• Title/Summary/Keyword: Hollow

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Synthesis of Core/Shell Graphene/Semiconductor Nanostructures for Lithium Ion Battery Anodes

  • Sin, Yong-Seung;Jang, Hyeon-Sik;Im, Jae-Yeong;Im, Se-Yun;Lee, Jong-Un;Lee, Jae-Hyeon;Wang, Junyi;Heo, Geun;Kim, Tae-Geun;Hwang, Seong-U;Hwang, Dong-Mok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.288-288
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    • 2013
  • Lithium-ion battery (LIB) is one of the most important rechargeable battery and portable energy storage for the electric digital devices. In particular, study about the higher energy capacity and longer cycle life is intensively studied because of applications in mobile electronics and electric vehicles. Generally, the LIB's capacity can be improved by replacing anode materials with high capacitance. The graphite, common anode materials, has a good cyclability but shows limitations of capacity (~374 mAh/g). On the contrary, silicon (Si) and germanium(Ge), which is same group elements, are promising candidate for high-performance LIB electrodes because it has a higher theoretical specific capacity. (Si:4200 mAh/g, Ge:1600 mAh/g) However, it is well known that Si volume change by 400% upon full lithiation (lithium insertion into Si), which result in a mechanical pulverization and poor capacity retention during cycling. Therefore, variety of nanostructure group IV elements, including nanoparticles, nanowires, and hollow nanospheres, can be promising solution about the critical issues associated with the large volume change. However, the fundamental research about correlation between the composition and structure for LIB anode is not studied yet. Herein, we successfully synthesized various structure of nanowire such as Si-Ge, Ge-Carbon and Si-graphene core-shell types and analyzed the properties of LIB. Nanowires (NWs) were grown on stainless steel substrates using Au catalyst via VLS (Vapor Liquid Solid) mechanism. And, core-shell NWs were grown by VS (Vapor-Solid) process on the surface of NWs. In order to characterize it, we used FE-SEM, HR-TEM, and Raman spectroscopy. We measured battery property of various nanostructures for checking the capacity and cyclability by cell-tester.

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Synthesis of Fine Ba-Nd-Ti-O Powders by Spray Pyrolysis from Spray Solution with Sucrose (수크로스 함유 분무용액으로부터 분무열분해 공정에 의한 미세 Ba-Nd-Ti-O 분말 합성)

  • Ko, You-Na;Jung, Dae-Soo;Koo, Hye-Young;Kang, Yun-Chan
    • Korean Journal of Materials Research
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    • v.20 no.3
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    • pp.142-147
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    • 2010
  • Nano-sized $BaNd_2Ti_5O_{14}$ powders were prepared by the spray pyrolysis process. Sucrose used as the organic additive enabled the formation of nano-sized $BaNd_2Ti_5O_{14}$ powders. The powders prepared from the spray solution without sucrose had a spherical shape, dense structure and micron size before and after calcination. However, the precursor powders prepared from the spray solution with sucrose had a large size, and hollow and porous morphology. The precursor powders had an amorphous crystal structure because of the short residence time of the powders inside the hot wall reactor. The complete decomposition of sucrose did not occur inside the hot wall reactor. Therefore, the precursor powders obtained from the spray solution with sucrose of 0.5M had a carbon content of 39.2wt.%. The powders obtained from the spray solution with sucrose of 0.5M had a slightly aggregated structure of nano-sized primary powders of $BaNd_2Ti_5O_{14}$ crystalline phase after calcination at $1000^{\circ}C$. The calcined powders turned into nano-sized $BaNd_2Ti_5O_{14}$ powders after milling. The mean size of the $BaNd_2Ti_5O_{14}$ powders was 125 nm.

Evaluation of CIA(Conventional Intermittent Aeration) and MIA(Modified Intermittent Aeration) in Membrane Submerged Advanced Wastewater Treatment Process (멤브레인을 침지한 하수고도처리공법에서 기존간헐포기와 개량간헐포기의 효율성 비교평가)

  • Seo, In-Seok;Kim, Yeon-Kwon;Kim, Ji-Yeon;Kim, Hong-Suck;Kim, Byung-Goon;Choi, Chang-Gyu;Ahn, Hyo-Won
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.2
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    • pp.257-264
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    • 2006
  • In this study, the treatment of domestic wastewater in a field-scale membrane submerged intermittently aerated activated sludge process($210m^3/day$) was investigated under difference aeration methods. Operating temperature was 5.4 to 25.0 and membrane used in this study is a polyethylene hollow fiber membrane(pore size $0.4{\mu}m$). The range of operating flux was $9.7{\sim}24.4l/m^2-h$ and membrane permeates periodically operated for 7min followed idle for 3 min. The results showed that MIA(modified intermittent aeration) was more efficient in nitrogen and phosphorus removal. The removal efficiencies of T-N and T-P were 73.0% and 69.6% for CIA(conventional intermittent aeration) and 57.5%, 58.6% for MIA (modified intermittent aeration). With application of modified intermittent aeration, DO reached nearly Omg/l within 10 minutes after air off. Organics of influent could be entirely consumed to the denitrification and the P-release without the influence by remained DO in intermittent aeration reactor. Therefore, newly developed KSMBR(Kowaco-KMS-Ssangyoung Membrane Bio-Reactor) process with modified intermittent aeration can be one of the useful process for stable nitrogen and phosphorus removal.

PPTA/PVDF blend membrane integrated process for treatment of spunlace nonwoven wastewater

  • Li, Hongbin;Shi, Wenying;Qin, Longwei;Zhu, Hongying;Du, Qiyun;Su, Yuheng;Zhang, Haixia;Qin, Xiaohong
    • Membrane and Water Treatment
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    • v.8 no.4
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    • pp.311-321
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    • 2017
  • Hydrophilic and high modulus PPTA molecules were incorporated into PVDF matrix via the in situ polymerization of PPD and TPC in PVDF solution. PPTA/PVDF/NWF blend membrane was prepared through the immersion precipitation phase inversion method and nonwoven coating technique. The membrane integrated technology including PPTA/PVDF/NWF blend membrane and reverse osmosis (RO) membrane was employed to treat the polyester/viscose spunlace nonwoven process wastewater. During the consecutive running of six months, the effects of membrane integrated technology on the COD, ammonia nitrogen, suspended substance and pH value of water were studied. The results showed that the removal rate of COD, ammonia nitrogen and suspended substance filtered by PPTA/PVDF blend membrane was kept above 90%. The pH value of the permeate water was about 7.1 and the relative water flux of blend membrane remained above 90%. After the deep treatment of RO membrane, the permeate water quality can meet the water circulation requirement of spunlace process.

The nano scale bending and dynamic properties of isolated protein microtubules based on modified strain gradient theory

  • Benmansour, Djazia Leila;Kaci, Abdelhakim;Bousahla, Abdelmoumen Anis;Heireche, Houari;Tounsi, Abdelouahed;Alwabli, Afaf S.;Alhebshi, Alawiah M.;Al-ghmady, Khalid;Mahmoud, S.R.
    • Advances in nano research
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    • v.7 no.6
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    • pp.443-457
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    • 2019
  • In this investigation, dynamic and bending behaviors of isolated protein microtubules are analyzed. Microtubules (MTs) can be considered as bio-composite structures that are elements of the cytoskeleton in eukaryotic cells and posses considerable roles in cellular activities. They have higher mechanical characteristics such as superior flexibility and stiffness. In the modeling purpose of microtubules according to a hollow beam element, a novel single variable sinusoidal beam model is proposed with the conjunction of modified strain gradient theory. The advantage of this model is found in its new displacement field involving only one unknown as the Euler-Bernoulli beam theory, which is even less than the Timoshenko beam theory. The equations of motion are constructed by considering Hamilton's principle. The obtained results are validated by comparing them with those given based on higher shear deformation beam theory containing a higher number of variables. A parametric investigation is established to examine the impacts of shear deformation, length scale coefficient, aspect ratio and shear modulus ratio on dynamic and bending behaviors of microtubules. It is remarked that when length scale coefficients are almost identical of the outer diameter of MTs, microstructure-dependent behavior becomes more important.

A New Potato Cultivar "Early Valley", with High Yield and Early Maturity

  • Lim, H.T.;Dhital, S.P.;Khu, D.M.;Choi, S.P.;Kang, C.W.;Kim, T.J.;Mo, H.S.;Hwang, W.N.;Lee, W.J.
    • Korean Journal of Breeding Science
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    • v.41 no.1
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    • pp.61-67
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    • 2009
  • "Early Valley", is an early maturing potato cultivar with high yield potential. "Early Valley" is a clonal selection resulting from the cross between 'Suncrisp' and 'A87109-10'. It has medium plant height and light green foliage. "Early Valley" has medium flowering habit and white flowers. Tubers are smooth, yellow skin, light yellow flesh, round tuber shape, medium eye depth, and medium dormancy and good keeping quality. It has stable yield under wide range of climatic conditions. "Early Valley" is resistance to late blight, but moderately susceptible to common scab and hollow heart. This cultivar is also resistant to potato rotting at harvesting during the raining season. "Early Valley" has high level of antioxidant activity (about three times higher) and vitamin C (higher by 40%) than the 'Superior'. This cultivar has high level of tuber uniformity and capable of yielding 36.56 t/ha which is 17.07% higher than the control potato cultivar 'Superior' under optimum agronomical practices.

A Relationship between Micro-Landforms and Distribution of the Ancient Dwelling Site in the Middle Western area, Korea (한반도 중서부 도서지역에 있어서 사면 미지형과 옛 주거지 분포와의 대응관계)

  • Park, Ji Hoon;Choi, Seong Gil
    • Journal of The Geomorphological Association of Korea
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    • v.20 no.3
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    • pp.109-118
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    • 2013
  • The purpose of this study is to clarify the optimum locational environment of Neolithic Age and Bronze Age dwelling sites in Yeongjong-do, Incheon in terms of geographical characteristics. To make this possible, the micro-landform location environment of individual dwelling sites has been analyzed targeting 145 dwelling sites of Neolithic Age and 47 dwelling sites of Bronze Age in which quantitative analysis is possible among the dwelling sites verified in the investigation area until now. As a result, the micro-landform of hills where Neolithic Age and Bronze Age dwelling sites are crowded the most has been determined as the upper side hollow (64 dwelling sites, 44.1%) and the crest slope (39 dwelling sites, 83%), respectively. This means that the optimum locational environment of dwelling sites has been changed as the times have progressed from Neolithic Age to Bronze Age in the investigation area and the location of micro-landform of hills also where dwelling sites are located also has relatively moved up a little seen in terms of geographical perspective.

Powering Performance Characteristics of 2,5000 Ton Class Trimaran (2,5000톤급 삼동선의 저항추진특성)

  • Kuk-Jin Kang;Chun-Ju Lee;Do-Hyun Kim
    • Journal of the Society of Naval Architects of Korea
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    • v.38 no.3
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    • pp.14-22
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    • 2001
  • This paper presents the results of hull form design and powering performance for a 2.500 ton class trimaran frigate. A series of resistance tests and numerical calculations have been conducted to figure out the influences of side-hull form and position on the resistance characteristics of the trimaran. And the propulsion test was conducted to investigate the propulsion efficiency of the trimaran, and the powering performance of the trimaran was compared with that of the similar mono-hull ships in full scale. From the research it was found that the longitudinal position of side-hull had a large influence on the resistance characteristics of the trimaran while the side-hull form and transverse position had a small influence on it. The trimaran showed favorable resistance performance when the side-hull was located near the stern of trimaran, which was resulted from the fact that the side-hull stem was located near the primary wave hollow generated by the main hul1. The powering performance of the trimaran was superior to that of the similar mono-hull ships above the middle speed range.

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An Experimental Study of Nonlinear Viscoelastic Bushing Model for Torsional Mode (비선형 점탄성 부싱모델의 회전방향모드에 대한 실험적 연구)

  • Lee, Seong-Beom;Lee, Sung-Jae;Jun, Sung-Chul;Song, Dong-Ryul;Jeong, Jae-Young;Park, Chan-Seok;Lee, Woo-Hyun
    • Elastomers and Composites
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    • v.43 no.1
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    • pp.25-30
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    • 2008
  • A bushing is a device used in automotive suspension systems to reduce the load transmitted from the wheel to the frame of the vehicle. A bushing is a hollow cylinder, which is bonded to a solid steel shaft at its inner surface and a steel sleeve at its outer surface. The relation between the force and moment applied to the shaft and the relative deformation and rotational angle of a bushing exhibits features of viscoelasticity. Since a moment-rotational angle relation for a bushing is important for multibody dynamics numerical simulations, the simple relation between the moment and rotational angle has been derived from experiment. It is shown that the predictions by the proposed moment-rotational angle relation are in very good agreement with the experimental results.

Experimental Study on the Fire Resistance of Concrete Filled Steel Tubes according to Concrete Compressive Strengths (콘크리트 압축강도에 따른 강관기둥부재의 내화성능에 관한 실험적 연구)

  • Kwon, In-Kyu
    • Journal of the Korean Society of Hazard Mitigation
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    • v.11 no.2
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    • pp.1-8
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    • 2011
  • Concrete filled steel tubes(CFST) is considered as a column having better structural stability and better performance of fire resistance than that made with H-section and hollow section in itself. To get the fire resistance of the CFST, two kinds of concrete strength were used, 21 MPa, 40 MPa and 4 sorts of the applied loads were calculated and used to the specimens such as 3.5 m long, round and rectangular section. After various fire tests under 4 sorts of load ratios, the fire resistance of the CFST is not possible to get over 1 hour because of the rapid decrease of concrete strength. The below 50% of the applied load is recommended to obtain over 1 hour fire resistance of the CFST.