• 제목/요약/키워드: High-Mn steel

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압력용기용 Ni-Mo-Cr계 고강도 저합금강의 P, Mn 함량에 따른 템퍼 취화거동 및 입계편석거동 평가 (Evaluation of Temper Embrittlement Effect and Segregation Behaviors on Ni-Mo-Cr High Strength Low Alloy RPV Steels with Changing P and Mn Contents)

  • 박상규;김민철;이봉상;위당문
    • 대한금속재료학회지
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    • 제48권2호
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    • pp.122-132
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    • 2010
  • Higher strength and fracture toughness of reactor pressure vessel steels can be obtained by changing the material specification from that of Mn-Mo-Ni low alloy steel (SA508 Gr.3) to Ni-Mo-Cr low alloy steel (SA508 Gr.4N). However, the operation temperature of the reactor pressure vessel is more than $300^{\circ}C$ and the reactor operates for over 40 years. Therefore, we need to have phase stability in the high temperature range in order to apply the SA508 Gr.4N low alloy steel for a reactor pressure vessel. It is very important to evaluate the temper embrittlement phenomena of SA508 Gr.4N for an RPV application. In this study, we have performed a Charpy impact test and tensile test of SA508 Gr.4N low alloy steel with changing impurity element contents such as Mn and P. And also, the mechanical properties of these low alloy steels after longterm heat treatment ($450^{\circ}C$, 2000hr) are evaluated. Further, evaluation of the temper embrittlement by fracture analysis was carried out. Temper embrittlement occurs in KL4-Ref and KL4-P, which show a decrease of the elongation and a shifting of the transition curve toward high temperature. The reason for the temper embrittlement is the grain boundary segregation of the impurity element P and the alloying element Ni. However, KL4-Ref shows temper embrittlement phenomena despite the same contents of P and Ni compared with SC-KL4. This result may be caused by the Mn contents. In addition, the behavior of embrittlement is not largely affected by the formation of $M_3P$ phosphide or the coarsening of Cr carbides.

Si, Mn함유 IF 고강도강의 소둔거동 및 도금특성에 미치는 이슬점 온도의 영향 (Effect of Dewpoints on Annealing Behavior and Coating Characteristics in IF High Strength Steels Containing Si and Mn)

  • 전선호;신광수;손호상;김대룡
    • 대한금속재료학회지
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    • 제46권7호
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    • pp.427-436
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    • 2008
  • The effect of dewpoints on annealing behavior and coating characteristics such as wettability and galvannealing kinetics was studied by annealing 0.3wt%Si - 0.1~0.4wt% Mn added interstitial-free high strength steels(IF-HSS). The 0.3wt%Si-0.1wt%Mn steel exhibited good wettability with molten zinc and galvannealing kinetics after annealing when the dewpoint of $H_2-N_2$ mixed gas was above $-20^{\circ}C$. It is shown that the wettability and galvannealing kinetics are directly related to the coverage of the external(surface) oxide formed by selective oxidation during annealing. At $N_2-15%H_2$ annealing atmosphere, the increase of dewpoint results in a gradual transition from external to internal selective oxidation. The decrease of external oxidation of alloying elements with a concurrent increase of their subsurface enrichment in the substrate, showing a larger surface area that was free of oxide particles, contributed to the improved wettability and galvannealing kinetics. On the other hand, the corresponding wettability and galvannealing kinetics were deteriorated with the dewpoints below $-20^{\circ}C$. The continuous oxide layer of network and/or film type was formed on the steel surface, leading to the poor wettability and galvannealing kinetics. It causes a high contact angle between annealed surface and molten zinc and plays an interrupting role in interdiffusion of Zn and Fe during galvannealing process.

고(<24%)Mn 플럭스코어드와이어를 사용한 다층 용접 시 초층 응고조직의 결정면방위에 따른 미세조직과 경도 (Microstructure and Hardness of 1st layer with Crystallographic Orientation of Solidification Structure in Multipass Weld using High Mn-Ni Flux Cored Wire)

  • 한일욱;엄정복;윤중길;이봉근;강정윤
    • Journal of Welding and Joining
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    • 제34권5호
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    • pp.77-82
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    • 2016
  • In this study, Microstructure and hardness of 1st layer with crystallographic orientation were investigated about solidification structure in multipass weld using high Mn-Ni flux cored wire. Microstructure of solidification consisted of austenite matrix and a little ${\varepsilon}-phase$ in grain boundaries. Orientation of grains was usually (001), (101), (111). According to crystallographic orientation, morphology of primary dendrite was different. The depletion of Fe and the segregation of Mn, C, Ni, Si, Cu, Cr, O were found along the grain boundaries. The area of segregation was wide with an order of (001), (101), (111) grains. And hardness of grains with crystallographic orientation increased with an order of (001), (101), (111) grains because of the segregation along dendrite boundary.

0.14C-6.5Mn 합금강의 미세조직과 잔류오스테나이트 형성에 미치는 역변태처리의 영향 (Effect of Reverse Transformation on the Microstructure and Retained Austenite Formation of 0.14C-6.SMn Alloy Steel)

  • 송기홍;이오연
    • 열처리공학회지
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    • 제13권4호
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    • pp.253-258
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    • 2000
  • The present study aimed to develop the TRIP(transformation induced plasticity) aided high strength low carbon steel sheets using reverse transformation process. The cold-rolled 0.14C-6.5Mn steel was reverse-transformed by slow heating to intercritical temperature region and air cooling to room temperature. An excellant combination of tensile strength and elongation of $98.3kgf/mm^2$ and 44.4% appears. This combination comes from TRIP phenomena of retained austenite during deformation. The stability of retained austenite Is very Important for the good ductility and it depends on diffusion of carbon and manganese during reverse transformation. The air cooling after holding at intercritical temperature retards the formation of pearlite and provides the carbon enrichment in retained austenite, resulting the increase of elongation in cold-roiled TRIP steel.

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Ti을 첨가한 Mn 강의 인장특성과 표면특성 (Tensile Strength and Surface Characteristics of Mn Steel with Ti Addition)

  • 황령경;윤성태;이관영;황선중
    • 한국주조공학회지
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    • 제44권1호
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    • pp.9-15
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    • 2024
  • 본 연구에서는 망간강을 소재로 하는 부품의 수명향상을 위해 망간강에 Ti의 첨가량을 변화하여 망간강을 주조하였으며, 주조한 소재의 특성을 확인하기 위하여 인장 및 표면 특성 그리고 베어링률 등 가공특성에 대해 조사하였다. 고망간강에 Ti 첨가 시 0.5%를 초과 시 결정립 미세화로 인한 합금의 강도가 향상되었으며 내부에 미세 탄화물이 형성시킴으로써 Mn만 첨가된 합금에 비해 표면의 마모에 대한 저항성을 높이는 결과를 나타냄을 확인하였다. 망간강에서 Ti의 함유량이 증가함으로 인해 인장강도가 증가함에는 큰 차이가 없었으나 마모성의 부분에서는 Ti이 Mn에 비해 마모성에는 미량이지만 더 큰 영향을 끼치며 Ti의 함량에 따라 탄화물의 크기 및 분포가 조대하고 균일하게 분포하였다. 망간강을 소재로 하는 부품의 수명향상을 위해 망간강에 Ti 첨가함으로써 강도 및 표면특성을 향상시킬수 있음을 확인하였다. Ti이 수지상정 결정립의 미세화로 인한 내마모성이 우수한 재질을 개발하는데 효과있음을 알 수 있었다. Ti가 첨가된 샘플에서 탄화물은 표면 거칠기에 대한 내성을 증가시키는 것으로 나타났으며 Mn강의 특성상 표면경화가 일어나기 시작하여 수명이 연장되는 것으로 보인다.

고장력 냉연강판에서 미세조직에 대한 연속어닐링조건의 영향 (Effects of Continuous Annealing Parameters on Microstructures in a Cold-Rolled High Strength Steel)

  • 정우창
    • 열처리공학회지
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    • 제17권5호
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    • pp.283-292
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    • 2004
  • The effects of the annealing parameters on microstructures were examined in a cold-rolled high strength steel containing 0.1% C, 0.5% Si, 1.5% Mn, and 0.04% Nb. It was impossible to avoid martensite in the microstructure even though the continuous annealing parameters were controlled. This indicates that the alloying elements such as silicon and manganese contributing to manganese equivalent($Mn_{eq}$) should be reduced to produce the ferrite-pearlite microstructure for the solid solution and precipitation hardened steel. It was found that a decrease in the rapid cooling temperature to $520^{\circ}C$ was effective to change the microstructure from ferrite-martensite to ferrite-pearlite-martensite. Typical dual-phase properties exhibiting a low yield ratio and a continuous yielding behavior were obtained when the rapid cooling temperature was in the range of $680^{\circ}C$ to $600^{\circ}C$. The critical volume fraction of martensite for the typical properties of dual-phase steel was about 11 percent.

Fe-3.0Ni-0.7Cr-1.4Mn-X강의 고주기피로특성에 미치는 질화/DLC코팅의 영향 (The Effect of Nitriding/DLC Coating on the High Cycle Fatigue Properties of Fe-3.0Ni-0.7Cr-1.4Mn-X Steel)

  • 장재철;김송희
    • 한국표면공학회지
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    • 제49권6호
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    • pp.587-594
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    • 2016
  • Various surface treatments and thin film coating processes on the surface of injection die steel have been developed to extend the life. Most of previous studies were mainly focused on investigating the wear and static bonding behavior of thin films. In this study complex surface treatments of DLC coating combined with ion nitriding were applied to increase fatigue life and wear resistance. Ion nitriding, DLC coating, and DLC coating following nitriding on the surface of Fe-3.0Ni-0.7Cr-1.4Mn-X steel were investigated to uncover the beneficial effect which is applicable to injection die. The effect of various surface treatments and coating conditions on high cycle fatigue resistance was studied. Surface morphology change during fatigue tests were observed with AFM. Fatigue life of the die steel increased by 10 to 1,000 times at the various level of stress amplitudes in the condition of DLC coating following the ion nitriding for 3 hrs comparing with the only DLC coated condition.

초음파를 이용한 18Mn-5Cr강 발전기 리테이닝 링의 신호분석에 관한 연구 (Research for Signal Analysis of 18Mn-5Cr Steel Generator Retaining Ring using Ultrasonic Wave)

  • 길두송;안연식;박상기
    • 동력기계공학회지
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    • 제14권2호
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    • pp.65-70
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    • 2010
  • Retaining rings are used to support the field winding end turns from the centrifugal force by the high speed of the field and these are the overstressed parts among the generator parts. There have been several retaining failures in Europe and America, all attributable to stress corrosion cracking in 18Mn-5Cr steel. Since then, each manufacture companies have developed a good 18Mn-5Cr steel in temperature, strength characteristic and it is used in many field now. From many findings and test results, we could conformed that the failure might be grown in the overstressed condition unrelated to the moisture particle.

0.27% C-1.5% Mn-1.0% Cr 강의 미세조직과 기계적성질에 미치는 Si의 영향 (Effect of Si on Mechanical Properties and Microstructure in 0.27% C-1.5% Mn-1.0% Cr Steel)

  • 정우창
    • 열처리공학회지
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    • 제30권3호
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    • pp.117-126
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    • 2017
  • The variation in microstructure and mechanical properties during heat treatment was examined in a series of 0.27% C-1.5% Mn-1.0% Cr steels with silicon contents in the range of 0 to 1.0 wt%. It was found that addition of 0.5%~1.0% silicon increased both tensile strength and impact toughness through solid solution strengthening and microstructural refinement. 0.27% C-1.0% Si-1.5% Mn-1.0% Cr steel showed tensile strength of 1,700 MPa in the as-quenched condition and the steel revealed a full martensitic structure even after air cooling from $900^{\circ}C$ to room temperature, showing air hardening characteristics. Tempering at $150^{\circ}C$ which corresponds to the typical paint-baking temperature after painting of body in white, slightly decreased the tensile strength and increased elongation, but substantially increased the impact toughness compared to the as-quenched steel.