• Bulletin of the Korean Chemical Society
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• v.32 no.12
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• pp.4205-4209
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• 2011

The $Li_2Mn_{0.5}Fe_{0.5}SiO_4$ silicate was prepared by blending of $Li_2MnSiO_4$ and $Li_2FeSiO_4$ precursors with same molar ratio. The one of the silicates of $Li_2FeSiO_4$ is known as high capacitive up to ~330 mAh/g due to 2 mole electron exchange, and the other of $Li_2FeSiO_4$ has identical structure with $Li_2MnSiO_4$ and shows stable cycle with less capacity of ~170 mAh/g. The major drawback of silicate family is low electronic conductivity (3 orders of magnitude lower than $LiFePO_4$). To overcome this disadvantage, carbon composite of the silicate compound was prepared by sucrose mixing with silicate precursors and heat-treated in reducing atmosphere. The crystal structure and physical morphology of $Li_2Mn_{0.5}Fe_{0.5}SiO_4$ was investigated by X-ray diffraction, scanning electron microscopy, and high resolution transmission electron microscopy. The $Li_2Mn_{0.5}Fe_{0.5}SiO_4$/C nanocomposite has a maximum discharge capacity of 200 mAh/g, and 63% of its discharge capacity is retained after the tenth cycles. We have realized that more than 1 mole of electrons are exchanged in $Li_2Mn_{0.5}Fe_{0.5}SiO_4$. We have observed that $Li_2Mn_{0.5}Fe_{0.5}SiO_4$ is unstable structure upon first delithiation with structural collapse. High temperature cell performance result shows high capacity of discharge capacity (244 mAh/g) but it had poor capacity retention (50%) due to the accelerated structural degradation and related reaction.

• Journal of the Korean Electrochemical Society
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• v.22 no.4
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• pp.148-154
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• 2019

Vanadium oxide based materials have been studied as novel negative electrode materials in lithium-ion batteries (LIBs) because of their high specific capacity. In this study, potassium metavanadate ($KVO_3$) was synthesized and its electrochemical properties are evaluated as a negative electrode materials. The aqueous solution of $NH_4VO_3$ is mixed with a stoichiometric amount of KOH. The solution is boiled to remove $NH_3$ gas and dried to obtain a precipitate. The obtained $KVO_3$ powders are heat-treated at 300 and $500^{\circ}C$ for 8 h in air. As the heat treatment temperature increases, the initial reversible capacity decreases, but the cycle performance and Coulombic efficiency are improved slightly. On the contrary, the electrochemical performances of the $KVO_3$ electrodes are greatly improved when a polyacrylic acid (PAA) as binder was used instead of polyvinylidene fluoride (PVDF) and a fluoroethylene carbonate (FEC) was used as electrolyte additive. The initial reversible capacity of the $KVO_3$ is 1169 mAh/g and the Coulombic efficiency is improved to 76.3% with moderate cycle performance. The $KVO_3$ has the potential as a novel high-capacity negative electrode materials.

• Journal of Information Technology Services
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• v.11 no.3
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• pp.67-87
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• 2012

These days, firms are focusing on the improvement of relationships with business partners. The supply chain integrations are taking critical role in improving the relationships with business partners. In accordance with the development of the IT technology, it became possible for firms not only to integrate inner parts of the organization, but also to integrate the company with other organizations in the supply chain, which is open system. Therefore, in e-Biz environments, it is imperative for firms to strengthen the core capacity through the supply chain integration, and to precisely determine the components of the determinants of e-Business integration which impact the firm performance. This study analyzed determinants that have impacts on business integration in IT capacity perspectives in competetive environments. We analyzed 163 domestic companies to find out many significant suggestive points. First, IT management capacity, process innovation capacity are adopted as determinants of differentiation and competetive edges against competing firms. Second, it is analyzed that the more the companies are in intensified competetive environment, the more likley that the innovation capacity and partner management capacity become the determinants of the business integration of the companies and that they pursue new market development strategy. Third, it is analyzed that the more the companies are in high demand fluctuation, the more likley that the innovation capacity becomes the determinants of the business integration of the companies, and that they pursue new market development strategy and operation efficiency strategy. Last, it is analyzed that the more the companies are Technology dependent, the more likely that IT management capacity and process innovation capacity become the determinants of business integration, and that they pursue new market development strategy and operation efficiency strategy. These results provide us the foundation that the determinants that we have analyzed can impact the supply chain integration strategies which take into account the competetive environments.

• Journal of the Korean Society for Heat Treatment
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• v.13 no.4
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• pp.231-238
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• 2000

Flake graphite cast irons with the high damping capacity have been used for the control of vibration and noise occurring in the members of various mechanical structures under vibrating conditions. However, the damping capacity which is morphological characteristics of graphite is one of the important factors in reducing the vibration and noise, but hardly any work has deal with this problem. Therefore, the authors have examined the damping capacity of various cast irons with alloying elements and studied the influences of the matrix structures, mechanical properties and morphological characteristics of graphite. The main results obtained are as follows: Effects of pouring temperature on the damping capacities and mechanical properties were investigated in 3.6%C cast iron. At $1400^{\circ}C$, specific damping capacity showed the maximum value, and decreased with increase pouring temperature. Mechanical properties showed opposite trend with the damping capacity. And then, effects of Ni on the damping capacities and mechanical properties have been investigated in 3.6%C gray cast iron. At 0.2%Ni content, specific damping capacity showed the maximum value, and decreased with further increase in Ni content. Graphite length also showed same behavior. This indicates that the specific damping capacity has a close relation with graphite length. In case of Mo addition in 3.6%C-0.2%Ni cast iron, specific damping capacity and tensile strength was 27% and $20kgf/mm^2$ at 3.6%C-0.2%Ni-0.3%Mo cast iron respectively.

• Journal of Environmental Science International
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• v.9 no.4
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• pp.351-367
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• 2000

Air-lift biofilm reactor should be an admirable process substituting conventional activated sludge process, because of its small area requirement as well as high volumetric loading capacity and stability against loading and chemical shocks. However most of the past research on the performance of ABR was focused on the sewage treatment. This research studied the applicability of ABR to treat high strength wastewater. A bench-scale ABR was operated to treat high strength synthetic wastewater, tannery wastewater and petrochemical wastewater, and its applicability was conclusive In case of synthetic wastewater, ABR showed good performance in which the substarate removal efficiency was higher that 80% even under short HRT(1.4 hr) and high volumetric loading rate(9.3 kgCODcr/$m^3$.day). When ABR was applied to treat tannery wastewater, it was suggested that the maximum volumetric loading rate and F/M ratio should be 7.7kgCODcr/$m^3$.day, 0.76 $day^{-1}$, respectively. And high substrate removal efficiency over than 90 % was observed with 4,000 mgCODcr/L of petrochemical wastewater. Even though effluent concentration was quite high, ABR should be applicable to treat the high strength wastewater, because of its high loading capacity.

• Journal of Power System Engineering
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• v.14 no.4
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• pp.43-49
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• 2010

In the present study, optimization of throttle margin for high pressure turbine to be retrofitted or partially modified for power uprating or life extension in nuclear power plant, has been performed to increase the electrical output. Throttle margin for high pressure turbine is required to maintain all the time the rated power by opening more of governor valves whenever inlet pressure is decreased due to the tube plugging of steam generator. If throttle margin of high pressure turbine is too much compared to remaining lifetime, loss of electrical output due to pressure drop of governor valves is inevitable. On the contrary, if it is too little, the rated power operation can not be accomplished when inlet pressure of high pressure turbine is dropped after many years operation. So, throttle margin for high pressure turbine in nuclear power plant is compromised considering for the degradation of steam generator, governor valve capacity, manufacturing tolerance of high pressure turbine, future plan of power uprating, and remaining lifetime of power plant.

• Korean Chemical Engineering Research
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• v.60 no.3
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• pp.446-451
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• 2022

In this study, to improve capacity and cycle stability, the pitch coated nano silicon sheets/CNT composites were prepared through electrostatic bonding of nano silicon sheets and CNT. Silica sheets were synthesized by hydrolyzing TEOS on the crystal planes of NaCl, and then nano silicon sheets were prepared by using magnesiothermic reduction method. To fabricate the nano silicon sheets/CNT composites, the negatively charged CNT after the acid treatment was used to assemble the positively charged nano silicon sheets modified with APTES. THF as a solvent was used in the coating process of PFO pitch. The physical properties of the prepared anode composites were analysed by FE-SEM, XRD and EDS. The electrochemical performances of the synthesized anode composites were performed by current charge/discharge, rate performances, differential capacity and EIS tests in the electrolyte LiPF₆ dissolve solvent (EC:DMC:EMC = 1:1:1 vol%). It was found that the anode material with high capacity and stability could be synthesized when high composition of silicon and conductivity of CNT were used. The pitch coated nano silicon sheets/CNT anode composites showed initial discharge capacity of 2344.9 mAh/g and the capacity retention ratio of 81% after 50 cycles. The electrochemical property of pitch coated anode material was more improved than that of the nano silicon sheets/CNT composites.

• The Korean Journal of Physiology
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• v.1 no.1
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• pp.77-82
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• 1967

The normal lung volumes were determined and subdivided under sitting position in 48 middle school girls, 49 high school girls and 44 house wives. All subjects were free of pulmonary and vascular diseases. The vital capacity was measured by Mckessons spirometer and the residual volume was determined by Rahn's three breathing method. 1. The lung volumes (BTPS) of middle school girls determined were: $RV\;0.59{\pm}0.11l\;FRC\;1.45{\pm}2.22l\;VC\;2.68{\pm}0.29l$ 2. The lung volumes (BTPS) of high school girls determined were: $RV\;0.83{\pm}0.19l\;FRC\;1.9{\pm}0.25l\;VC\;3.15{\pm}0.24l$ 3. The lung volumes (BTPS) of house wives determind were: $RV\;0.95{\pm}0.61{\ell}\;FRC\;2.1{\pm}0.25{\ell}\;VC\;3.06{\pm}0.29l$ 4. The calculated residual ratio $(RV/TLC{\times}100)$ were: $17.7{\pm}2.57%$ in middle school girls and $20.6{\pm}3.65%$ in high school girls and $24.0{\pm}2.31%$ in house wives 5. The functional residual ratio $(FRC/TLC{\times}100)$ were: $43.7{\pm}5.98%$ in middle school girls and $48.8{\pm}4.41%4 in high school girls and $52.6{\pm}5.38%$ in house wives. 6. The correlation coefficients between vital capacity and total lung capacity were r=0.96 in middle school girls and r=0.986 in high school girls and r=0.856 in house wives. 7. The regression equations were obtained follows: $TLC(l) =1.105{\times}VC+0.304$ (in middle school girls) $TLC(l) =1.551{\times}VC-0.902$ (in high school girls) $TLC(l) =0.999{\times}VC+0.954$ (in house wives)

• Land and Housing Review
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• v.7 no.1
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• pp.31-41
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• 2016

In this paper, we propose experimental results, which target the major variables that influence the structural performance of a wall, as well as the resulting seismic and hysteretic behavior. Results also provide the basis for the application of performance based design by identifying the nonlinear hysteretic behavior of the wall with boundary element details recently proposed in previous study by Chun et al(2011). From the experimental results, the crack and fracture patterns of a specimen, which adopt the proposed boundary element details, showed similar tendencies regardless of whether axial force or high performance steel bars is applied. Furthermore, results show that the maximum strength of the specimen can be predicted accurately based on the design equation proposed by the standard. In addition, with a higher axial force, there is a tendency that both the initial load and maximum strength increase as deformation capacity reduces, requiring consideration of the reduced deformation capacity due to a high axial force. For walls under such high axial forces, using high performance steel bars is a very effective manner of enhancing deformation capacity. Therefore, reinforcing the plastic hinge region with boundary elements using high performance steel bars is preferable.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.2
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• pp.158-165
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• 2019

The purpose of this study is to investigate analytically the flexural behavior of beam reinforced by an alkali-activated slag-based fiber-reinforced composite. The materials and mixture proportion were selected to manufacture an alkali-activated slag-based fiber-reinforced composite with high tensile strain capacity over 7% and compressive strength and tension tests were performed. The composite showed a compressive strength of 32.7MPa, a tensile strength of 8.43MPa, and a tensile strain capacity of 7.52%. In order to analyze the flexural behavior of beams reinforced by ultra-high-ductile composite, nonlinear sectional analysis was peformed for four types of beams. Analysis showed that the flexural strength of beam reinforced partially by ultra-high-ductile composite increased by 8.0%, and the flexural strength of beam reinforced fully by ultra-high-ductile composite increased by 24.7%. It was found that the main reason of low improvement in flexural strength is the low tensile strain at the bottom of beam. The tensile strain at bottom corresponding to the flexural strength was 1.38% which was 18.4% of tensile strain capacity of the composite.