• Title/Summary/Keyword: High value added

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Studies on Adsorption Behaviour for Heavy Metal Ions from Waste Water Using Eco-philic Cellulose Derivatives (환경친화형 셀룰로오스계 유도체의 합성 및 폐수내 중금속 이온 흡착거동 연구)

  • Lee, Soon-Hong;Bae, Joong-Don
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.11
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    • pp.1146-1152
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    • 2005
  • Graft copolymers were synthesized from methylcellulose(MC) and acrylic acid(AA) with active carboxyl groups in the presence of potassium persulfate($K_2S_2O_8$) initiator to enhance adsorption capacity of toxic heavy metal such as $Pb^{2+}$ and $Cu^{2+}$ from wastewater. The resulting grafted copolymers(MC-g-AA/PAA) were mixture of the graft copolymers from MC and AA(MC-g-AA) and polyacrylic acid homopolymers(PAA). The degree of palling was increased with rising concentration of monomer and initiator under the reaction conditions at $60^{\circ}C$, 3 hrs. The water insoluble property of MC-g-AA showed more than 19.7% degree of grafting. So that it could be an adsorbent of heavy metals. Adsorption characteristics of the MC-g-AA were evaluated depending on the degree of grading, pH of wastewater, adsorption time, dosage of MC-g-AA and concentration of heavy metals in the different conditions. Degree of grafting, and initial concentration of heavy metal ions increased, the adsorption amount of $Pb^{2+}$ and $Cu^{2+}$ increased, but added MC-g-AA increased, the adsorption amount per unit weight of $Pb^{2+}$ and $Cu^{2+}$ decreased. The MC-g-AA showed the high $Pb^{2+}$ and $Cu^{2+}$ adsorption amount in the range pH $4{\sim}6$. Also all of $Pb^{2+}$ and $Cu^{2+}$ ions reached in adsorption equilibrium in neighborhood 4 hours. The adsorption of heavy metals described by Freundlich isotherm, it was determined the value of l/n of $Pb^{2+}$ and $Cu^{2+}$ that 0.4294 and 0.3453, respectively.

Development of an Index for the Risk Assessment of Walking Trail (탐방로 재난 위험성 평가를 위한 위험지수 개발)

  • Kwak, Jae Hwan;Kim, Hong Gyun;Kim, Youl;Kim, Man-Il;Lee, Moon Se
    • The Journal of Engineering Geology
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    • v.28 no.3
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    • pp.379-395
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    • 2018
  • A walking trail environment can be divided into the upper part of the trail, the trail itself, and the lower part of the trail. In this study, based on field investigations, we developed a risk index for trails by considering human/societal factors that affect each of these three trail environments. A checklist was developed for field investigations, and checklist items were scored through relative importance analysis. The relative weights of items were analyzed using the AHP (Analytic Hierarchy Process) technique, revealing that the upper environment of a trail is twice as important as the rest of the environment. The importance and score of items belonging to each environment were determined. We define the risk index as the sum of the item scores. Weights were added using data from existing investigations including landslides risk rating and designated risk steep slopes. The risk index has a maximum value of 200, and the maximum and minimum calculated scores of 335 risk sections were 159 and 64.2, respectively. As a result of comparative analysis between field observations and risk index calculations, most sections at relatively low risk had risk values less than 100, and sections with high risks or that had been the site of accident yielded scores that exceeded 140.

Microbial bioconversion of natural Philippine nut oils into a value-added hydroxy fatty acid, 7,10-dihydroxy-8(E)-octadecenoic acid (미생물 생변환을 통한 필리핀 너트유로부터 기능성 지방산 7,10-dihydroxy-8(E)-octadecenoic acid 생산)

  • Dasangrandhi, Chakradhar;Ellamar, Joel B.;Kim, Young Soon;Kim, In Hwan;Kim, Hak-Ryul
    • Korean Journal of Food Science and Technology
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    • v.49 no.1
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    • pp.28-34
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    • 2017
  • Biocatalytic modification of natural resources can be used to generate novel compounds with specific properties, such as higher viscosity and reactivity. The production of hydroxy fatty acids (HFAs), originally found in low quantities in plants, is a good example of the biocatalytic modification of natural vegetable oils. HFAs show high potential for application in a wide range of industrial products, including resins, waxes, nylons, plastics, lubricants, cosmetics, and additives in coatings and paintings. In a recent study, Pseudomonas aeruginosa strain PR3 was used to produce 7,10-dihydroxy-8(E)-octadecenoic acid (DOD) from oleic acid. This present study focused primarily on the utilization of three natural nut oils obtained from the Philippines -pili nut oil (PNO), palm oil (PO), and virgin coconut oil (VCO)- to produce DOD by P. aeruginosa strain PR3. Strain PR3 produced DOD from PNO and PO only, with PNO being the more efficient substrate. An optimization study to achieve the maximum DOD yield from PNO revealed the optimal incubation time and medium pH to be 48 h and 8.0, respectively. Among the carbon sources tested, fructose was the most efficiently used, with a maximum DOD production of 130 mg/50 mL culture. Urea was the optimal nitrogen source, with a maximum product yield of 165 mg/50 mL culture. The results from this study demonstrated that PNO could be used as an efficient substrate for DOD production by microbial bioconversion.

Effects of fermentation by the commercial starter ABT-5 on the flavor and antioxidant activities of dark chocolate (복합 유산균 스타터 ABT-5를 이용한 발효 다크 초콜릿의 항산화 활성 및 향기 성분)

  • Koh, So Yae;Ryu, Ji-Yeon;Kim, Hyeon A;Kim Cho, Somi
    • Korean Journal of Food Science and Technology
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    • v.49 no.6
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    • pp.617-624
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    • 2017
  • Chocolate, one of the most popular confectioneries in the world, is known for its aromatic flavor and high antioxidant activities. In this study, we investigated the effects of fermentation with commercially available lactic acid bacteria, ABT-5, on the flavor and antioxidant activities of dark chocolate. During 24 h fermentation, pH decreased from 5.52 to 3.97 and total acidity increased from 0.51 to 1.85%, whereas total polyphenol and flavonoid contents as well as DPPH and ABTS radical scavenging activities remained unchanged. Furthermore, compared with control HepG2 cells treated with unfermented dark chocolate, those treated with the fermented dark chocolate showed significantly lower levels of reactive oxygen species and higher viability under $H_2O_2-induced$ oxidative stress. Finally, GC-MS and headspace GC-MS analysis detected 4-hydroxy-2,5-dimethyl-3(2H)-furanone and 2-furanmethanol, known to enhance flavor, in the fermented dark chocolate. Collectively, these results suggest that ABT-5-fermented dark chocolate could be utilized for developing value-added dark chocolate products.

A Study on the Pyrolysis Processing for sludge disposal in sewage treatment plant (하수처리장내 슬러지 처리를 위한 열분해공정에 관한 연구)

  • Ha, Sang-An;Kim, Hyeoog-Seok;Sung, Nak-Chang
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.4
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    • pp.65-74
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    • 2002
  • This Study was investigated operating condition of pyrolysis processing for sludge disposal in sewage treatment plant. Important parameters studied include running time of pyrolysis, run time of dry and pyrolysis processing, water content of sewage sludge, solids amount of sewage sludge(TS%), condition of pyrolysis temperature. Most degradation reaction of sewage sludge are first order, it assumed first order and elucidated the kinetics. This was the basis of characteristics analysis of sludge degradation mechanism. Also, with the increasing of temperature, how the yield of oil and char product change was observed, and the distribution of gas product components was observed. Main components of gas and carbon product are a little difference with pyrolysis temperature, but it consist of $CH_4$, $C_2H_4$, $C_3H_8$, $C_4H_{10}$, toluene, $C_6H_6$, $SO_2$, CO etc. The gas of $C_1-C_4$ yield increased along with degradation temperature of $670^{\circ}C$ and oil yield decreased of $C_6H_6$ and $C_6H_5OH$ with temperature of $600^{\circ}C$. Particularly, low value added char yield 134kg/t at $670^{\circ}C$, but increased to 194kg/t at pyrolysis temperature of $600^{\circ}C$. In the result of elementary analysis on it, it is mainly composed of carbon. From this fact, in pyrolysis of sludge, it comfirmed that carbonization reaction occur at high temperature well.

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Strength properties of composite clay balls containing additives from industry wastes as new filter media in water treatment

  • Rajapakse, J.P.;Gallage, C.;Dareeju, B.;Madabhushi, G.;Fenner, R.
    • Geomechanics and Engineering
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    • v.8 no.6
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    • pp.859-872
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    • 2015
  • Pebble matrix filtration (PMF) is a water treatment technology that can remove suspended solids in highly turbid surface water during heavy storms. PMF typically uses sand and natural pebbles as filter media. Hand-made clay pebbles (balls) can be used as alternatives to natural pebbles in PMF treatment plants, where natural pebbles are not readily available. Since the high turbidity is a seasonal problem that occurs during heavy rains, the use of newly developed composite clay balls instead of pure clay balls have the advantage of removing other pollutants such as natural organic matter (NOM) during other times. Only the strength properties of composite clay balls are described here as the pollutant removal is beyond the scope of this paper. These new composite clay balls must be able to withstand dead and live loads under dry and saturated conditions in a filter assembly. Absence of a standard ball preparation process and expected strength properties of composite clay balls were the main reasons behind the present study. Five different raw materials from industry wastes: Red Mud (RM), Water Treatment Alum Sludge (S), Shredded Paper (SP), Saw Dust (SD), and Sugar Mulch (SM) were added to common clay brick mix (BM) in different proportions. In an effort to minimize costs, in this study clay balls were fired to $1100^{\circ}C$ at a local brick factory together with their bricks. A comprehensive experimental program was performed to evaluate crushing strength of composite hand-made clay balls, using uniaxial compression test to establish the best material combination on the basis of strength properties for designing sustainable filter media for water treatment plants. Performance at both construction and operating stages were considered by analyzing both strength properties under fully dry conditions and strength degradation after saturation in a water bath. The BM-75% as the main component produced optimum combination in terms of workability and strength. With the material combination of BM-75% and additives-25%, the use of Red Mud and water treatment sludge as additives produced the highest and lowest strength of composite clay balls, with a failure load of 5.4 kN and 1.4 kN respectively. However, this lower value of 1.4 kN is much higher than the effective load on each clay ball of 0.04 kN in a typical filter assembly (safety factor of 35), therefore, can still be used as a suitable filter material for enhanced pollutant removal.

EFFECTS OF ACTIVATED CARBON ON GROWTH, RUMINAL CHARACTERISTICS, BLOOD PROFILES AND FEED DIGESTIBILITY IN SHEEP

  • Garillo, E.P.;Pradhan, R.;Tobioka, H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.8 no.1
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    • pp.43-50
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    • 1995
  • This study was carried out to investigate the effects of activated carbon (AC) on growth, ruminal charateristics, blood profiles and feed digestibility in sheep, using roughage-based or concentrate-based diets. Twelve Suffolk breed of sheep of similar age and weight were distributed into 4 groups in a $2{\times}2$ factorial design. Two groups were fed a roughage-based diet with (R + AC) and without AC (R - AC), while the other two were fed a concentrate-based diet with (C + AC) and without AC (C - AC), respectively. The addition of 0.3% AC was based on dry matter of feed offered to animals. The incorporation of AC in roughage and concentrate based diets had no marked effects on feed intake, daily gain and feed conversion of the animals within experimental diets. The results obtained might be due to the low level of AC added in the diet. The animal on both concentrate-based diets were higher than the roughage-based diets in terms of daily gain and feed conversion ratio. However, it was observed that the animals provided with AC in the concentrate-based diet did not suffer from diarrhea and easily adjusted to high concentrate feeding. Further, the pH value for all diets before feeding was noted to be similar. After feeding, however, pH was shown to be higher in R + AC (p < 0.05) than in C + AC diet. Rumen protozoa number was decreased after feeding for both + AC diets, but in C - AC diet it was higher than in the roughage-based diets. For ammonia-nitrogen, C - AC was found to be higher than C + AC diet and the roughage-based diets before feeding. Total volatile fatty acid concentration, propionate and valerate molar ratios for both diets and time of collection were not affected. However, acetate, butyrate and valerate molar ratios were observed to be affected by diets and time of collections. The diets with AC increased (p < 0.05) before feeding for acetate molar ratio, but not different within diet, however, the roughage diets were found to be higher (p < 0.05) in acetate than the concentrate diet. In the blood parameters, the glutamic pyruvic transaminase (GPT), red and white blood cell (RBC, WBC) counts and packed cell volume (PCV) did not differ within and among the diets. Likewise, the WBC differential count in both diets with either - AC or + AC were similar in trend. However, lymphocyte count was noted to be increased in R + AC than the R - AC diet. The addition of AC in both diets did not affect nutrient digestibilities within diets.

A Study on the Spectatorship through Character of (<심슨가족>의 캐릭터를 통한 관객성 연구)

  • Youm, Dong-Cheol
    • Cartoon and Animation Studies
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    • s.21
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    • pp.1-17
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    • 2010
  • As animation emerged as a high value-added content business, more studies are conducted focusing on the fact that the key to the success of animation is not a story but a character. This study aims to examine the characters of , the globally loved animation, and figure out its interactive way of attracting viewers based on Spectatorship Theory, so that it can help set the nation's TV animation series to be made on the right track. To achieve this goal, it will explore various aspects including the concept of animation character, the relations between ideology and character, and the changes in design according to a social phenomenon, then based on Spectatorship Theory will analyze and suggest how the characters of fulfill the required conditions to attract viewers. In addition, it will examine the wide application of the characters of . In conclusion, unlike theatrical animation, TV animation has a characteristic that it can easily and repeatedly deliver messages to viewers over a long time, however, domestic TV animation turned out to fail to utilize the advantage. In other words, while its character has distinct individuality, it is not supported by creative and solid story line, and the character is not attractive as much as the characters of which successfully evoke sympathy from viewers. In animation, arousing sympathy from its viewers or audiences is very important, so a character that well reflects social discourse is an integral part of it. Therefore, in-depth and specialized study on animation's character is highly required for the sustainable success and growth of domestic animation.

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The Strengthening of Export Competitiveness through the 6th Agriculture Industrialization and the 4th Industrial Revolution (4차 산업혁명 시대에 농업의 6차산업화와 이를 통한 수출경쟁력 강화)

  • Jung, Jin-Sup;Khoe, Kyungil
    • The Journal of Industrial Distribution & Business
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    • v.9 no.3
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    • pp.31-43
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    • 2018
  • Purpose - With the technology of the 4th industrial revolution, business models of agricultural sector are changing rapidly toward convergence and high value-added business models due to the 6th industrialization of agricultural. Our goals is to examine the 6th industrialization of agriculture, and then to apply the technology of the 4th industrial revolution to the 6th industrialization of agriculture, suggesting the possibility of future agriculture, and then linking the export competitiveness of agricultural products. Research design, data, and methodology - As the methodology, case studies and empirical analyzes were conducted as well as literature studies. The case analyses included tomatoes, pig breeding farms, and an empirical analysis was conducted using the AHP analysis by experts of the 6th industrialization. In addition, using 124 survey data, this study examined and analyzed the items of the 4th industrial revolution technology for the 6th industrialization of agriculture and the strengthening of export competitiveness. Results - Results showed that the technology of the 4th Industrial Revolution helped "6th industrialization of agriculture" and "the strengthening of export competitiveness" using two successful cases. The AHP analysis was also carried out, and it was found that the improvement of the technology in the 4th industrial revolution could contribute to the future industrialization as well as the 6th industrialization of agriculture. First of all, we looked many conditions were important and urgent. Among the technologies of the 4th industrial revolution, the mobile, big data were important. Moreover, it was recognized that linkage and convergence related efforts would greatly contribute to strengthening export competitiveness of agriculture such as price and quality competitiveness. Conclusions - The 4th industrial revolution such as hyper-connectivity, hyper-intelligence and hyper-predictability contribute greatly to the 6th industrialization of agriculture, and therefore it is essential to improve the competitiveness of the agricultural sector by using the technology of the 4th industrial revolution. In particular, based on analyses of the diamond model, the "demand conditions" was the most important factor for the activation of the 6th Industrialization, and then "related and supporting fields", "factor conditions" and "business context" were followed in order. The results of this study can be useful for policy, practical and academic sectors.

A study on carbonization on the surface of steel sheet during the BAF annealing process (BAF 소둔공정에서 탄화 현상에 관한 연구)

  • Lee, Jong-Lyul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.7
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    • pp.42-49
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    • 2018
  • In steel industries, cold-rolled sheet manufacturing is one of the links between the front and rear important industries for national competitiveness and high value-added production. In particular, in small and medium-sized enterprises, one of the major problems is the carbonization phenomenon of the steel sheet during the annealing process. Carbonization occurring on the surface of the coil help reduce steel production. After conducting various experiments to identify the cause of carbonization on the surface of a cold-rolled steel, the following results were obtained: (1) An analysis of the rolling oil, which is used in the field, revealed it to contain approximately 40 ppm carbonized material. (2) A comparison of the thermal denaturation characteristics of the fresh rolling oil and using rolling oil by FT-IR analysis showed that thermal denaturation had occurred, as shown by the significant decrease in the relative intensity of the 2900 and $1750cm^{-1}$ peaks. (3) The thermal decomposition of the rolling oil took place for the rolling oil at approximately $220^{\circ}C$. Furthermore, annealing experiments at $200^{\circ}C$ showed that the carbonization phenomenon of the sample was not observed. On the other hand, carbonization was observed at temperatures higher than $240^{\circ}C$.