• 한국자기공명학회논문지
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• 제2권1호
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• pp.66-83
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• 1998

Study on spin-rotation relaxation of nuclear spins located on a methyl group can reveal valuable dynamic information related to the internal rotation of methyl group itself. Toward this end we have measured methyl carbon-13 spin-rotation of methyl group itself. Toward this end we have measured methyl carbon-13 spin-rotational relaxation rate in toluene and 2-chloro-p-xylene over the temperature range of 179-363K. To interpret the temperature dependence of measured spin-rotational relaxation rate we have revised the temperature dependence of measured spin-rotational relaxation rate we have revised the expression derived thus far by other authors and reproduced experimental data on the basis of the newly derived expression. The results confirmed that our expression leads to better agreement with experimental data than the previous one over observed temperature range, especially at high temperature.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2000년도 International Symposium on Magnetics The 2000 Fall Conference
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• pp.461-461
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• 2000

We have investigated electronic structuresof antiferromagnetic YBaCo_2O_5 using the local spin-density approximation (LSDA) + U method. The charge and orbital ordered insulating ground state is correctly obtained with the strong on-site Coulomb interaction. Co^{2+} and Co^{3+} ions are found to be in the high spin (HS) and intermediate spin (IS) state, respectively. The tetragonal to orthorhombic structural transition is responsible for the ordering phenomena and the spin states of Co ions. The large contribution of the orbital moment to the total magnetic moment indicates that the effect of the spin-orbit coupling is very important in YBaCo_2O_5.

• 한국전기전자재료학회논문지
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• 제35권1호
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• pp.58-65
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• 2022

The field of liquid crystal display (LCD) is constantly in the spotlight and the process of depositing an alignment layer in the LCD manufacturing process is very important to obtain excellent performance such as low-power driving and high-speed response to improve LCD performance. Therefore, research on liquid crystal (LC) alignment is being actively conducted. When manufacturing LCD, it is necessary to consider the effect of the alignment layer thickness as one of the factors affecting various LCD performances. In addition, previous studies confirmed the LC alignment characteristics correlate with the rotation speed in the spin coating process. Therefore, the electro-optical properties of the LCD were investigated by manufacturing a polyimide alignment layer by varying the rotation speed in the spin coating process in this study. It was confirmed that the thickness of the polyimide alignment layer was controlled according to the spin coating conditions. The average transmittances of anti-parallel LC cells at the spin coating speed of 2,500 rpm and 3,000 rpm are about 60%, which indicates that the LC cell has relatively higher performance. At the spin coating speed of 3,000 rpm, the voltage-transmittance curve of twisted nematic (TN) LC cell was below 1.5 V, which means that the TN LC cell operated at a low power. In addition, high-speed operating characteristics were confirmed with a response time of less than 30 ms. From these derived data, we confirmed that the ideal spin coating speed is 3,000 rpm. And these results provide an optimized polyimide alignment layer process when considering enhanced future LCD manufacturing.

• Bulletin of the Korean Chemical Society
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• 제24권7호
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• pp.981-985
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• 2003

Fluorine-19 NMR solution measurements have been made for various phenyl-fluorinated iron porphyrin complexes. Large chemical shifts for phenyl fluorine signals of iron(III) and iron(II) are observed, and these signals are sensitive to electronic structure. The chemical shift differences in ortho-phenyl fluorine signals between high-spin ferric and low-spin ferric tetrakis(pentafluorophenyl)porphyrins are approximately 40 ppm, whereas the differences are approximately 7 ppm between high- and low-spin states of ferrous tetrakis(pentafluorophenyl)porphyrin complexes. Analysis of fluorine-19 isotropic shifts for the iron(III) tetrakis(pentafluorophenyl) porphyrin using fluorine-19 NMR indicates there is a sizable contact contribution at the ortho-phenyl fluorine ring position. Large phenyl fluorine-19 NMR chemical shift values, which are sensitive to the oxidation and spin states, can be utilized for identification of the solution electronic structures of iron(III) and iron(II) porphyrin complexes.

• 인지과학
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• 제27권1호
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• pp.129-157
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• 2016

본 연구는 한국어의 소음속말인지(Speech perception in noise, SPIN)에 대하여 알아 보았다. 영어의 SPIN 테스트와 비슷한 형식을 채택하여 새로운 한국어 SPIN 테스트를 개발하였다. 예측성 효과와 소음효과, 이 둘의 상호작용에 대하여 알아봄으로써 기존의 영어에 기반을 둔 연구에서 발견한 것들을 재확인하고자 하였다. 새로운 한국어 SPIN 테스트를 사용하여 14명의 성인 한국인을 대상으로 한 실험 결과는 이전 연구들이 발견한 사항들을 다시 한 번 입증하였다. 첫째, 참여자들의 대체적인 SPIN 수행능력은 상대적으로 고소음 보다 저소음환경에서 더 나았다. 둘째, 문맥상 비교적 예측하기 쉬운 단어들이 예측하기 어려운 단어들보다 특히 고소음 환경에서 더 정확히 인지되었다. 이러한 결과는 청자들이 두 가지 종류의 정보, 즉 음성적 정보와 문맥적 정보를 말인지에 적극적으로 사용한다는 것을 의미하는 것으로 해석할 수 있다. 소음으로 인해서 말소리의 음성적인 특징이 약해졌을 때 청자들은 말소리를 처리하기 위해서 언어적 문맥정보를 적극적으로 이용하는 것이다. 본 연구에서 발견한 것들은 영어의 SPIN 테스트에 기반을 둔 기존 연구들에서 발견한 것과 일치한다. 게다가, 표적어의 빈도 효과에 대한 가능성을 발견하였는데, 이는 한국어의 이 분야에 대한 더 다양하고 활발한 연구가 있어야 함을 시사한다.

• 센서학회지
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• 제30권6호
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• pp.451-455
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• 2021

Porous copper bromide (CuBr) films are highly advantageous for detecting ammonia (NH₃). The fabrication of porous CuBr films requires complex high-temperature processes or multistep processes. Herein, we report the uncomplicated preparation of porous CuBr films by a spin-coating method and the films' excellent NH₃ sensing properties. The porous films were prepared by spin-coating 100, 150, and 200 mM CuBr solutions, and then dried in a vacuum oven for 2 h. All the films showed a high NH₃ response; in particular, the film prepared using a 100 mM CuBr solution showed an extremely high response (resistance ratio = 852) to 5 ppm NH₃. The film also showed fast response and recovery times, 272 s and 10 s respectively, even at room temperature. The outstanding NH₃ sensing characteristics were explained in relation to the porosity and thickness of the prepared films. The high-performance NH₃ sensors used in this study can be used for both indoor air quality and environmental monitoring applications.

• 센서학회지
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• 제23권6호
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• pp.377-382
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• 2014

Detecting and segmenting diffuse targets in laser ranging data is a critical problem for tactical reconnaissance. In this study, we propose a new method that facilitates the characterization of diffuse irregularly shaped objects using "spin images," i.e., local 2D histograms of laser returns oriented in 3D space, and a clustering process. The proposed "cluster-based spin imaging" method resolves the problem of using standard spin images for diffuse targets and it eliminates much of the computational complexity that characterizes the production of conventional spin images. The direct processing of pre-segmented laser points, including internal points that penetrate through a diffuse object's topmost surfaces, avoids some of the requirements of the approach used at present for spin image generation, while it also greatly reduces the high computational time overheads incurred by searches to find correlated images. We employed 3D airborne range data over forested terrain to demonstrate the effectiveness of this method in discriminating the different geometric structures of individual tree clusters. Our experiments showed that cluster-based spin images have the potential to separate classes in terms of different ages and portions of tree crowns.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2000년도 춘계연구발표회 논문개요집
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• pp.150-151
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• 2000

• Bulletin of the Korean Chemical Society
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• 제22권4호
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• pp.413-416
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• 2001

• 한국자기학회:학술대회 개요집
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• 한국자기학회 1999년도 추계연구발표회 논문개요집
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• pp.104-105
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• 1999