• Title/Summary/Keyword: Hot corrosion

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A Study on the Development of Al Alloy for the Vehicle Connecting Rod Using Hot Forging (열간단조공법을 이용한 컨로드용 Al 합금의 개발에 관한 연구)

  • Kim, S.H.;Hwang, T.M.
    • Journal of Power System Engineering
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    • v.12 no.1
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    • pp.66-71
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    • 2008
  • Alumium alloys hot forging process are gaining increased acceptance in the automotive and electronic industries and hot forging is one of the most efficient manufacturing method for mass product parts. It has been investigated the microstructures and mechanical properties of Al-11.7Si-0.5Mg (KNT40-T6)alloy fabricated by hot forging process for development of connecting rod in this study. The microstructure of hot forged specimen was composed of eutectic structure of alumimum solid solution and $Mg_2Si$ precipitates. The tensile strength of solutionized Al-11.7Si-0.5Mg alloy was 217MPa. This alloy showed a good corrosion resistance using electrochemical polarization test.

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Study of Hot Salt Stress Corrosion Crack Initiation of Alloy IMI 834 by using DC Potential Drop Method

  • Pustode, Mangesh D.;Dewangan, Bhupendra;Raja, V.S.;Paulose, Neeta;Babu, Narendra
    • Corrosion Science and Technology
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    • v.15 no.5
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    • pp.203-208
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    • 2016
  • DC potential drop technique was employed during the slow strain rate tests to study the hot salt stress corrosion crack (HSSCC) initiation at 300 and $400^{\circ}C$. Threshold stresses for HSSCC initiation were found to about 88 % of the yield strength at both temperatures, but the time from crack initiation to final failure (${\Delta}t_{scc}$) decreased significantly with temperature, which reflects larger tendency for brittle fracture and secondary cracking. The brittle fracture features consisted of transgranular cracking through the primary ${\alpha}$ grain and discontinuous faceted cracking through the transformed ${\beta}$ grains.

Hot Corrosion of Fe-Cr-Si and Fe-Cr-Pt alloys in Molten Salts. (Si, Pt이 첨가된 Fe-Cr 합금의 고온 용융염에서의 부식)

  • 박철우;최송천;이동복
    • Journal of the Korean institute of surface engineering
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    • v.27 no.1
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    • pp.3-11
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    • 1994
  • Cyclic hot corrosion studies have been carried out on(82~94) wt. % Fe-(5, 10, 15) wt. % Cr alloys con-taining either (1, 3)wt. % of Si or Pt as minor alloying elements in molten salts of($Na_2SO_4$+NaCl) between 820 and $920^{\circ}C$. Si or Pt decreased corrosion rate with the most pronounced effect being observed for alloys having 15wt. %Cr. Especially, as Si or Pt contents are increased from 1 to 3 wt. %, improved corrosion resistance was obtained. The beneficial effect of Si addition is due to the presence of the Si-rich second phase along the grain boundaries as well as the formation of the protective $SiO_2$layer between substrates and oxide scale. The Pt addition also increased the corrosion resistance by enhancing the formation ($Cr_2O_3$+layers and by increasing the adherence of the oxide scale.

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Corrosion of Fe-Cr Steels at 600-800℃ in NaCl Salts

  • Lee, Dong Bok;Kim, Min Jung;Yadav, Poonam;Xiao, Xiao
    • Journal of the Korean institute of surface engineering
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    • v.51 no.6
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    • pp.354-359
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    • 2018
  • NaCl-induced hot corrosion behavior of ASTM T22 (Fe-2.25Cr-1Mo), T91 (Fe-9Cr-1Mo), T92 (Fe-9Cr-1.8W-0.5Mo), 347HFG (Fe-18-Cr-11Ni), and 310H (Fe-25Cr-19Ni) steels was studied after spraying NaCl on the surface. During corrosion at $600-800^{\circ}C$ for 50-100 h, thick, non-adherent, fragile, somewhat porous oxide scales formed. All the alloys corroded fast with large weight gains owing to fast scaling and destruction of protective oxide scales. Corrosion rates increased progressively as the corrosion temperature and time increased. Corrosion resistance increased in the order of T22, T91, T92, 347HFG, and 310H, suggesting that the alloying elements of Cr, Ni, and W beneficially improved the corrosion resistance of steels. Basically, Fe oxidized to $Fe_2O_3$, and Cr oxidized to $Cr_2O_3$, some of which further reacted with FeO to form $FeCr_2O_4$ or with NiO to form $NiCr_2O_4$.

New Corrosion-Resistant Zn-Al-Mg Alloy Hot-Dip Galvanized Steel Sheet

  • Kohei Tokuda;Yasuto Goto;Mamoru Saito;Hiroshi Takebayashi;Takeshi Konishi;Yuto Fukuda;Fumiaki Nakamura;Koji Kawanishi;Kohei Ueda;Hidetoshi Shindo
    • Corrosion Science and Technology
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    • v.23 no.2
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    • pp.121-130
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    • 2024
  • In recent years, Zn-Al-Mg alloy galvanized steel sheets have been widely used as coated steel sheets to support social capital in the infrastructure field. A feature of Zn-Al-Mg alloy-coated steel sheets is that they provide a better corrosion protection period than Zn-coated steel sheets. In this study, the corrosion resistance of a new Zn-Al-Mg alloy-coated steel sheet was investigated and compared to that of conventional commercially available coated steel sheets. The investigation confirmed that increasing the Mg concentration in the Zn-Al-Mg-coated steel sheet improved corrosion resistance, which was more than 10 times that of the galvanized steel sheet specified in JIS G 3302. The study findings also confirmed that the corrosion resistance reached more than twice that of the coated steel sheet specified in JIS G 3323. If such galvanized steel sheets are applied to social infrastructures that are exposed to severely corrosive environments, the service life of the infrastructure might be extended.

Al-hot Dipping Followed by High-Temperature Corrosion of Carbon Steels in Air and Ar-0.2%SO2 Gas

  • Abro, Muhammad Ali;Jung, Seung Boo;Lee, Dong Bok
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.05a
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    • pp.128-129
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    • 2015
  • Al-rich coatings were prepared on hot rolled low carbon steel by hot dipping method in molten Al-bath to investigate the corrosion resistance with the possible outcomes and defects of aluminized coatings in air and $Ar-0.2%SO_2$ mixed gases. Coating microstructure was composed of an inner Al-Fe intermetallic layer and outer Al-rich layer. Aluminum oxidized preferentially to the thin, outer, protective ${\alpha}-Al_2O_3$ layer, without forming the nonprotective iron/sulfur-oxide layer after heating at $800^{\circ}C$ for 20 h, in both the gases and provided the resistance against corrosion.

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Al-hot Dipping Followed by High-Temperature Corrosion of Carbon Steels in Air and Ar-0.2%SO2 Gas

  • Kim, Min-Jeong;abro, Muhammad Ali;Park, Sang-Hwan;Ji, Gwon-Yong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.05a
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    • pp.122-122
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    • 2015
  • Al-rich coatings were prepared on hot rolled low carbon steel by hot dipping method in molten Al-bath to investigate the corrosion resistance with the possible outcomes and defects of aluminized coatings in air and $Ar-0.2%SO_2$ mixed gases. Coating microstructure was composed of an inner Al-Fe intermetallic layer and outer Al-rich layer. Aluminum oxidized preferentially to the thin, outer, protective ${\alpha}-Al_2O_3$ layer, without forming the nonprotective iron/sulfur-oxide layer after heating at $800^{\circ}C$ for 20h, in both the gases and provided the resistance against corrosion.

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Effects of Niobium Microalloying on Microstructure and Properties of Hot-Dip Galvanized Sheet

  • Mohrbacher, Hardy
    • Corrosion Science and Technology
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    • v.9 no.2
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    • pp.67-73
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    • 2010
  • Niobium microalloying is effective in hot-rolled and cold-rolled steels by providing a fine-grained microstructure resulting in increased strength. To optimize the strengthening effect, alloy design and hot-rolling conditions have to be adapted. As a key issue the dissolution and precipitation characteristics of Nb are discussed in particular with regard to the run-out table conditions. It is then considered how the hot-rolled microstructure and the solute state of Nb interact with the hot-dip galvanizing cycle. The adjusted conditions allow controlling the morphology and distribution of phases in the cold-rolled annealed material. Additional precipitation hardening can be achieved as well. The derived options can be readily applied to produce conventional HSLA and IF high strength steels as well as to modern multiphase steels. It will be explained how important application properties such as strength, elongation, bendability, weldability and delayed cracking resistance can be influenced in a controlled and favorable way. Examples of practical relevance and experience are given.

Atmospheric Corrosion of Rolling Stock Structures (철도차량 구조물의 대기부식 특성)

  • Chang Se-Ky;Kim Yong-Ki;Oh Chang-Rok;Goo Byeong-Choon
    • Proceedings of the KSR Conference
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    • 2004.10a
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    • pp.663-667
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    • 2004
  • Underframes of rolling stock structure are made of hot rolled steel of SS400 or SM490A. While these underframe steels are designed to satisfy the mechanical requirements, their corrosion behavior also should taken into account. Underframes are coated to prevent corrosion, but they are often defected by external factors to result in local corrosion which may cause the weakness of mechanical strength. Thus, the corrosion of underframe steels was examined through atmospheric corrosion test to estimate service life and safety.

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Thermal Shock and Hot Corrosion Resistance of Si3N4 Fabricated by Nitrided Pressureless Sintering (질화상압(NPS)법으로 제조한 질화규소의 열충격 저항성 및 내부식성 특성평가)

  • Kwak, Kil-Ho;Kim, Chul;Han, In-Sub;Lee, Kee-Sung
    • Journal of the Korean Ceramic Society
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    • v.46 no.5
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    • pp.478-483
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    • 2009
  • Thermal shock and hot corrosion resistance of silicon nitride ceramics are investigated in this study. Silicon nitrides are fabricated by nitride pressureless sintering (NPS) process, which process is the continuous process of nitridation reaction of Si metal combined with subsequent pressureless sintering. The results of thermal shock test show it sustains 400MPa of initial strength during test in the designated condition of ${\Delta}T=700{\sim}25^{\circ}C$ up to maximum 4,800 cycles. Hot corrosion tests also reveal that the strength degradation of NPS silicon nitride did not occur at $700^{\circ}C$ with an exposure in Ar, $H_2$, Na and K for 1,275 h.