• 한국수소및신에너지학회논문집
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• 제27권5호
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• pp.589-596
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• 2016

Effects of pressure, temperature, gas velocity, and fuel flow rate on reduction of three oxygen carriers, SDN70, OC-1, OC-2, were measured and investigated in a pressurized bubbling fluidized bed reactor. Among three oxygen carriers OC-2 was selected as the best oxygen carrier in view of fuel conversion and $CO_2$ selectivity. However, all oxygen carriers showed good reactivity even at high pressure conditions. SDN70 particle showed maximum reactivity at $900^{\circ}C$ and low reactivity at $950^{\circ}C$. However, reactivity decay of OC-1 and OC-2 particles at high temperature condition was negligible. The fuel conversion and the $CO_2$ selectivity slightly decreased as the gas velocity increased, whereas they are slightly increased as the fuel concentration increased.

• 대한기계학회논문집B
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• 제40권9호
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• pp.577-587
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• 2016

순산소 마일드 연소는 공기를 사용하는 연소에 비하여 열효율 및 연소안정성이 높고 배기가스 배출량이 낮아 유망한 연소기술 중 하나로 알려져 있지만 마일드 화염의 형성에는 아직까지 많은 어려움이 있는 실정이다. 본 논문에서는 순산소 마일드 형성을 위하여 연소기 형상 및 운전조건 변화가 순산소 마일드 연소에 미치는 영향을 3차원 수치해석을 적용하여 분석하였다. 수치해석 결과 마일드 연소화염의 특징인 고온영역과 평균온도를 감소시키는 데 있어서 산화제유속 증가가 보다 효과적임을 확인하였다. 또한 외부 예열이 없는 조건에서도 최적화된 산소-연료 공급조건에서 순산소 마일드 연소화염의 형성 가능성을 확인하였고 안정적인 순산소 마일드 연소는 당량비 0.90, 연료유속 10 m/s, 산소유속 200 m/s, 노즐간 거리 33.5 mm 조건에서 보다 안정적으로 형성됨을 확인할 수 있었다.

• 한국자동차공학회논문집
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• 제14권4호
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• pp.99-106
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• 2006

High velocity oxygen-fuel thermal spray coating of the WC-Co cermet material is a well-established process for modifying the surface properties of the structural components exposed to the corrosive and wear attacks, and also these coating are well-known method to improve the fatigue strength of material. In this study, HVOF coated SM490B are prepared to evaluation of the effect of coating on tension and fatigue crack growth behavior. The pre-crack of the fatigue crack growth test specimens machined at deposited material area, heat affected zone and boundary, respectively. Through these test, the following results are obtained: 1) Tensile strength was about 498 MPa, and fracture occurred on base metal area. 2) The fatigue crack of coated specimens propagated more rapidly than non-coated specimen in all specimens. 3) In the same coating thickness specimens, the specimens with pre-crack at boundary more rapidly propagated than the specimens with pre-crack at HAZ and deposited material area. These results can be used as basic data in a structural integrity evaluation of rolled SM490B weldments considering HVOF coating.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2002년도 제25회 KOSCI SYMPOSIUM 논문집
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• pp.57-64
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• 2002

This paper describes the results of a series of experiments executed by using two pilot-scale oxv-fuel burners are designed for maximum capacity of 50,000 kacl/hr, 300,000 kcal/hr and installed in the test furnace. The effects of turn-down ratio, excess oxygen ratio, nozzle exit velocity, injection angle, swirl vane angle and inlet oxygen temperature on the combustion characteristic are investigated. Temperature distributions are measured using R-type and Molybdenum sheathed C-type thermocouple. The results showed that maximum temperature and mean temperature increase with the increase of turn-down ratio and inlet oxygen temperature. The maximum flame temperature was increased about 35% compared to the case of equivalent air operated condition. In addition, Optimum excess oxygen ratio and nozzle characteristics are obtained for this oxy-fuel glass melting furnace.

• 한국수소및신에너지학회논문집
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• 제32권1호
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• pp.53-62
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• 2021

Batch type reduction-oxidation tests were performed to check effects of temperature, pressure, gas velocity, and capacity on reduction characteristics of mass produced particle in a 0.5 MWth chemical looping combustion system. The fuel conversion and the CO2 selectivity increased as the temperature increased and as the gas velocity decreased. However the CO2 selectivity showed the maximum and decreased as the capacity increased because the CO emission increased. The results show that high temperature, low gas velocity and low inert gas concentration are preferable to ensure high reactivity of oxygen carrier in the fuel reactor.

• 한국분말재료학회지
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• 제25권5호
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• pp.408-414
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• 2018

This study investigates the microstructure and wear properties of cermet (ceramic + metal) coating materials manufactured using high velocity oxygen fuel (HVOF) process. Three types of HVOF coating layers are formed by depositing WC-12Co, WC-20Cr-7Ni, and Cr3C2-20NiCr (wt.%) powders on S45C steel substrate. The porosities of the coating layers are $1{\pm}0.5%$ for all three specimens. Microstructural analysis confirms the formation of second carbide phases of $W_2C$, $Co_6W_6C$, and $Cr_7C_3$ owing to decarburizing of WC phases on WC-based coating layers. In the case of WC-12Co coating, which has a high ratio of $W_2C$ phase with high brittleness, the interface property between the carbide and the metal binder slightly decreases. In the $Cr_3C_2-20CrNi$ coating layer, decarburizing almost does not occur, but fine cavities exist between the splats. The wear loss occurs in the descending order of $Cr_3C_2-20NiCr$, WC-12Co, and WC-20Cr-7Ni, where WC-20Cr-7Ni achieves the highest wear resistance property. It can be inferred that the ratio of the carbide and the binding properties between carbide-binder and binder-binder in a cermet coating material manufactured with HVOF as the primary factors determine the wear properties of the cermet coating material.

• 동력기계공학회지
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• 제18권4호
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• pp.72-77
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• 2014

The aim of this study to investigate polarization characteristics of WC-based alloy coatings fabricated by high velocity oxygen fuel(HVOF) process. The coatings were fabricated by HVOF process with WC-CrC-Ni, WC-Co-Cr, WC-Co composite powders. Corrosion tests were carried out using potentiostat/galvanostat at solution with pH 2 and pH 6. Corrosion potential(Ecorr) and corrosion current density(Icorr) could be analyzed from polarization curve. WC-Co-Cr coating showed more incorrodible characteristics than other coatings at solution pH 2. WC-CrC-Ni coating was more favorable anti-corrosion characteristics than other coatings at solution with pH 6.

• 한국분말재료학회지
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• 제29권3호
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• pp.226-232
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• 2022

In this study, a new manufacturing process for a multilayer-clad electrical contact material is suggested. A thin and dense BCuP-5 (Cu-15Ag-5P filler metal) coating layer is fabricated on a Ag plate using a high-velocity oxygen-fuel (HVOF) process. Subsequently, the microstructure and bonding properties of the HVOF BCuP-5 coating layer are evaluated. The thickness of the HVOF BCuP-5 coating layer is determined as 34.8 ㎛, and the surface fluctuation is measured as approximately 3.2 ㎛. The microstructure of the coating layer is composed of Cu, Ag, and Cu-Ag-Cu3P ternary eutectic phases, similar to the initial BCuP-5 powder feedstock. The average hardness of the coating layer is 154.6 HV, which is confirmed to be higher than that of the conventional BCuP-5 alloy. The pull-off strength of the Ag/BCup-5 layer is determined as 21.6 MPa. Thus, the possibility of manufacturing a multilayer-clad electrical contact material using the HVOF process is also discussed.

• 한국분말재료학회지
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• 제29권4호
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• pp.283-290
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• 2022

A Cu-15Ag-5P filler metal (BCuP-5) is fabricated on a Ag substrate using a high-velocity oxygen fuel (HVOF) thermal spray process, followed by post-heat treatment (300℃ for 1 h and 400℃ for 1 h) of the HVOF coating layers to control its microstructure and mechanical properties. Additionally, the microstructure and mechanical properties are evaluated according to the post-heat treatment conditions. The porosity of the heat-treated coating layers are significantly reduced to less than half those of the as-sprayed coating layer, and the pore shape changes to a spherical shape. The constituent phases of the coating layers are Cu, Ag, and Cu-Ag-Cu3P eutectic, which is identical to the initial powder feedstock. A more uniform microstructure is obtained as the heat-treatment temperature increases. The hardness of the coating layer is 154.6 Hv (as-sprayed), 161.2 Hv (300℃ for 1 h), and 167.0 Hv (400℃ for 1 h), which increases with increasing heat-treatment temperature, and is 2.35 times higher than that of the conventional cast alloy. As a result of the pull-out test, loss or separation of the coating layer rarely occurs in the heat-treated coating layer.

• 한국수소및신에너지학회논문집
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• 제29권5호
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• pp.473-482
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• 2018

To check applicability of recently developed new oxygen carrier for 0.5 MWth chemical looping combustion system, reactivity tests were carried out at high temperature and high pressure conditions. Pressure, temperature, gas velocity, $CH_4$ flow rate, and solid height were considered as operating variables. The new oxygen carrier (N016-R4) showed not only high fuel conversion but also high $CO_2$ selectivity within all the operating conditions in this study. The reactivity of N016-R4 particle was compared with previous oxygen carriers. The N016-R4 particle represented outstanding reactivity among 10 oxygen carriers in terms of fuel conversion and $CO_2$ selectivity.