• Membrane Journal
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• v.9 no.2
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• pp.89-96
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• 1999

국내 K-그룹 연구소에서 제조한 폴리설폰 중공사막의 산소/질소 혼합물에 대한 압력, stage , cut , 공급기체 혼합물의 조성에 따른 분리성능을 조사하였다. 본 실험의 압력범위와 온도 3$0^{\circ}C$에서의 이상분리인자 (O2/N2)는 5.7이었으며, 유입기체 혼합물의 21mole % 산소농도가 약 50 mole%로 농축되었다. 저압측과 고압측의 압력비는 산소농축에 미치는 영향이 적었으며 이상분리인자의 영향은 매우 컸다. 그러나, 이상분리인자가 증가함에 따라 이상분리인자의 영향은 둔화되었다. 따라서, 이상분리인자가 큰 신소재 개발과 더불어 공정변수의 최적화가 필요하다. 수학적 모델링에 의한 예측치와 실험치가 잘 맞았다.

• Proceedings of the Membrane Society of Korea Conference
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• 1999.04a
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• pp.113-114
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• 1999

• Proceedings of the Membrane Society of Korea Conference
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• 2003.07a
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• pp.119-122
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• 2003

No Abstract, See Full Text

• Proceedings of the Membrane Society of Korea Conference
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• 2005.11a
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• pp.174-177
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• 2005

• Proceedings of the Membrane Society of Korea Conference
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• 2005.11a
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• pp.291-294
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• 2005

• Proceedings of the Membrane Society of Korea Conference
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• 1998.10a
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• pp.91-92
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• 1998

1. 서론 : 고분자를 소재로 하는 중공사막의 제막은 일반적으로 상전환법(phase inversion method)에 의하여 제조된다. 이 방법에 의한 비대칭막의 생성은 용매가 고분자용액을 빠져나가는 속도와 응결액이 고분자쪽으로 침투되는 속도의 차이에 의해서 막의 1차구조가 형성된다. 그러므로 이 속도를 첨가제 등을 사용하여 조절하므로서 막의 특성을 변화시킬 수 있다. 본 연구에서는 polyetherimide(PEI) 중공사막의 첨가제로서 dioxane 등 9종류를 사용하여 중공사막의 생성 구조에 미치는 영향을 검토하였다.

• Proceedings of the Membrane Society of Korea Conference
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• 1998.10a
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• pp.93-95
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• 1998

1. 서론 : 폴리이미드계 고분자는 기계적 성질과 내열성이 우수한 고분자 소재이다. 일반적으로 기체분리막으로서의 유리상 고분자는 기체의 투과성은 결여되지만, 고분자쇄의 동결속박에 의한 자유부피에 따라 기체의 선택성이 높게 나타난다. 본 연구에서는 고분자로서 polyetherimide(PEI) 를 이용하여 제막조건(고분자 농도, air gap, 용매, 내부응고제 주입량 등)을 달리하는 중공사막을 제조하여, 제막변수에 따른 막의 구조 및 기체투과 특성을 검토하였다.

• Membrane Journal
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• v.15 no.3
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• pp.224-232
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• 2005

The use of the lung assist device (LAD) would be well suited for acute respiratory failure (ARF) patients, combining the simplicity of mechanical ventilation with the ability of extracoporeal membrane oxygenators (ECMO) to provide temporary relief for the natural lungs. This study's specific attention was focused on the effect of membrane vibration in the LAD. Quantitative experimental measurements were performed to evaluate the performance of the device, and to identify membrane vibration dependence on blood hemolysis. We tried to decide upon excited frequency band of limit hemolysis when blood hemolysis came to through a membrane vibration action. The excited frequency of the module type 5, consisted of 675 hollow fiber membranes, showed the maximum gas transfer rate. We concluded that the maximum oxygen transfer rate seemed to be caused by the occurrence of maximum amplitude and the transfer of vibration to hollow fiber membranes. It was excited up to $25{\pm}5$ Hz at each blood flow rate of module type 5. We found that this frequency became the 2nd mode resonance riequency of the flexible in blood flow. Blood hemolysis was low at the excited frequency of $25{\pm}5$ Hz. Therefore, we decided that limit hemolysis frequency of this LAD was $25{\pm}5$ Hz.

• Membrane Journal
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• v.10 no.2
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• pp.75-82
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• 2000

This study, which was tarried out to investigate the characteristics of permeation rates and fouling phenomena in drinking-water treating processes with MF membrane, showed that pressure drop was dependent on the length of membrane module and operating pressure; the pressure drop increased with the length of membrane module and operating pressure, operation at a relatively low pressure(0.5kg/$cm^2$) is better than that at a relatively (2.0kg/$cm^2$), since high operating pressure accelerates the clogging. In case of out-in permeation type, almost same flux was obtained after a certain operating time regardless of membrane length and operating pressure. In order to understand, the microbial fouling, chemical cleaning was carried out to the forced contaminated hollow-fiber membrane with chemicals($H_2O_2$, NaOCl, and NaOH). Chemical cleanings with $H_2O_2$and NaOCl, which are oxidizing agents, are better for sterilizing and desorbing the microbes than those with NaOH.

• Applied Chemistry for Engineering
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• v.9 no.7
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• pp.1036-1042
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• 1998

It was investigated that the extraction of Cr(VI) from aqueous solution into the organic TDA and the stripping(back extraction) of Cr(VI) from the Cr(VI)-TDA complex into NaOH aqueous solution by hydrophobic hollow fiber membrane. It was found that the mass transfer rates of stripping process were smaller than those of the extraction process. This result was expected that membrane resistance, neglected in the extraction process, acts on the stripping process when organic phase flow in the tube side of the hydrophobic membrane. Hollow fiber modules were made by potting the desired number(60, 100, 150, 300fibers). We also examined the effect of flow rates of aqueous and organic phase on the mass transfer rate in the membrane modules. From these experiments, we identified for the extraction process by using hydrophobic membrane, the effect of flow rate of aqueous phase on the mass transfer rate was significant, but that of organic phase was negligible one. In the stripping process, however, mass transfer rate depend neither flow rate of aqueous(stripping solution) phase nor that of organic(Cr-TDA complex) phase.