• Title/Summary/Keyword: Holocellulose

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EVALUATIN OF NALITA WOOD(Trema orientalis) AS SOURCE OF FIBER FOR PARERMAKING

  • Jahan, M. Sarwar;Mun, Sung-Phil
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2003.11a
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    • pp.17-26
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    • 2003
  • Nalita wood(Trema orientalis) is one of the fastest growing woods in the world. It may be a viable species for pulpwood. The physical, chemical and morphological properties of Nalita were studied. The total lignin, pentosan and holocellulose content in Nalita wood were 24.7%, 22% and 81.2%, respectively. Its fiber length was about 0.92 mm, which are comparable to Acacia mangium. Nitrobenzene oxidation of Nalita wood meal indicated that the guaciayl and syringyl unit were the major constituent of Nalita lignin. Nalita produced 50% pulp yield at Kappa number 21 in soda-anthraquinone process. The strength properties of Nalita pulp were comparable to other tropical hardwood pulp. At $40_{\circ}$ SR, the breaking length, burst index, tear index and total energy absorption were 6000 m, $3.5kPa{\cdot}m^2/g\;and\;7.0mN{\cdot}m^2/g\;and\;75J/m^2$, respectively.

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Study of initial decomposition of the littera of platanus orientalis in stream ecosystem (溪流 生態系에 負荷된 버즘나무 落葉의 初期 分解)

  • Shim, Kue-Cheol;Lee, Sun-Kyung;Lee, Jung-Eun;Chang, Nam-Kee
    • The Korean Journal of Ecology
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    • v.15 no.4
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    • pp.387-394
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    • 1992
  • Decomposition in the litteras of platanus orientalis was studied by month in the dam of seoul national university. total amounts of the litter had the tendency to decrease with the laps of the time. Those of crude protein and phosphate contents, however, increased much more than initial amounts. It was throught that the growth of aquatic microbes gave rise to increase them. Dry weight, organic matter and holocellulose tended to decreased gradually. But, the amount of calcium loss increased rapidly since march and then the amoung of potassium and sodium decreased slowly. It was thought that this changing pattern was ascribed to water temperature, the growth of aquaqtic microbes and the leaching of soluble parts by stream current.

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New Korean Traditional Papermaking from Morus spp.(I)-Anatomical and Chemical Properties and Pulping Characteristics- (뽕나물 이용한 새로운 한지의 제조(제 1보)-해부학적 , 화학적 성밀 및 펄프화 특성-)

  • 최태호
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.3
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    • pp.96-104
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    • 1999
  • Anatomical and chemical properties of three mulberry species (Morus spp) were analyzed as an alternative row material for the paper mulberry (Broussonetia kazinoki) . The pulping and papermaing characteristics of bast fiber and whole stalks by three different pulping processes, conventional alkali, alkali-hydrogen peroxide, and sulfomethylated, for the Hanji were investigated. The fiber dimension of M.bombycis was the biggest of the species. The fiber length of upper part and the fiber width and cell wall thickness of lower part were bigger than the others. The extractives and ash contents of bast fiber were higher than those of whole stalk , and holocellulose and lignin contents of whole stalk were higher than those of bast fiber. The pulp yields of M.alba bast fiber, M.bombycis whole stalk, and sufomethylated pulping were higher than the others.

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Characterization of Nalita Wood (Trema orientalis) as a Source of Fiber for Papermaking (Part I): Anatomical, morphological and chemical properties

  • M. Sarwar Jahan;Mun, Sung-Phil
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.5
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    • pp.72-79
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    • 2003
  • Nalita wood (Trema orientalis), one of the fastest growing woods in the world, is characterized anatomical, morphological and chemical properties at annual growth ring level in order to investigate as papermaking raw material. The proportion of fibers and vessel was increased with an increase of growth ring (from pith to bark). The fiber length of Nalita was increased with increasing growth ring, and an average fiber length was about 817 um. The average basic density of Nalita was about 0.38 g/cc. The total lignin & holocellulose in Nalita were increased and ash & alcohol-benzene extract decreased from pith to bark. These values were about 23.5 - 24.4 %, 78.1 - 80.1 %, 1.04 - 0.92 % and 2.1 - 1.8 %, respectively. The xylan was the predominant sugar in the hemicellulose of Nalita.

Preliminary Study on Automation of Bark Peeling Process for Paper Mulberry (닥나무 흑피제거 자동화 공정 기초연구)

  • Kwon, Oh-Hun;Kim, Hyun-Chel
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.4
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    • pp.59-66
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    • 2011
  • This study was carried out to develop the automation bark peeling process of paper mulberry for making Hanji. Nowadays, almost raw material has been imported from south-east asia for making Hanji. Raw material dependence is very high for Hanji-making by low productivity in korea. This study is focused on the resolution for problem of bark peeling automation. Water and sand jet of compressed air was possible bark peeling for black bast fiber. The effect of removing black bast fiber increased the longer the steaming time. Also using drum of bark peeling showed that results under temperature $80^{\circ}C$ and Rpm 50/min were best bark peeling and separating bast fiber from stem. The contents of holocellulose, lignin, ethanol-benzene extractives, and ash were 91.63~95.55%, 1.4~2.0%, 1.12~1.65%, and 1.4~4.3%, respectively. Chemical characteristics are similar between imported raw-material with drum bark.

Effect of Enzymatic Hydrolysis of Cellulose Nanofibers on the Properties of Poly (Vinyl Alcohol) Nanocomposite

  • Han, Song-Yi;Park, Chan-Woo;Lee, Seung-Hwan
    • Journal of Forest and Environmental Science
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    • v.33 no.2
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    • pp.154-159
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    • 2017
  • Enzymatic treatment was conducted to hydrolyze pure cellulose nanofiber (PCNF), holocellulose nanofiber (HCNF), and lignocellulose nanofiber (LCNF) for 6, 24 and 72 hours and thus-obtained nanofibers (1, 3, 5, 10 wt%) were used to reinforce polyvinyl alcohol (PVA). Glucose production yield was increased by enzymatic hydrolysis. Tensile strength and elastic modulus of all PVA nanocomposite reinforced three nanofibers were improved by increasing enzymatic hydrolysis time of nanofibers and these values were higher in order of nanocomposite reinforced with PCNF>HCNF>LCNF. Furthermore, tensile properties of nanocomposite with PCNF were increased by nanofiber content. Thermal stability of PVA was improved by adding nanofibers and by increasing nanofiber content.

Analysis of secondary reactions in concentrated sulfuric acid hydrolysis of hollocellulose by 1H-NMR spectroscopy (1H-NMR 분광분석을 통한 진한 산 가수분해 반응 2차 반응 조건 분석)

  • Lee, Jai-Sung;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.3
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    • pp.37-43
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    • 2014
  • Kinetics of holocellulose hydrolysis in concentrated sulfuric acid was analyzed using $^1H$-NMR spectroscopy with different reaction time, temperature and acid concentration in secondary hydrolysis. In this work, reaction condition of secondary hydrolysis was similar to concentrated sulfuric acid process with electrodialysis or simulated moving bed chromatography process for sulfuric acid recycling. By $^1H$-NMR spectroscopy, acid hydrolyzates from higher secondary acid hydrolysis (25-35% acid concentration) was successfully analyzed without any difficulties in neutralization or adsorption of acid hydrolyzate to solid salt. Higher acid concentration, higher temperature and longer reaction time led to more cellulose for glucose conversion but accompanied with glucose to galactose isomerization, glucose to unknown compounds and degradation of glucose to organic acid via furans.

Studies on the Composition analysis of Oak Mushroom (Lentinula edodes) Cultural Waste (표고버섯 재배용 참나무 폐골목의 화학적 성분분석)

  • Lee, Min-Woo;Seo, Yung-Bum
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2008.04a
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    • pp.222-228
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    • 2008
  • The chemical composition and thermal, crystal characterization of oak mushroom waste were investigated in comparison with those normal oak wood for utilization of cellulose from oak mushroom waste. The oak mushroom waste contained a higher percentage of ash, and hot water extractives than oak wood. This results indicated that the materials inside the body are easily decomposed during the oak mushroom cultivation. The lower percentage of holocellulose and a-cellulose of oak mushroom waste caused by fungal decomposition too. Whereas, the thermal decomposition behavior and crystallinity of oak mushroom waste was similar to that of normal oak wood, which indicated that the cellulose characterization of oak mushroom waste is resistant to fungal decomposition. In additionally, a degree of polymerization of oak mushroom waste must be investigate for examination of cellulose crystalline characterization, especially.

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The Chemical Composition of Abies koreana Wilson Wood (구상나무(Abies koreana Wilson)재(材)의 화학적(化学的) 조성(組成))

  • Moon, Chang Kuck;Pack, Chong Yawl;Kang, Wee Pyung
    • Journal of Korean Society of Forest Science
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    • v.50 no.1
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    • pp.1-4
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    • 1980
  • The Chemical components of Abies koreana Wilson grown in Korea were analized. The results obtained were summarized as follows. 1. The ash content is ca 0.56% on the average, and of the range is 0.33 to 0.76%. 2. The cold water extractive content is ca 8.76% on the average and of the range is 5.55 to 12.5%. 3. The hot water extractive content is ca 10.16% on the average and of the range is 4.80 to 13.65%. 4. Basic extractive content is ca 14.60% on the average and of the range is 5.51 to 25.44%. 5. The alcohol benzol soluble fraction is ca 4. 23% and of the range is 2.94 to 5.44%. 6. The holocellulose content is ca 76.49% on the average and of the range is 73.68% to 79.10%. 7. The cellulose content is ca 56.30% on the average and of the range is 46.02% to 61. 33%. The cellulose contains 78.54% ${\alpha}$-cellulose, 7.66% ${\beta}$-cellulose and 14.04% ${\gamma}$-cellulose respectively. 8. The Klason lignin content is ca 25.03% on the average and of the range is 22.5 to 27.0%. In conclusion, ash content is comparable to the other needle leaf trees. It has 76.49% in holocellulose content which is comparable value to the Pinus densiflora's. It has lower value than the Pinus densiffora in pentosan and lignin content. Having not resin cannal in xylem and long tracheid, this wood could be usable industrial material.

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Characteristics of Fermented Wood Chips and Pig Manure (목질칩을 이용한 분뇨 발효 시 목질칩과 돈분뇨의 성분 변화)

  • Kim, Myung-Kil;Choi, Don-Ha;Choi, In-Gyu
    • Journal of Korea Foresty Energy
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    • v.24 no.2
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    • pp.1-9
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    • 2005
  • After manufacturing fermentation system for degrading pig manure using environmentally friendly technique, performance of the system and characteristics of wood chips and pig manure fermented in the system were analyzed. Results from this study shows that proper fermentation temperature($55{\sim}60^{\circ}C$) reached 3days after the system started and degradation rate, which expresses fermentation performance of system, was $180{\iota}$/day. Even as progressing the fermentation of wood chips and pig manure mixture, the amount of extractives drawn out by alkali, and alcohol-benzene and lignin content was not varied. However, ash content in wood was increased. The inorganic compounds in pig manure seem to be transferred into wood chip. On the other hand holocellulose contents in wood were decreased a little. Holocellulose seems to be consumed as the second carbon source in fermentation process. Results through analysis of inorganic- and heavy metal elements contents in wood chips and pig manure fermented in long term process shows that inorganic elements($Ca^{2+},\;Mg^{2+},\;K^+,\;Na^+$ etc.) contents were increased with fermentation time and heavy metal elements(Cd, As, Cu etc.) which cause environmental pollution were not detected. Number of microorganisms including bacteria, actinomycetes, and fungi, the number of C.F.U(Colony Forming Unit) was increased while temperature in fermentation system was abruptly increased.

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