• 한국표면공학회지
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• 제49권1호
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• pp.26-31
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• 2016

In this paper, the characteristics of a cavitation-erosion damage behavior on the STS 304 and hot-dip aluminized STS 304 under cavitation environment in sea water solution was investigated. The electrochemical experiments were carried out by potential measurement, anodic/cathodic polarization test, Tafel analysis, and also galvanostatic experiment in current density variables for the samples. The apparatus of cavitation-electrochemical experiment was manufactured in compliance with modified ASTM G-32 standard, with the conditions of sea water temperature of $25^{\circ}C$ and the measurement, amplitude of $30{\mu}m$. The damage behavior was analyzed by an observation of surface mophologies and a measurement of damage depth by a scanning electron microscope(SEM) and a 3D microscope, respectively, after electrochemical test. After polarization experiment under cavitation environment, much higher damage depths for the hot-dip aluminized STS 304 were observed comparing to the untreated STS 304. In addition, higher corrosion current density in hot-dip aluminized STS 304 presented than that of untreated STS 304 as a result of Tafel analysis.

• Nuclear Engineering and Technology
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• 제29권2호
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• pp.175-180
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• 1997

It has been known that eater-side corrosion of fuel rods in nuclear reactor is accompanied with the metallic loss of wall thickness and hydrogen pickup in the fuel dadding tube. The fuel dad corrosion is one of the major factors to be controlled to maintain the fuel integrity during reactor operation. An oxide later thickness measuring device equipped with ECT probe system was developed by KAERI, and whose performance test was carried out in NDT(Non-destructive Test) hot-cell or PIE(Post Irradiation Examination) Facility. At first, the calibration/performance test was executed for the unirradiated standard specimen rod fabricated with several kinds of plastic thin films whose thickness ore predetermined, and the result of which showed a good precision within 10% of discrepancy. And then, hot test us peformed for the irradiated fuel rod selectively extracted from J44 fuel assembly discharged from Kori Unit-2. The data obtained with this device were compared with the metallographic result obtained from destructive examination in PIEF hot-cell on the same fuel rod to verify the validity of the measurement data.

• Corrosion Science and Technology
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• 제10권1호
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• pp.30-36
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• 2011

The effect of dynamic flow or forced convection were investigated and compared on the formation of inhibition layer, galvanizing and galvannealing reactions through the hot-dip galvanizing simulator with the oscillation of specimen in zinc bath, continuous galvanizing pilot plant with zinc pumping system through the snout and continuous galvanizing operation with Dynamic $Galvanizing^{TR}$ system. The interfacial Al pick-up was not consistent between the results of simulator, pilot plant and line operation, but the morphology of inhibition layer became compact and refined by the forced convection. The growth of Fe-Zn intermetallics at the interface was inhibited by the forced convection, whereas the galvannealing rate would be a little promoted.

• Corrosion Science and Technology
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• 제9권4호
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• pp.143-146
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• 2010

For the issue of flaking of the hot-dip galvanizing coating during drawing, the microcosmic characteristics of the coatings have been analyzed and experiments have been done to investigate the influence of coating thickness, Al content and steel substrate strength on its flaking-resistance. The results show that the fact of flaking is that the coating partially flaked off at the position far away from interface of steel substrate and coating, and not entirely flaked off from steel substrate because of poor adhesion. The flaking-resistance of coating decreases with the increasing of coating thickness and steel substrate strength, and increases with the increasing of Al content in coating at the same experimental conditions.

• 한국재료학회지
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• 제15권3호
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• pp.155-160
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• 2005

The electrolytic reduction of spent oxide fuel involves the liberation of oxygen in a molten LiCl electrolyte, which results in a chemically aggressive environment that is very corrosive fir typical structural materials. So, it is essential to choose the optimum material f3r the process equipment handling molten salt. In this study, the corrosion behavior of Al-Y coated Haynes 263 in a molten salt of $LiCl-Li_2O$ under oxidation atmosphere was investigated at $650^{\circ}C$ for $72\~168$ hours. The corrosion rate of Al-Y coated Haynes 263 was low while that of bare Haynes 263 was high in a molten salt of $LiCl-Li_2O$. Al-Y coated Haynes 263 improved the corrosion resistance better than bare Haynes 263 alloy. An Al oxide layer acts as a protective film which Prohibits Penetration of oxygen. Corrosion Products were formed $Li(Ni,Co)O_2$ and $LiTiO_2$ on bare Haynes 263, but $LiAlO_2,\;Li_5Fe_5O_8\;and\;LiTiO_2$ on Al-Y coated Haynes 263.

• 한국세라믹학회지
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• 제54권2호
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• pp.121-127
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• 2017

Gadolinium tetraboride ($GdB_4$) was synthesized by reduction of $Gd_2O_3$ using boron carbide in presence of carbon. Effect of temperature on product quality was investigated. Pure $GdB_4$ powder was obtained in vacuum at $1500^{\circ}C$. Pressureless sintering experiments revealed that sintering takes place only above $1600^{\circ}C$. A maximum density of 77.1% of the theoretical value was obtained at $1800^{\circ}C$ by pressureless sintering. Hot pressing resulted in 95.5% of theoretical density at the lower temperature of $1700^{\circ}C$ under 35 MPa pressure. Hardness and fracture toughness of dense $GdB_4$ were measured and found to be 21.4 GPa and $2.3MPa{\cdot}m^{1/2}$, respectively. After exposure to air at $900^{\circ}C$, the formation of a porous and non-protective oxide layer was observed.

• Nuclear Engineering and Technology
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• 제39권5호
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• pp.591-602
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• 2007

The results of Reactivity-Initiated Accidents (RIA) experiments have been analysed and the main variables affecting the fuel failure propensity identified. Fuel burn-up aggravates the mechanical loading of the cladding, while corrosion, or better the hydrogen absorbed in the cladding as a consequence of corrosion, may under some conditions make the cladding brittle and more susceptible to failure. Experiments point out that corrosion impairs the fuel resistance for RIA transient occurring at cold conditions, whereas there is no evidence of important embrittlement effects at hot conditions, unless the cladding was degraded by oxide spalling. A fuel failure threshold correlation has been derived and compared with experimental data relevant for BWR and PWR fuel. The correlation can be applied to both cold and hot RIA transients, account taken for the lower ductility at cold conditions and for the different initial enthalpy. It can also be used for non-zero power transients, provided that a term accounting for the start-up power is incorporated. The proposed threshold is easy to use and reproduces the results obtained in the CABRI and NSRR tests in a rather satisfactory manner. The behaviour of advanced PWR alloys and of MOX fuel is discussed in light of the correlation predictions. Finally, a probabilistic approach has been developed in order to account for the small scatter of the failure predictions. This approach completes the RIA failure assessment in that after determining a best estimate failure threshold, a failure probability is inferred based on the spreading of data around the calculated best estimate value.

• 한국재료학회지
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• 제14권4호
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• pp.251-259
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• 2004

In the development of the advanced spent fuel management process based on the molten salt technology, it is essential to choose the optimum material for the process equipment handling molten salt. Corrosion behavior of Ni 200 and Ni-base alloys in molten salt of LiCl-$Li_2$O under oxidation atmosphere was investigated in the temperature range of $650～800^{\circ}C$ for 24～312 hrs. The order of corrosion rate was Ni 200 > Inconel 690 > Inconel 601 > Inconel 600. Inconel 600 alloy showed the highest corrosion resistance among the examined alloys, but Ni 200 exhibited the highest corrosion rate. Corrosion products of Inconel 600 and Inconel 601 were $Cr_2$$O_3$ and $NiFe_2$$O_4$. In case of Inconel 690, a single layer of $CrO_2$$O_3$ was formed in the early stage of corrosion and an outer layer of $NiFe_2$O$_4$ and inner layer of $Cr_2$$O_3$ were formed with increase of corrosion time. Inconel 600 showed local corrosion behavior and Inconel 601, 690 showed uniform corrosion behavior.

• Corrosion Science and Technology
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• 제11권2호
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• pp.37-42
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• 2012

Recent issues in the automotive industries are, improvement of fuel efficiency according to the worldwide $CO_2$ regulation, passenger safety through enhanced crashworthiness, superior design and cost reduction due to price fluctuation of raw material. To meet these demands, steelmaking companies are developing advanced high strength steel and new process technologies such as hydroforming, TWB(Tailor Welded Blank), hot stamping and so on. In addition, eco-friendly and high corrosion resistant coating technologies are getting more attention to comply with the environmental regulations. In this paper, reviews and prospects of recent coating technologies for automotive use are presented.

• International Journal of Advanced Culture Technology
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• 제3권1호
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• pp.39-45
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• 2015

This research aims to study an effect of sodium chloride solution concentration on the corrosion rate of AA1100 aluminium alloy and SGACD zinc coated steel lap joint with a test duration of 30 days and a test temperature of $45^{\circ}$. The summarized results are as follows. Increase of the NaCl solution concentration increased the weight loss of Al, corrosion rate of Al, weight loss of Fe and also decreased the corrosion rate of Fe. Increase of the test duration affected to increase the weight loss and corrosion rate of Al and also decrease the weight loss and corrosion rate of Fe. The corrosion that was formed in a lap joint consisted of the uniform corrosion on the surface of the metals and the galvanic corrosion in the lap area of the joint. The maximum weight loss of AA 1100 aluminium and SGACD zinc coated steel that was occurred in the sodium chloride with 3.25% was 2.203% and 3.208%, respectively.. The maximum corrosion rate of AA 1100 aluminium and SGACD zinc coated steel that was occurred in 4.00% and 3.5% sodium chloride solution was 0.156 mm/year and 0.479 mm/year, respectively.