• Journal of the Korean Ceramic Society
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• v.54 no.3
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• pp.222-227
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• 2017

Flake-type micro hollow silica was synthesized by precipitation method using an $Mg(OH)_2$ inorganic template and sodium silicate and ammonium sulfate as the silica precursors. We investigated the effects of the silica precursor concentration on the shape, shell thickness, and surface of the hollow silica. When the concentration of the silica precursor was 0.5 M, the hollow silica had a smooth and translucent thin shell, but the shell was broken. On the other hand, the shell thickness of the hollow silica changed in the range of 12 nm to 18 nm with the increase of the precursor concentration from 0.7 M to 1.1 M. Simultaneously, unintended spherical silica satellites were created on the shell surface. The number of satellites and the size rose according to the increased concentration of silica precursor. The reason for the formation of spherical silica satellites is that the $NH_4OH$ nucleus generated in the synthesis of hollow silica acted as another silica reaction site.

• Structural Engineering and Mechanics
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• v.45 no.3
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• pp.355-371
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• 2013

Single- and multi-span orthotropic functionally graded hollow cylinders subjected to axisymmetrical bending are investigated on the basis of a unified shear deformable shell theory, in which the transverse displacement is expressed by means of a general shape function. To approach the through-thickness inhomogeneity of the hollow cylinder, a laminated model is employed. The shape function therefore shall be determined for each fictitious layer. To improve the computational efficiency, we resort to a transfer matrix method. Based on the principle of minimum potential energy, equilibrium equations are established, which are then solved analytically using the transfer matrix method for arbitrary boundary conditions. Numerical comparisons among a third-order shear deformable shell theory, an exact elastic theory and the present theory are provided for a simply supported hollow cylinder, from which the present theory turns out to be superior in stress estimation. Distributions of displacements and stresses in single- and three-span hollow cylinders with different boundary conditions are also illustrated in numerical examples.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.05a
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• pp.159-162
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• 2005

To overcome the drawbacks of conventional load-control method and displacement-control method, the so-called volume-control method was developed by utilizing a pressure node added into a layered shell element. The pressure node has an increment of pressure as an additional degree of freedom of the shell element. In this study, the hollow RC columns are discretized with multi-layered shell elements and a modeling technique utilizing the volume-control analysis for various hollow RC column structures is introduced. The results of the nonlinear analysis using the modeling for hollow RC columns subjected to lateral reversed cyclic loading as well as lateral loading under compression are shown. Validity of the modeling technique is also verified by comparing the analysis results with experimental results and other analysis data.

• Bulletin of the Korean Chemical Society
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• v.34 no.3
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• pp.986-988
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• 2013

• Bulletin of the Korean Chemical Society
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• v.35 no.11
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• pp.3303-3306
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• 2014

A facile and effective approach has been developed to prepare hybrid hollow microspheres, via consecutive processes of pickering mini-emulsion polymerization for core-shell formation, and calcination of the sacrificial core. The resulting hollow composite particles have mono-layered shells. The morphology and size characteristics of synthesized composite particles were investigated, using dynamic light scattering (DLS) and scanning electron microscopy (SEM) measurements.

• Journal of the Korean Ceramic Society
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• v.56 no.1
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• pp.98-103
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• 2019

Optical filters to control light wavelength of displays or cameras are fabricated by multi-layer stacking process of low and high index thin films. The process of multi-layer stacking of thin films has received much attention as an optimal process for effective manufacturing in the optical filter industry. However, multi-layer processing has disadvantages of complicated thin film process, and difficulty of precise control of film morphology and material selection, all of which are critical for transmittance and coloring effect on filters. In this study, the composite $TiO_2$, which can be used to control of UV absorption, coated on nano hollow silica sol, was synthesized as a coating material for optical filters. Furthermore, systematic analysis of the process parameters during the chemical reaction, and of the structural properties of the coating solutions was performed using SEM, TEM, XRD and photo spectrometry. From the structural analysis, we found that the 85 nm nano hollow silica with 2.5 nm $TiO_2$ shell formation was successfully synthesized at proper pH control and titanium butoxide content. Photo luminescence characteristics, excited by UV irradiation, show that stable absorption of 350 nm-light, correlated with a 3.54 eV band gap, existed for the $TiO_2$ shell-nano hollow silica reacted with 8.8 mole titanium butoxide solution. Transmittance observed on substrate of the $TiO_2$ shell-nano hollow silica showed effective absorption of 200-300 nm UV light without deterioration of visible light transparency.

• Journal of the Korean Applied Science and Technology
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• v.33 no.3
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• pp.421-427
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• 2016

Nanosized hollow silica was prepared by $St{\ddot{o}}ber$ method in the presence of aluminum isopropoxide. The mixture of polyelectrolytes such as poly(sodium 4-styrene sulfonate)(PSS) and polyacrylic acid(PAA) were used as templates. Tetraethylorthosilicate(TEOS) and aluminum isopropoxide were used as precursors for silica and alumina, respectively. The function of aluminum isopropoxide is to increase the porosity of silica shell. The characterizations of hollow silica were examined by TEM(transmission electron microscopy), TGA(thermogravimetric analysis), BET(Brunauer Emmett Teller), Energy-dispersive X-ray spectroscopy(EDS), and FT-IR spectrum. It was found that the shell thickness of hollow silica was around 8 nm and the core diameter was around 20 nm by TEM.

• Macromolecular Research
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• v.11 no.6
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• pp.518-522
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• 2003

We fabricated polymeric hollow spheres having macropores, which combine the advantageous properties of porous materials and hollow spheres. To fabricate such spheres, a polystyrene/methylmethacrylate solution was dispersed in water by vigorously stirring and then the suspension was quenched using liquid nitrogen. Water and methyl methacrylate present in the quenched suspension were readily sublimated by freeze-drying. Conclusively, the hollow-sphere structure and the macropores of its shell were created by the processes of liquid nitrogen-quenching and sublimation of methyl methacrylate domains within the shell, respectively.

• Smart Structures and Systems
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• v.14 no.2
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• pp.225-246
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• 2014

The present paper develops piezo-thermo-elastic analysis of a thick spherical shell for generalized functionally graded piezoelectric material. The assumed structure is loaded under thermal, electrical and mechanical loads. The mechanical, thermal and electrical properties are graded along the radial direction based on a power function with three different non homogenous indexes. Primarily, the non homogenous heat transfer equation is solved by applying the general boundary conditions, individually. Substitution of stress, strain, electrical displacement and material properties in equilibrium and Maxwell equations present two non homogenous differential equation of order two. The main objective of the present study is to improve the relations between mechanical and electrical loads in hollow spherical shells especially for functionally graded piezoelectric materials. The obtained results can evaluate the effect of every non homogenous parameter on the mechanical and electrical components.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2006.04a
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• pp.891-897
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• 2006

The volume control method which utilize a pressure node added into a finite shell element can overcome the drawbacks of conventional load control method and displacement control method. In this study, an improved volume control method is introduced for effective analysis of path-dependant behaviors of RC structures subjected to cyclic loading. RC shell structures including RC hollow columns are anlayized by discretizing the structures with layered shell elements and by applying in-plane two dimensional constitutive equations for concrete layers and reinforcement layers of the shell elements. The so-called path dependant volume control method is verified by comparing analysis results with other data including experimental results.