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Synthesis and Properties of Copolyester Resin for Precoated MeTAL (Precoated Metal용 Copolyester Resin의 합성 및 물성)

  • Park, Lee Soon;Lee, Tae Hyung;Kim, Soon Hak;Chang, Jin Gyu
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.427-431
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    • 1999
  • Copolyester resins for the coil coating process of aluminium and steel strip were synthesized and their thermal properties, molecular weight and solvent solution characteristics were examined. Copolyesters were obtained by two step reactions. The first step was to prepare bishydroxyethyl terephthalate (BHET), bishydroxyneopentyl terephthalate (BHNPT), bishydroxyethyl isophthalate (BHEI), bishydroxyneopentyl sebacate (BHNPS), bishydroxyneopentyl adipicate (BHNPA) and bishydroxyethyl adipicate (BHEA) oligomers by esterification reactions. The second step was the polycondensation reaction utilizing those oligomers to obtain relatively high molecular weight copolyesters (Mw = 30,000~59,000 g/mol) as measured by GPC. These copolyesters were amorphous polymers as shown by DSC without $T_m$ peaks probably due to the kink structure introduced by BHET oligomer and relatively large free volume by bulky BHNPT and BHNPS oligomers. The copolyester samples with half of BHET oligomer substituted by BHNPT while keeping BHEI (0.3 mole) and BHNPS (0.1 mole) ratio constant showed glass transition temperature above $40^{\circ}C$ and good solubility in toluene both at low ($-5^{\circ}C$) temperature and room temperature.

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Effects of Plant-mineral Composites (PMC) on the Water Quality, Plankton Community and Microcystin-LR in Eutrophic Waters (식물-광물 혼합제가 부영양 수체의 수질, 플랑크톤 및 microcystin-LR에 미치는 영향)

  • Kim, Baik-Ho;Lee, Ju-Hwan;Park, Chae-Hong;Kwon, Dae-Yul;Park, Hye-Jin;Mun, Byeong-Cheon;Mun, Byeong-Jin;Choi, In-Chel;Kim, Nan-Young;Min, Han-Na;Park, Myung-Hwan;Hwang, Soon-Jin
    • Korean Journal of Ecology and Environment
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    • v.44 no.4
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    • pp.347-357
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    • 2011
  • We examined two reservoirs (Inkyung res. and Joongang res.) and two streams (Kyungan str. and Jecheon str.), all of which were eutrophic, during the 2010 warm season, to evaluate the water quality improvement activity (WQIA) of plant-mineral composite (PMC), which was previously developed to control suspended solids, including cyanobacterial bloom (Kim et al., 2010). We simultaneously measured both solid (S-MCLR) and dissolved microcystin-LR (D-MCLR), before and after PMC treatment, in the Joongang reservoir. Taking water body size and volume into account, we conducted the whole-scale experiment in the Inkyung reservoir, and mesocosm-scale experiments in the other three systems. The WQIAs of PMC were found to be comparatively high in SS (70~81%), TP (75~91%), BOD (65~91%), Chl-a (88~98%), phytoplankton (84~92%) and zooplankton (68~88%), except for the Kyungan stream, which was below 45% in all parameters. After PMC treatment, the concentrations of both SMCLR (47%) and D-MCLR (96%) decreased within two days, suggesting a mitigation possibility of hazardous chemicals such as agrochemicals and endocrine disrupters in the aquatic ecosystem. Our results collectively indicate that PMC is a useful agent to control suspended solids, including nuisance cyanobacterial bloom and their exudates, in an undisturbed water system with a long residence time.

Characteristics of Vitrification Process for Mixture of Simulated Radioactive Waste Using Induction Cold Crucible Melter (유도가열식 저온용융로를 이용한 혼합모의 방사성폐기물의 유리화 공정 특성)

  • 김천우;양경화;박병철;박승철;황태원;박종길;신상운;하종현;송명재
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.3
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    • pp.165-174
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    • 2004
  • In order to simultaneously vitrify the ion exchange resin(IER) and combustible dry active waste(DAW) generated from Korean nuclear power plants, a vitrification pilot test was conducted using an induction cold crucible melter(CCM) . The energy necessary for startup of the glass using a Ti-ring was evaluated as about 290 kWh. The power supplied from a high frequency generator to melt the glass properly was ranged from 160 to 190 kW without any interruption. When the mixture of the IER and DAW was fed into the CCM, the concentration of CO was lowered up to 1/40 compared to feeding the IER solely. It may be caused by the DAW which can produce about 1.8 times higher heat compared to the IER. When the swelling phenomenon occurred in the glass melt, the concentration of $NO_2$, oxidizing gas, was higher than NO, reducing gas. Total feed amounts of the IER and DAW were 368 and 751 kg, respectively. And then, about 74 of volume reduction factor was achieved.

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Characteristics of Ionic Composition of Rainwater in Taean (태안지역 강우의 이온 조성)

  • Lee, Jong-Sik;Kim, Gun-Yeob;Lee, Jeong-Taek;Lee, Kwan-Yong;Park, Byoung-Yong
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.9 no.1
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    • pp.49-54
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    • 2007
  • The issue of acid precipitation and related environmental problems in East Asia has been emerging. To evaluate the acidity and chemical characteristics of rainwater in Korea, its chemical properties during cultivation season from April to October in 2005 were investigated at Taean. Also, to estimate the contribution of ions on acidity, ion composition characteristics and neutralization effects by cations were determined. The electrical conductivity balance between measured and estimated values showed a high correlation. Rainwater was highly distributed in the range of pH $4.5{\sim}5.0$. The acidity of rainwater was relatively low during the month of June compared with other monitored periods. $Na^+$ was the main cation, followed by $H^+>Ca^{2+}>NH_4^+>K^+>Mg^{2+}$. Among these ions, $Na^+,\;NH_4^+,\;Ca^{2+}$ and $H^+$ comprised over 94% of the total cations. Rainwater anion composition was more than 80% with $SO_4^{2-}$ and $NO_3^-$. In rainwater samples, $NH_4^+$ and $Ca^{2+}$ contributed greatly to neutralizing the rain acidity. The sulfate content decreased until September, and sea salt derivatives were higher in May and October than during other monitored periods. Also, 78% of the soluble sulfate in rainwater was nss-$SO_4^{2-}$ (non-sea salt sulfate).

Studies on the Relation between Characteristics of Stem and Leaf Area and Weight in the Mulberry Tree (뽕나무지조의 성상과 엽면적 및 엽중과의 관계에 관한 연구)

  • 김호락;김문협
    • Journal of Sericultural and Entomological Science
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    • v.13 no.1
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    • pp.1-11
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    • 1971
  • This study are conducted to observe the correlation which are concerned with tile internode length to the leaf area and leaf weight. Where as, small leaf variety Gae Ryang Su Ban, and large leaf variety Ro Sang are adopted to observe their correlations in a group consisting of 30 varieties and in identifiable varieties. The results are as follows: A. Such positive correlations are observed between each characteristics and leaf area with leaf weight. (1) There are highly positive correlation between internode length and leaf area with leaf weight together within varieties group. (2) No correlation with stem length is observed, but high correlation is acknowledged in identifiable varieties although positive correlations are recognized. (3) Correlations are showed between stem volume and leaf area with leaf weight in identifiable varieties, especially Gae Ryang Su Ban higher than any other varieties. (4) Petiole length is not correlated to leaf area and leaf weight in varieties group, but petiole weight is highly correlated to leaf area and leaf weight in varieties group, Gae Ryang Su Ban and Ro Sang variety. B. Internode length along with the stem parts shows the same tendency of variance as most varieties do; internode length of I part at the base is the longest one, gradually shrunk to that of III part and gloved longer, and again internode length becomes shorter to the top. C. Variance of leaf area and leaf weight along with the parts are the lowest ones at the I part, gradually increased to the maximum at IV part, and here after it comes to shrink.

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The Effect of Therapy Oriented CT in Radiation Therapy Planning (치료 계획용 전산화 단층촬영이 방사선 치료계획에 미치는 효과)

  • Kim, Sung-Kyu;Shin, Sei-One;Kim, Myung-Se
    • Radiation Oncology Journal
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    • v.5 no.2
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    • pp.149-155
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    • 1987
  • The success of radioation therapy depends on exact treatment of the tumor with significant high dose for maximizing local control and excluding the normal tissues for minimizing unwanted complications. To achieve these goals, correct estimation of target volume in three dimension, exact dose distribution in tumor and normal critical structures and correction of tissue inhomogeneity are required. The effect of therapy oriented CT (plannng CT) were compared with conventional simulation method in necessity of planning change, set dose, and proper distribution of tumor dose. Of 365 new patients examined, planning CT was performed in 104 patients $(28\%)$. Treatment planning was changed in $47\%$ of head and neck tumor, $79\%$ of intrathoracic tumor and $63\%$ of abdmonial tumor. in breast cancer and musculoskeletal tumors, planning CT was recommended for selection of adequate energy and calculation of exact dose to critical structures such as kidney or spinal cord. The average difference of tumor doses between CT planning and conventional simulation was $10\%$ in intrathoracic and intra-abdominal tumors but $20\%$ in head and neck tumors which suggested that tumor dose may be overestimated in conventional simulation Although some limitations and disadvantages including the cost and irradiation during CT are still criticizing, our study showed that CT Planning is very helpful in radiotherapy Planning.

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Factor Analysis of Decreased Score on Coronary Artery Calcium Score (관상동맥 석회화점수 감소 요인 분석)

  • Shim, Jae-Goo;Kim, Yon-Min;Kim, Jin-Woo
    • Journal of the Korean Society of Radiology
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    • v.10 no.4
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    • pp.285-290
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    • 2016
  • The purpose of our study was to retrospectively evaluate the cause of a decreased calcium score of follow-up studies on coronary artery calcium scores (CACs) computed tomography (CT). The subjects were healthy 100 people(85 males $60.6{\pm}6.9$ years, 15 females $67.2{\pm}7.3$ years). The subjects decreased CACs were divided into 4 subgroups depending on Agatston classification, minimal (1-10), mild (11-100), moderate (101-400), severe (400<). As a result of decreased CACs were scan location disagreement 51%, motion artifact 26%, equipment changes 14%, operator mistakes 5%, input miss 2%, image loss 1%, arrhythmia 1%. In the mild group, the most common decreased CACs were 49 people. In the minimal group, the most significant variation reduction has occurred to 6 people. Scan location disagreement was considered a partial volume effects due to the scan starting position. It showed less than 100 CACs a high variation (19.7%) in more than 100 CACs, a lower variation (2.2%), these could be seen that the variation range is different that can be tolerated according to the calcification score. Motion artifact factor was found in 26%, which is so closely related to the preceding tests that affect the higher heart rate like this pulmonary function test, exercise stress test.

Effect of cultivar and ascorbic acid on in vitro shoot regeneration and development of bombardment-mediated plastid transformation of tomato (Lycopersicon esculentum) (토마토 재분화 효율 향상 및 엽록체 형질전환 조건)

  • Roh, Kyung-Hee;Lee, Ki-Jong;Park, Jong-Sug;Kim, Jong-Bum;Lee, Seung-Bum;Suh, Seok-Cheol
    • Journal of Plant Biotechnology
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    • v.37 no.1
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    • pp.77-83
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    • 2010
  • Eighteen cultivars of tomato were tested for their regeneration response. Lycopersicon esculentum cv. 2001-58 showed a very high frequency of regeneration (93%). We evaluated the effect of two compounds with known antioxidant activity (ascorbic acid and cystein). The use of ascorbic acid ($200\;-\;300\;{\mu}M/L$) has a positive effect on shoot regeneration. To develope a system for plastid transformation in tomato via homologous recombination, we constructed the tomato plastid expression vector (pKRT22-AG) harboring 2.2 kb flanking sequences cloned from intact plastid genome and gfp gene. To investigate the factors affecting the delivery system of the pKRT22-AG into chloroplast using bombardment, We assessed the optimal DNA concentration, gold particle volume and target distance. Expression of the GFP protein was observed within chloroplast on protoplast of cotyledon explant by confocal laser scanning microscopy, which indicates that the protocol developed in this study be useful for the production of plastid transgenic plants in tomato.

Study on Physical Properties of Domestic Species II: Sorption, Thermal, Electrical and Acoustic Properties of Pinus koraiensis and Larix kaempferi (국산재의 응용물성연구II: 잣나무 낙엽송의 수분흡착성 및 열적·전기적·음향적 성질)

  • Byeon, Hee-Seop;Lee, Won-Hee;Park, Byung-Soo;Chong, Sung-Ho;Kang, Ho-Yang
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.4
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    • pp.1-10
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    • 2008
  • A series of the studies on the applied physical properties of domestic species have been conducted last three years. Pinus koraiensis and Larix kaempferi were two of the three species examined for the first year. Because the same apparatus and experimental procedures were used for all species, their results can be easily comparable. The experiments for sorption property were conducted with 20- and 80-mesh wood powder and resulted in their EMCs and sorption isotherms at various RH conditions. The thermal conductivity and diffusivity, and electric resistance and volumetric electric resistivity were measured with a thermal-wire device and a high electric resistance meter. The differences in the thermal and electric properties between quarter- and flat-sawn specimens were observed, which were partially attributed to their anatomical differences. An acoustic measurement system was used to evaluate dynamic MOE and internal friction. This paper provides the useful fundamental data for designing a wood structure, correcting a portable resistance-type moisture meter, and acoustic properties of wood.

Salinity Distribution in the Mid-eastern Yellow Sea during the High Discharge from the Keum River Weir (금강하구언 대량방류시 황해 중동부 해역의 염분분포)

  • Choi, Hyun-Yong;Lee, Sang-Ho;You, Kwang-Woo
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.4 no.1
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    • pp.1-9
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    • 1999
  • Hydrographic survey was carried out in the mid-eastern Yellow Sea from Keum River to Taean Peninsula in order to study the motion of the freshwater from the Keum River during July 07-12, 1997 when a large volume of freshwater was discharged from the Keum River weir. The low-salinity (less than 30.0 psu) plume was distributed over the large area between the Keum River and Ochong Island, 60 km northwest off the Keum River mouth. A band of relatively low saline water, originating from the Keum River, was also observed to the north of Ochong Island. The strong haline front had advanced from near Sibidongpa Island to Ochong Island, 25 km northwest of Sibidongpa Island, for 48 hours. A northwestward flow of a speed greater than 0.2 m/s was observed in the surface plume layer to the north of Sibidongpa Island where the water column was strongly stratified. The observed mean flow and the change of the frontal position are interpreted as resulting from the spreading of the Keum River plume. These results suggest that the discharge from the Keum River plays an important role in the coastal circulation of the mid-eastern Yellow Sea adjacent to the river.

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