 h) and steam extractions (3 h) at a ratio of 500 g : 3,000 mL (sawdust : distilled water). The sawdust medium was a mixture of 76% sawdust, 20% rice bran, 3% glucose, 0.4% potassium nitrate and 0.6% calcium carbonate. Following sawdust pretreatments proved most suitable : L. leptolepis (steam extraction), P. densiflora (hot-water extraction) and P. koraiensis (hot-water extraction). Mycelial growth on P. koraiensis sawdust increased in proportion to an increase in hot-water extraction time. Mycelial growth was optimum on the sawdust extracted for 12 hours, hot-water extraction beyond this period proved unsuitable. With the exception of P. densiflora at 100 ㎍/mL, antifungal activity occurred in every sample. Maximum inhibition of mycelial growth was obtained from following concentration of hot-water extractives : P. densiflora (10⁴ ㎍/mL) and P. koraiensis (10⁴ ㎍/mL). This study has provided useful preliminary information for the cultivation of L. edodes.

• Journal of the Korean Wood Science and Technology
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• 제24권3호
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• pp.51-56
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• 1996

The Bark lignin(alkali- and acid lignin), bark extractives(hot water-and $Na_2SO_3$ extractives) of Quercus acutissima and Pinus densiflora, and flavonoids were used to detect heavy metal adsorption. The adsorption ratio of heavy metals by lignin was assigned for 40 to 50%, but was not dependent on lignin kinds. However, in case of the addition of light metals such as $Ca^{++}$ and $Mg^{++}$ to lignin the adsorption ratio was increased by 20 to 40%, and $Pb^{++}$ was almost completely adsorbed. On hot water extractives, the adsorption ratio was very low because the substrate was water-soluble, so the substrate should be water-insoluble to adsorb the heavy metals. However, the adsorption ratios of $Cd^{++}$ and $Pb^{++}$ on $Na_2SO_3$ extractives were significantly increased, while those of $Zn^{++}$ and $Cu^{++}$, were similar to lignin. When four kinds of heavy metals were treated to $Na_2SO_3$ extractives together, more than 97% of $Pb^{++}$ and $Cu^{++}$ was adsorbed_ and $Zn^{++}$ was more adsorbed by 40%, and $Cd^{++}$ was not changed, comparing with the case that on kind of heavy metal was treated. There were differences between adsorption ratio of the kinds of flavonoids and heavy metals, and the adsorption ratio of heavy metals was assigned to 20 to 45% per 0.1g flavonoid.

• Journal of the Korean Wood Science and Technology
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• 제20권2호
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• pp.73-80
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• 1992

The effect of presteaming on native oak specimens(Quercus serrata) of 2.5cm thick were investigated by measuring specific gravities, internal moisture gradients, residual extractives, and transport rates of free and bound water. The specific gravities and internal moisture gradients of the presteamed samples did not much deviate from those of the controls, but after presteaming discrepancy in moisture content between specimens lessened. The amount of residual hot-water extractives of the presteamed samples were less than those of the controls by 25%. The transport rates of bound water were determined by measuring steady-state diffusion coefficients with a vapormeter cup. After presteaming the diffusion coefficients in radial direction increased by 35%, but decreased those in the tangential direction.

• Journal of Korean Society of Forest Science
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• 제58권1호
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• pp.23-26
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• 1982

The chemical components in sap and heart wood of Q. variabilis and Q.serrate grown in Mt. Jiri were analyzed Q. variabilis ash contents were 0.57%, in sap wood portion and 1.00% in heart wood. Of the extractives cold water extractives were 5.74% in sap wood and 4.77% in heart wood. Hot water extractives were 6.33% in sap, 6.30% in heart wood portion. 1% caustic soda extractives were 15.52% in sap wood and 15.63% in heart wood. Alcohol-benzol extractives were 4.89% in sap wood and 2.96% in heart wood Holocellulose contents were 73.19% in sap wood, 78.83% in heart wood. Lignin contents were 21.76% in sap wood and 18.14% in heart wood portion. In pentosan contents there were 15.92% in sap wood and 26.50% in heart wood. In Q serrata ash contents were 0.26% in sap wood and 0.27% in heart wood. Cold water extractives were 2.81% in sap wood and 2.04% in heart wood. Hot water extractives were 5.32% in sap wood and 7.08% in heart wood portion. 1%-C austic soda extractives were 15.73% in sap wood and 16.55% in heart wood. Alcohol-benzol extractives were 3.93% in sap wood and 3.51% in heart wood. Holo celluloe contents were 74.21% and 74.84% in sap and heart wood portion respectively. Lignin contents were 14.11% in sap wood and 19.19% in heart wood. Of the pentosan contents there were 20.75% and 21.44% in sap and heart wood respectively. In conclution ash, holocellulose, lignin and pentosan contents showed always consistent differences between sap and heart wood in Q.variabilis, but in Q.serrata only lignin content showed slight difference between sap and heart wood.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• 제43권5호
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• pp.60-67
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• 2011

Hemicelluloses pre-extracted from Korean mixed wood chip were investigated as a wet-end additive. Hemicelluloses dissolved in hot water and alkali solution were isolated by ethyl alcohol precipitation from pre-extractives. They showed molecular weight of 9,000 ~ 27,000 g/mol as revealed by size exclusion chromatography. The reduction of molecular weight through hot water extraction was caused by autohydrolysis. Chemical composition of the hemicelluloses were analyzed with high-performance liquid chromatography and UV-Vis spectroscopy. As the surface charge of isolated hemicelluloses were negative, the adsorption of hemicelluloses onto softwood unbleached kraft pulp fiber was promoted by poly-DADMAC. The physical properties of handsheets increased as the molecular weight of hemicellulose increased. On the other hands, the optical property decreased with hemicellulose adsorption.