• Carbon letters
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• 제13권1호
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• pp.48-50
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• 2012

Mass production of graphene-based materials, which have high specific surface area, is of importance for industrial applications. Herein, we report on a facile approach to produce thermally modified graphene oxide (TMG) in large quantities. We performed this experiment with a hot plate under environments that have relatively low temperature and no using inert gas. TMG materials showed a high specific surface area (430 $m^2g^{-1}$). Successful reduction was confirmed by elemental analysis, X-ray photoelectron spectroscopy, thermogravimetic analysis, and X-ray diffraction. The resulting materials might be useful for various applications such as in rechargeable batteries, as hydrogen storage materials, as nano-fillers in composites, in ultracapacitors, and in chemical/bio sensors.

• 한국조명전기설비학회:학술대회논문집
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• 한국조명전기설비학회 2004년도 춘계학술대회 논문집
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• pp.392-396
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• 2004

Experimental equipments for long-term outdoor tests of EHV insulators in outdoor were constructed. The testing insulators have been energized with 89 [kV] phase-to-ground AC voltage under identical condition at station, and the investigation was carried out for leakage current and various environments such as temperature, relative humidity and wind velocity. The test results of leakage current wave trends have forms on distorted waves including harmonics. The porcelain and glass insulators have low leakage current in case of daytime because moisture and humidity have relative low values. In comparison with these conditions, high leakage current was shown at dawn and rainy day due to high humidity. However, leakage current of polymer insulators was shown approximately $129[{\mu}m]$ without relation to the weather due to hydrophobicity on their surface.

• 한국기계가공학회지
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• 제19권4호
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• pp.1-8
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• 2020

Mechanical components that support structures in aerospace and power generation industries require high-strength materials. Particularly, in the aerospace industry, aluminum alloys, titanium alloys, and composite materials are increasingly used due to their high maneuverability and durability to withstand low temperature extreme environments; however, ultra-high-strength steel is still used in key components under heavy loads such as landing gears. In this paper, the fault cause analysis and troubleshooting of aircraft parts made of ultra-high-strength steel (300M) broken during normal operation are described. To identify the cause of the defect, a temporary inspection of the same aircraft was performed, and material testing, non-destructive inspection, microstructure examination, and fracture area inspection of the damaged parts were performed. Fracture analysis results showed that a crack in the shape of a branch developed from the tool mark in the direction of the intergranular strain. Based on the results, the cause of fracture was confirmed to be stress corrosion.

• 한국대기환경학회지
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• 제31권5호
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• pp.449-460
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• 2015

Carbonaceous aerosol is generally classified into OC (organic carbon) and EC (elemental carbon) by thermal optical analysis. Both NIOSH (National institute of occupational safety and health) with high temperature (HighT) and IMPROVE-A (Interagency monitoring of protected visual environments) with low temperature (LowT) protocols are widely used. In this study, both protocols were applied for ambient $PM_{2.5}$ samples (Daejeon, Korea) in order to underpin differences in OC and EC measurements. An excellent agreement between NIOSH and IMPROVE-A protocol was observed for TC (total carbon). However, significant differences between OC and EC appeared and the differences were larger for EC than OC. The main differences between two protocols are temperature profile and charring correction method. For the same charring correction method, HighT_OC was 10% higher than LowT_ OC, while HighT_EC was 15% and 33% lower than LowT_EC for TOT (thermal-optical transmittance) and TOR (thermal-optical reflectance), respectively. This difference may be caused by the temperature of OC4 in He step and possibly difference in POC (pryorilized OC) formation. For the same temperature profile, OC by TOT was about 26% higher than that by TOR. In contrast, EC by TOT was about 50% lower than that by TOR. POC was also dependent on both temperature profile and the charring correction method, showing much distinctive differences for the charring correction method (i.e., POC by TOT to POC by TOR ratio is about 2). This difference might be caused by different characteristics between transmittance and reflectance for monitoring POC formation within filters. Results from this study showed that OC and EC depends on applied analysis protocol as shown other studies. Because of the nature of the thermal optical analysis, it may not be possible to have an absolute standard analysis protocol that is applicable for any ambient $PM_{2.5}$. Nevertheless, in order to provide consistent measurement results for scientists and policy makers, future studies should focus on developing a harmonized standard analysis protocol that is suitable for a specific air domain and minimizes variations in OC and EC measurement results. In addition, future elaborate studies are required to find and understand the causes of the differences.

• Nuclear Engineering and Technology
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• 제48권5호
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• pp.1206-1218
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• 2016

This article proposes a highly reliable power and communication system that guarantees the protection of essential instruments in a nuclear power plant under a severe accident. Both power and communication lines are established with not only conventional wired channels, but also the proposed wireless channels for emergency reserve. An inductive power transfer system is selected due to its robust power transfer characteristics under high temperature, high pressure, and highly humid environments with a large amount of scattered debris after a severe accident. A thermal insulation box and a glass-fiber reinforced plastic box are proposed to protect the essential instruments, including vulnerable electronic circuits, from extremely high temperatures of up to $627^{\circ}C$ and pressure of up to 5 bar. The proposed wireless power and communication system is experimentally verified by an inductive power transfer system prototype having a dipole coil structure and prototype Zigbee modules over a 7-m distance, where both the thermal insulation box and the glass-fiber reinforced plastic box are fabricated and tested using a high-temperature chamber. Moreover, an experiment on the effects of a high radiation environment on various electronic devices is conducted based on the radiation test having a maximum accumulated dose of 27 Mrad.

• 한국재료학회지
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• 제21권11호
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• pp.596-603
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• 2011

The very high temperature gas reactor (VHTR) is one of the next generation nuclear reactors for its safety, long-term stability, and proliferation-resistance. The high operating temperature of over 800$^{\circ}C$ enables various applications with high energy efficiency. Heat is transferred from the primary helium loop to the secondary helium loop through the intermediate heat exchanger (IHX). The IHX material requires creep resistance, oxidation resistance, and corrosion resistance in a helium environment at high operating temperatures. A Ni-based superalloy such as Alloy 617 is considered as a primary candidate material for the intermediate heat exchanger. In this study, the microstructures of Alloy 617 crept in pure helium and air environments at 950$^{\circ}C$ were observed. The rupture time in helium was shorter than that in air under small applied stresses. As the exposure time increased, the thickness of outer oxide layer of the specimens clearly increased but delaminated after a long creep time. The depth of the carbide-depleted zone was rather high in the specimens under high applied stress. The reason was elucidated by the comparison between the ruptured region and grip region of the samples. It is considered that decarburization caused by minor gas impurities in a helium environment caused the reduction in creep rupture time.

• Corrosion Science and Technology
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• 제13권2호
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• pp.41-47
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• 2014

The isothermal corrosion tests of several types of stainless steels, Ni-based alloys, and ferritic-martensitic steels (FMS) were carried out at the temperature of 550 and $650^{\circ}C$ in SFR S-$CO_2$ environment (200 bar) for 1000 h. The weight gain was greater in the order of FMSs, stainless steels, and Ni-based alloys. For the FMSs (Fe-based with low Cr content), a thick outer Fe oxide, a middle (Fe,Cr)-rich oxide, and an inner (Cr,Fe)-rich oxide were formed. They showed significant weight gains at both 550 and $650^{\circ}C$. In the case of austenitic stainless steels (Fe-based) such as SS 316H and 316LN (18 wt.% Cr), the corrosion resistance was dependent on test temperatures except SS 310S (25 wt.% Cr). After corrosion test at $650^{\circ}C$, a large increase in weight gain was observed with the formation of outer thick Fe oxide and inner (Cr,Fe)-rich oxide. However, at $550^{\circ}C$, a thin Cr-rich oxide was mainly developed along with partially distributed small and nodular shaped Fe oxides. Meanwhile, for the Ni-based alloys (16-28 wt.% Cr), a very thin Cr-rich oxide was developed at both test temperatures. The superior corrosion resistance of high Cr or Ni-based alloys in the high temperature S-$CO_2$ environment was attributed to the formation of thin Cr-rich oxide on the surface of the materials.

• 한국세라믹학회지
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• 제52권6호
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• pp.462-466
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• 2015

This paper reports the microstructure of hot-pressed $ZrB_2$-SiC ceramics with added $B_4C$ as characterized by transmission electron microscopy. $ZrB_2$ has a melting point of $3245^{\circ}C$, a relatively low density of $6.1g/cm^3$, and specific mechanical properties at an elevated temperature, making it a candidate for application to environments with ultra-high temperatures which exceed $2000^{\circ}C$. Due to the non-sinterability of $ZrB_2$-based ceramics, research on sintering aids such as $B_4C$ or $MoSi_2$ has become prominent recently. From TEM investigations, an amorphous layer with contaminant oxide is observed in the vicinity of $B_4C$ grains remaining in hot-pressed $ZrB_2$-SiC ceramics with $B_4C$ as an additive. The effect of a $B_4C$ addition on the microstructure of this system is also discussed.

• 환경생물
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• 제25권4호
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• pp.363-369
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• 2007

본 연구는 히어리 개체군의 분포가 북사면에서 제한적으로 분포하는 요인을 구명하기 위하여 실내 실험 및 전라남도 순천지역의 히어리 자생지에서 생육지(남사면과 북사면) 실험를 대상으로 종자 발아실험과 미기상 환경을 조사하였다. 종자 발아실험은 실내 및 생육 현지에서 실시하였고, 미기상 요인 측정은 히어리가 분포하는 지역과 분포하지 않는 두 지점에 대하여 기온, 지온, 습도, 토양수분 및 광량자를 각각 측정하였다. 히어리의 종자는 사면에 따른 환경에는 영향을 받지 않고 발아되어 종자의 산포 및 발아단계에서 사면의 환경 차이가 제한 요소로 작용하지 않는 것으로 판단되었다. 하지만 발아한 유묘가 정착하는 단계에서 북사면이 남사면에 비해 낮은 온도와 높은 습도를 보여, 북사면이 상대적으로 건조에 취약한 유묘의 정착에 용이한 환경을 제공하는 것으로 조사되었다. 정착단계 이후 개체군의 성립 단계에서는 북사면이 남사면에 비하여 낮은 온도와 높은 습도가 유지되었지만 그 차이는 미미하게 나타나 히어리 개체군의 성립에 있어 발아단계에서 유묘로 정착하는 초기 단계에서의 히어리 개체군의 사면적 분포특성에 영향을 미치는 중요한 요인으로 작용함을 파악할 수 있었다.

• Nuclear Engineering and Technology
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• 제51권1호
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• pp.238-248
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• 2019

In the high-temperature and high-pressure irradiation environments, the multi-field coupling processes of hydrogen diffusion, hydride precipitation and mechanical deformation in Zircaloy cladding tubes occur. To simulate this hydrogen-induced complex behavior, a multi-field coupling method is developed, with the irradiation hardening effects and hydride-precipitation-induced expansion and hardening effects involved in the mechanical constitutive relation. The out-pile tests for a cracked cladding tube after irradiation are simulated, and the numerical results of the multi-fields at different temperatures are obtained and analyzed. The results indicate that: (1) the hydrostatic stress gradient is the fundamental factor to activate the hydrogen-induced multi-field coupling behavior excluding the temperature gradient; (2) in the local crack-tip region, hydrides will precipitate faster at the considered higher temperatures, which can be fundamentally attributed to the sensitivity of TSSP and hydrogen diffusion coefficient to temperature. The mechanism is partly explained for the enlarged velocity values of delayed hydride cracking (DHC) at high temperatures before crack arrest. This work lays a foundation for the future research on DHC.