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Determination of Cholesterol, Fatty Acids and Polyaromatic Hydrocarbons in PM10 Particles Collected from Meat Charbroiling (고기구이 스모크에서 채취한 PM10입자에서 콜레스테롤, 지방산과 PAH의 분포)

  • Seo, Young-Hwa;Ko, Kwang-Youn;Jang, Young-Kee
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.2
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    • pp.155-164
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    • 2010
  • Emission from biomass combustion such as meat charbroiling is an important source of organic aerosol. Since source profiles are necessary input profiles for source apportionment of aerosol by a chemical mass balance model, meat cooking organic source profiles are developed by measuring organic marker compounds, including palmitic acid, stearic acid, oleic acid and cholesterol as well as PAH compounds. Emissions from meat and pork charbroiling are collected on quartz filters with a PM10-high volume sampler, extracted with organic solvents, derivatized with diazomethane/TMS and analyzed by GC/MS isotope dilution method. Organic and elemental carbon are also analyzed by an OCEC analyzer. Wt.% of cholesterol to the organic carbon(OC) content from beef and pork charbroiling is only 0.056 and 0.062, but wt. % of all saturated fatty acids to the OC content from beef and pork charbroiling is 2.727 and 2.022, and the wt% of all unsaturated fatty acids to the OC content is 0.278 and 0.438, respectively. Content of total PAH compounds to the OC content from beef charbroiling is higher than that from pork charbroiling, and those are 0.116 wt% and 0.044 wt%. Among PAH compounds benzo(a)pyrene as a single compound is account for 0.0071 wt% and 0.0023 wt% of OC content from beef and pork charbroiling. Ratios of marker compound to cholesterol are calculated, and those values are in good agreement with the values already reported at the food cooking emission, indicating that they can be used as organic source profiles for the apportionment of organic aerosol.

Refined Exposure Assessment for Three Active Ingredients of Humidifier Disinfectants

  • Lee, Jong-Hyeon;Kang, Hyun-Joong;Seol, Hwi-Soo;Kim, Chan-Kook;Yoon, Seung-Ki;Gwack, Jin;Kim, Yong-Hwa;Kwon, Jung-Hwan
    • Environmental Engineering Research
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    • v.18 no.4
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    • pp.253-257
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    • 2013
  • Exposure assessment for three major active ingredients used for humidifier disinfectants, polyhexamethylene guanidine (PHMG), oligo(2-(2-ethoxy)ethoxyethyl guanidinium chloride (PGH), and 5-chloro-2-methylisothiazol-3(2H)-one/2-methylisothiazol-3(2H)-one (CMIT/MIT) mixture, was conducted in a bedroom using an air sampler for a refined risk assessment. The experimental site was selected to reflect consumer exposure conditions. Aerosols formed by a humidifier were sampled during 8 hr at 7.5 L/min. Absorbed PHMG and PGH by the sampler were quantified using a spectrophotometric method, and high performance liquid chromatography-ultraviolet detection was used for CMIT/MIT. Three exposure scenarios were assumed for adding humidifier disinfectants to the humidifier water at 1, 2, and 10 times the volume recommended by the product suppliers, and the humidifier was on at its maximum rate of producing aerosols in order to consider reasonable worst-cases. The sampled mass of PHMG and PGH ranged 200 to $2,800{\mu}g$ and 140 to $1,900{\mu}g$, respectively, under different exposure conditions, whereas the absorbed mass of CMIT/MIT was barely detected at the detection limit of 0.11/0.29 mg/L, only at 10 times the recommended level. The resulting risk quotients for PHMG and PGH ranged 1,400 to 20,000 and 1,000 to 13,000, indicating that health risks could be significant. For CMIT/MIT mixture, risk quotients were much smaller than estimated by assuming that they are conservative in the indoor environment, probably due to oxidative reactions. The refined exposure assessment presented here may provide a useful tool for assessing risks posed by active ingredients in spray-type biocidal products.

Investigation of Water-Washing Process Parameters for Removal of Alkali Metals and Chlorides from Electric Arc Furnace Dust (EAFD) (전기 제강로 분진(EAFD)으로부터 알칼리 금속 및 염화물 제거를 위한 수 세척 공정 운영인자 조사)

  • Lee, Han Saem;Park, Da so mi;Ha, Jong Gil;Shin, Hyun Sang
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.11
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    • pp.626-633
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    • 2017
  • The present study investigated the effect of a water-washing process, which is part of the acid hydrometallurgical process for recovery of high purity of zinc, on the removal of alkali metals and chlorides (Na, K, Ca, Cl) from Electric arc furnace dust (EAFD). Two EAFD samples with different properties were characterized by particle size, XRD and element analysis, and their washing efficiencies (%) on alkali metals and chlorides were compared according to pH, washing time, liquid to solid (L/S) ratio and number of washings. The results show that the alkali metals and chlorides could be effectively removed by the washing (at L/S ration of 3 for more than 30 min., pH 10~11) while minimizing loss of zinc (<0.1%), in which the washing efficiency was Na-78%, K-76%, Cl >99%, respectively. Na and K could be removed up to 97% and 89% respectively by 3 times of repeated washings. With increased sample volume (10 times) of the mixed (1:1, w/w) sample with two types of EAFD, it was confirmed that the pH(10~11) can be used as the main process control parameter for the washing of the alkali metals regardless of EAFD properties.

Youth Startup Firms: A Case Study on the Survival Strategy for Creating Business Performance (청년창업기업의 창업초기 생존전략 : 중진공 청년전용자금 활용기업 사례)

  • Lee, Seung-Chang;Lim, Won-Ho;Suh, Eung-Kyo
    • Journal of Distribution Science
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    • v.12 no.6
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    • pp.81-88
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    • 2014
  • Purpose - Entrepreneurship promotion is emerging as an important economic growth agenda. However, in Korea, entrepreneurship has weakened because of the collapse of the venture bubbles of the 2000s and the global economic recession in 2008, which have induced the business community to choose stability over risk. The Korean government has been implementing several support projects to inspire and promote youth entrepreneurship through various means including financial assistance; however, the perpetuation rate of young entrepreneurship is still low as compared to advanced economies such as the US and EU. This case study focuses on the Youth Start-Up Business Support Program of the Small & Medium Business Corporation, and explores practical alternatives. Further, it aims to suggest managerial factors and a conceptual model for change management factors affecting the business performance creation of a startup company, based on the Small and medium Business Corporation's young venture startup fund. Research design, data, and methodology - Many studies examine the current progress and issues of startup firms, for example, a lack of systematic cultivation of entrepreneurship and startup business training, lack of commercialization funding for youth startup businesses, lack of mentoring, and inadequate infrastructure. From prior research, we address four factors, namely, personal managerial capabilities, innovative business model, sufficient cash flow, and social network, affecting startup companies' business performance. This study involved a sample survey of 200 young entrepreneurs to investigate casual relations between the four factors and business performance. A regression analysis was used to verify the hypotheses. Results - First, in relation to differences in the founder's personal characteristics, age, sales amount, and number of employees significantly impact business performance. Second, regarding the causal relation between the four factors for creating business performance, an innovative business model and social networking have supported the hypotheses, revealing that the more that a start-up founder has an innovative business model and social networking, the more the start-up firms are likely to have better performance (e.g., sales volume, employment, ROE, ROI, etc.). Although the founder's competency and sufficient cash flow have no significant relationship with business performance, the mean value was higher performance for high founder's competency and sufficient cash flow. Conclusions - This study provides basic data on policy support strategies of the Small and Medium Business Corporation, to help young entrepreneurs achieve their start-up business goals. It shows that young entrepreneurship startup firms should strive to explore ideas to satisfy customers' needs, and that changes in customer value and the continuous innovation of business model differentiation are required to actively respond to change management. Moreover, at the infant startup stage, they should activate social network programs to share information, thereby offsetting resource scarcity and managing business risk. Further, the establishment of a long-term vision and the implementation of training programs in related specific fields should be supported to strengthen founders' personal capabilities.

Carbon-capture Performance of foam Concrete Using Stainless Steel Slag (스테인리스 스틸 AOD 슬래그를 이용한 폼 콘크리트의 탄소포집 성능)

  • Kim, Byung Jun;Yoo, Sung Won;Choi, Young Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.4
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    • pp.18-25
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    • 2020
  • The purpose of this study is to investigate the mechanical and carbon-capture properties of foam concrete containing stainless steel argon oxygen decarbonization(AOD) slag. AOD slag was used as a binder, and foam concrete having a foaming ratio of 69 ± 0.5 % and a slurry density of 573.2 to 578.6 kg / ㎥ was produced. In order to examine the effect of carbonation, blended specimen was cured by two types : normal curing and CO2 curing. As a result of the experiment, the specimens incorporating AOD slag showed higher compressive strength than Plain after CO2 curing. According to the analysis of the image of foam concrete, it was confirmed that the ST30 has a lower total pore volume and average pore size than plain, resulting in high compressive strength. The SEM analysis confirmed the formation of calcite by carbonation of AOD slag. Through the thermogravimetric analysis, the increase of CO2 uptake was confirmed by the incorporation of AOD slag. Foam concrete has a higher porosity than normal concrete, so it is expected that carbon-capture performance can be improved by using a AOD slag.

The alterations of $Ca^{2+}$-activated $K^+$ channels in coronary artery during cardiac hypertrophy

  • Kim, Nari;Lee, Sang-Kyeong;Chung, Joon-Yong;Seog, Dae-Hyun;Kim, Euiyong;Jin Han
    • Proceedings of the Korean Biophysical Society Conference
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    • 2003.06a
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    • pp.23-23
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    • 2003
  • It has been suggested that the impairment of smooth muscle cell (SMC) function by alterations in the $Ca^{2+}$-activated $K^{+}$ ( $K_{Ca}$ ) channels accounts for the reduction in coronary reserve during left ventricular hypertrophy (LVH). However, this hypothesis has not been fully investigated. The main goal of this study was to assess whether the properties of $K_{Ca}$ channels in coronary SMCs were altered during LVH. New Zealand white rabbits (0.8-1.0 kg) and Sprague-Dawley rats (300-400 g) were randomly selected to receive either an injection of isoproterenol (300 $\mu\textrm{g}$/kg body weight) or an equal volume of 0.9% saline (1 mL/kg body weight). The animals developed LVH 10 days after injection. In patch-clamp experiments, the unitary current amplitude and open probability for the $K_{Ca}$ channels were significantly reduced in LVH patches compared with control patches. The concentration-response curve of the $K_{Ca}$ channel to [C $a^{2+}$]$_{i}$ was shifted to the right. Inhibition of the $K_{Ca}$ channels with TEA was more pronounced in LVH cells than in the control cells. The whole-cell currents of $K_{Ca}$ channels were reduced during LVH. Western blot analysis indicated no differences in $K_{Ca}$ channel expression between the control and LVH coronary SM membranes. In contraction experiments, the effect of a high $K^{+}$concentration on the resting tension of the LVH coronary artery was greater than on that of the control. The effect of TEA on the resting tension of the LVH coronary artery was reduced as compared with the effect on the control. Our findings imply a novel mechanism for reduced coronary reserve during LVH.ing LVH.

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Atmospheric Concentration and Size Distribution of Airborne Particulates, Benzopyrene and Heavy Metals (대기(大氣) 중 Benzopyrene 및 중금속(重金屬)의 농도(濃度)와 입경분포(粒徑分布))

  • Heo, Moon-Young;Kweon, Chang-Ho;Yu, Ki-Seon;Choi, Seong-Kyu;Kweon, Chang-Ho;Kim, Kyeong-Ho;Sohn, Dong-Hun
    • YAKHAK HOEJI
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    • v.34 no.1
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    • pp.1-10
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    • 1990
  • Total suspended particulate (TSP) in the atmosphere was collected and size-fractionated by Andersen high volume air sampler for the past two years (Mar. 1987-Feb. 1989) in Seoul. The concentrations of several polycyclic aromatic hydrocarbons and heavy metals were determined to investigate the atmospheric concentrations, seasonal variations and its relationship with the size distribution of suspended particulate matter. The arithmetic mean concentration of total suspended particulate was $229.48\;{\mu}g/m^3$. The concentrations of heavy metals were $2971.94\;ng/m^3$ for Fe, $767.75\;ng/m^3$ for Zn, $765.80\;ng/m^3$ for Pb, $218.40\;ng/m^3$ for Cu, $129.91\;ng/m^3$ for Mn, respectively. And the concentration of PAHs were $3.23\;ng/m^3$ for benzo(a)pyrene, $2.71\;ng/m^3$ for benzo(k)fluoranthene, $4.53\;ng/m^3$ for benzo(ghi)perylene, respectively. The mass-size distribution of TSP was lowest in the particle size range $1.1-3.3\;{\mu}m$ increased as the particle size increased or decreased. But PAHs, Pb and Zn abounded in particles below $2.0\;{\mu}m$, while Fe and Mn abouned in particles above $2.0\;{\mu}m$. TSP and its chemical compositions showed the seasonal variations. The concentrations of anthrophogenic origin like TSP, PAH and heavy metals in the fine particles were highest in winter and lowest in summer. PAH and Ph analyzed showed significant correlations with each other and with TSP concentration in fine particles, indicating that the particles in which they are contained have a similar behavior in the atmosphere.

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Presentation and Representation of Modernity in Modern Architecture - On Exclusion of Ornament and Emergence of the surface - (근대주의 건축에서 모더니티 표상의 문제 - 장식의 배제와 표면의 부각을 중심으로 -)

  • Khang, Hyuk
    • Journal of architectural history
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    • v.15 no.4
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    • pp.37-56
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    • 2006
  • Introducing International Style, P. Johnson and H. R. Hitchcock gave three standards to be the Modern, volume and surface, regularity, and exclusion of applied decoration. In spite of the negation of stylistic, formal approach in the Modernist Manifestoes, one usually have understood Modernity in Architecture with its formal character, especially with no ornament and flat, abstract, white surface. Modernism as a new paradigm in architecture have emphasized that there is no representation of anything outside and only present architecture in itself. They said that Modernism only cared about the language of Architecture without figural reference. So apparently there is no way to prove to its Modernity with formal condition. Modernity is in Spirit and contents. But actually we understand well its existence by visual communication This study deals with this difficult situation how Modernity represents itself without visual media and asks the question how simultaneously it presents its thingness and materiality In order to analyse contradictory situation between representation and presentation in Modern Architecture we need to survey the historical process of changing position of ornaments and its meaning in time. With the crisis of representation the role of ornament have seriously changed and divided. It caused the two situation in pre-Modern Architecture. Firstly, Architecture tend to be a high art and formal expression became important much more. The Use of Ornament became a kind of fashion to show the power, class, money. Secondly, Ornament lost its cultural weight and the structure and material aspect became the central in architecture. Rational Structuralism would be the essential character in Modern Architecture. Here the theory of G. Semper and A. Loos on cladding(dressing) and Ornament can help its problems and limits. In the situation without conventional ornament Modernists need to present modernity with new media that only show the thing itself and by that it does not represent any thing else as like the value, idea outside buildings. They believed that only it concerned esthetics and morality in architecture. But in reality it referred to art and machines as like ships, aircraft, and cars. By excluding Ornament and showing the process of clearing, abstract, flat, white surface 'represent' Modernity by the indirect way referring the concept of transparency, reason, sanitation, tectonics, etc. An Ideology and myth intervened architectural discourse to make the doxa about the representation in Architecture. Surface must be a different kind of media and message that can communicate in different way with compared to conventional Ornament. Decorated Shed by R. Venturi and Post-Functionalism by P. Eisenman, that are the most famous post-modern discourse, shows well difficult and contradictory condition in contemporary architecture concerning representation and form, meaning and form.

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Quality Characteristics of White Bread made with Flour of Wheat Cultured with Pleurotus ostreatus (Pleurotus ostreatus을 배양한 밀 분말 첨가가 식빵의 품질 특성에 미치는 영향)

  • Kim, Han-Sup;Chung, Hyun-Chae;Bae, Jong-Ho;Han, Gi-Dong
    • Journal of the East Asian Society of Dietary Life
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    • v.22 no.6
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    • pp.879-885
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    • 2012
  • This study was carried out to investigate the quality characteristics of white bread made with flour of wheat cultured with Pleurotus ostreatus(POW). The property of the wheat used for the solid-state cultivation of the Pleurotus ostreatus was examined. The hydration time of wheat with cold water was 10 hours, with a final moisture content of 39%, which was much less than the optimum moisture content for mycelial growth. However, hot water soaking reduced the required hydration time of the wheat, and elevated the moisture content to 65% within 90~120 min. The POW was composed of 7.2% moisture, 15.4% protein, 1.1% fat, 1.7% ash and 2.9% fiber. The POW was substituted for wheat flour in white bread recipes at weight percentages of 0%, 2.5%, 5%, 7.5% and 10%. The weight, volume and fermentation of the dough tended to decrease with increasing POW content. The color of the bread crust and crumb darkened with increasing POW content. A sensory evaluation showed a high preference for the white bread made with 5% POW, indicating that the addition of 5% POW to flour for bread dough could improve the quality characteristics of white bread. These study results also provide useful information for using the flour of wheat cultured with Pleurotus ostreatus as an ingredient source for food processing.

Effects of Curcuma longa $L_{INNE}$ Pharmacopuncture at $ST_{36}$ on Adjuvant Induced Arthritis in Rats (강황(薑黃)약침이 CFA로 유발된 류마티스성 관절염에 미치는 영향)

  • Lee, Ook Jae;Lee, Dong Geun;Lee, Ju Hee;Lee, Jung Hun;Lee, Sang Hyun;Park, Geun Hee;Shin, Jeong Cheol
    • Journal of Acupuncture Research
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    • v.30 no.4
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    • pp.95-105
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    • 2013
  • Objectives : The objective of this study was to investigate the effects of Curcuma longa $L_{INNE}$ pharmacopuncture at $ST_{36}$ on Complete Freund's Adjuvant(CFA)-induced arthritis in rats. Materials and methods : Arthritis was induced by injecting CFA subcutaneously into the left knee joint and paw, and Curcuma longa $L_{INNE}$ pharmacopuncture(CLL-A. $0.0343{\mu}g/kg$; CLL-B. $0.171{\mu}g/kg$; CLL-C. $0.343{\mu}g/kg$) was injected at $ST_{36}$ each other day for 5 times beginning on day 10 after the CFA injection. Paw edema, withdrawal response, hematological, serological and histological observation were assessed. Results : In paw edema volume all 3 groups(CLL-A, CLL-B, CLL-C) showed significant decrease compared to the CFA control group. In withdrawal response to reaction time and withdrawal response to force all 3 groups(CLL-A, CLL-B, CLL-C) showed significant increase compared to the CFA control group. In serum AST, group CLL-C showed significant decrease compared to the CFA control group. In histological observations, in all 3 groups, more normal chondrocytes were observed compared to the CFA control group and safranin O stain showed high positive reaction in the cartilage tissue close to the bone tissue. Conclusions : The results suggest that Curcuma longa $L_{INNE}$ Pharmacopuncture at $ST_{36}$ has a suppressing inflammation effect on Freund's adjuvant arthritis in rats.